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Journal of Analytical Chemistry

, Volume 66, Issue 14, pp 1445–1454 | Cite as

Identification of the products of nonregioselective organic reactions by chromatography-mass spectrometry: Chloro derivatives of dialkyl ethers

  • I. G. ZenkevichEmail author
  • E. V. Eliseenkov
  • A. N. Kasatochkin
  • A. I. Ukolov
Articles
  • 55 Downloads

Abstract

The possibilities of GC-MS identification of the products of free-radical chlorination of dialkyl ethers are considered. The principal feature of this problem was the absence of appropriate reference information (both mass spectra and GC retention indices) for chloro derivatives of ethers. It was shown that all monochloro and selected dichloro derivatives can be identified on the basis of joint interpretation of their mass spectra combined with evaluating the retention indices using different additive schemes.

Keywords

dialkyl ethers free-radical chlorination mass spectra chromatographic retention indices identification of products 

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Copyright information

© Pleiades Publishing, Ltd. 2011

Authors and Affiliations

  • I. G. Zenkevich
    • 1
    Email author
  • E. V. Eliseenkov
    • 1
  • A. N. Kasatochkin
    • 1
  • A. I. Ukolov
    • 1
  1. 1.Department of ChemistrySt. Petersburg State UniversitySt. PetersburgRussia

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