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Quantification of chloroanilines in drinking water by gas chromatography as bromo derivatives

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A procedure is developed for determination of trace amounts of simple aniline, 2- and 4-chloro-anilines, 2,4- and 2,6-dichloroanilines, 2,4,5- and 2,4,6-trichloroanilines in drinking water; it includes the formation of bromo derivatives, solvent extraction with toluene, and gas chromatography monitoring with electron-capture detection. The conditions of bromination for chloroanilines in aqueous solutions are refined; the bromination agent in use is bromine water in the presence of glycine. The analytical range makes 0.01–10 μg/L; relative standard deviation, 0.01–0.08; detection limits, 0.002–0.007 μg/L; and the duration of analysis, 50 min.

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Authors and Affiliations

  1. Institute of Biology, Komi Research, Ural Branch, Russian Academy of Sciences, ul. Kommunisticheskaya 28, Syktyvkar, 167982, Russia

    I. V. Gruzdev & B. M. Kondratenok

  2. Department of Chemistry and Biology, Syktyvkar State University, ul. Petrozavodskaya 120, Syktyvkar, 167005, Russia

    M. V. Alferova

  3. Department of Chemistry, St. Petersburg State University, Universitetskii pr. 26, St. Peterburg, 198504, Russia

    I. G. Zenkevich

Authors
  1. I. V. Gruzdev
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  2. M. V. Alferova
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  3. B. M. Kondratenok
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  4. I. G. Zenkevich
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Original Russian Text © I.V. Gruzdev, M.V. Alferova, B.M. Kondratenok, I.G. Zenkevich, 2011, published in Zhurnal Analiticheskoi Khimii, 2011, Vol. 66, No. 10, pp. 1073–1080.

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Gruzdev, I.V., Alferova, M.V., Kondratenok, B.M. et al. Quantification of chloroanilines in drinking water by gas chromatography as bromo derivatives. J Anal Chem 66, 955–962 (2011). https://doi.org/10.1134/S1061934811100042

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  • DOI: https://doi.org/10.1134/S1061934811100042

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