Journal of Analytical Chemistry

, Volume 65, Issue 3, pp 234–238 | Cite as

Photometric cyclic-injection trace determination of phosphate ions in natural waters as an ion associate of phosphomolybdate with Astra Phloxine

  • A. V. Bulatov
  • P. A. Ivasenko
  • K. A. Subbotina
  • A. B. Vishnikin
  • L. N. Moskvin


A procedure for the automatic photometric determination of phosphate ions in natural waters was developed, based on the formation of a colored ion associate of the reduced form of phosphomolybdic heteropoly anion with a polymethine dye, Astra Phloxine. The detection limit was 5 μg P/L at the sample volume of 0.3 mL.


Reaction Vessel Indolinium Intermediate Solution Photometric Detector Sequential Injection Analysis 
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  1. 1.
    Alekin, O.A., Osnovy gidrokhimii (Foundations of Hydrochemistry), Leningrad: Gidrometeoizdat, 1970.Google Scholar
  2. 2.
    Molchanova, Ya.P., Zaika, E.A., Babkina, E.I., and Surnin, V.A., Gidrokhimicheskie pokazateli sostoyaniya okruzhayushchei sredy: spravochnye materialy (Hydrochemical Parameters of Environmental Conditions: References), Moscow: Sotsial’no-ekologicheskii Soyuz, 2000.Google Scholar
  3. 3.
    Moskvin, L.N., Bulatov, A.V., Nikolaeva, D.N., and Grigor’ev, G.L., Zhurn. anal. khim., 2002, vol. 57, no. 7, p. 709 [J. Anal. Chem. (Engl. Transl.), vol. 57, no. 7, p. 590].Google Scholar
  4. 4.
    Motomizu, S. and Li, Z., Talanta, 2005, vol. 66, no. 2, p. 332.CrossRefGoogle Scholar
  5. 5.
    Estela, J.M. and Cerda, V., Talanta, 2005, vol. 66, no. 2, p. 307.CrossRefGoogle Scholar
  6. 6.
    Galhardo, C.X. and Masini, J.C., Anal. Chim. Acta, 2000, vol. 417, no. 2, p. 191.CrossRefGoogle Scholar
  7. 7.
    Moskvin, L.N., Bulatov, A.V., Kolot, A.S., and Grigor’ev, G.L., Zavod. lab. Diagn. mater., 2008, vol. 74, no. 2, p. 8.Google Scholar
  8. 8.
    Tikhomirova, T.I., Kuznetsov, M.V., Dubovik, D.B., et al., Zhurn. anal. khim., 2000, vol. 55, no. 9, p. 942 [J. Anal. Chem. (Engl. Transl.), vol. 55, no. 9, p. 846].Google Scholar
  9. 9.
    Kuznetsov, V.V., Ermolenko, Yu.V., Novikov, D.V., and Bykhovskii, M.L., Zhurn. anal. khim., 2000, vol. 55, no. 7, p. 702 [J. Anal. Chem. (Engl. Transl.), vol. 55, no. 7, p. 630].Google Scholar
  10. 10.
    Vishnikin, A.B., J. Mol. Liquids, 2005, vol. 118, nos. 1–3, p. 51.CrossRefGoogle Scholar
  11. 11.
    Vishnikin, A.B., Al-Shwaiyat, M.E.A., Bazel, Ya.R., and Andruch, V., Microchim. Acta, 2007, vol. 159, nos. 3–4, p. 371.CrossRefGoogle Scholar
  12. 12.
    Mozzhukhin, A.V., Moskvin, A.L., and Moskvin, L.N., Zhurn. anal. khim., 2007, vol. 62, no. 5, p. 527 [J. Anal. Chem. (Engl. Transl.), vol. 62, no. 5, p. 475].Google Scholar
  13. 13.
    Fedorov, A.A., Chernyakhovskaya, F.V., Vernidub, A.S., Anan’evskaya, M.P., and Zamaraev, V.P., Analiticheskaya khimiya fosfora (Analytical Chemistry of Phosphorus), Moscow: Nauka, 1974.Google Scholar
  14. 14.
    Zhang, J.-Z., Fischer, C.J., and Ortner, P.B., Talanta, 1999, vol. 49, no. 2, p. 293.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2010

Authors and Affiliations

  • A. V. Bulatov
    • 1
  • P. A. Ivasenko
    • 1
  • K. A. Subbotina
    • 1
  • A. B. Vishnikin
    • 2
  • L. N. Moskvin
    • 1
  1. 1.St. Petersburg State UniversitySt. PetersburgRussia
  2. 2.Dnepropetrovsk National UniversityDnepropetrovskUkraine

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