Skip to main content
SpringerLink
Log in

Simultaneous determination of palladium and rhodium using on-line column enrichment and electrothermal atomic absorption spectrometric detection

  • Articles
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

Flow injection on-line micro-column pre-concentration was coupled with electrothermal atomic absorption spectrometry (ETAAS) for the simultaneous determination of Rh and Pd in environmental samples. The micro-column contained 1,5-Bis(2-pyridyl)-3-sulphophenyl methylene thiocarbonohydrazide (PSTH) immobilised on an anion-exchange resin (Dowex 1 × 8–200). The sorbent was tested in a micro-column, placed in the auto-sampler arm, at the flow rate 3.1 mL/min. Elution was performed with 2 M HNO3 and the system was optimised with a 60 s pre-concentration time.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Zereini, F., Alt, F. (Eds.) Anthropogenic Platinum-Group Element Emission. Their Impact on Man and Environment, Springer-Verlag, Berlin, Heidelberg, Germany, (2000)

    Google Scholar 

  2. Wei, C., Morrison, G. M., Sci. Total. Environ., 1994, vol. 146–147, p. 169.

    Article  Google Scholar 

  3. Helmers, E., Mergel, N., Fresenius J. Anal. Chem., 1998, vol. 362, p. 522.

    Article  CAS  Google Scholar 

  4. Rauch, S., Morrison, G.M., An Environmental Case History of Platinum Group Metals. In: Cornelis R., Crews H., Donard O., Ebdon L., Chen Y., editors. Trace Element Speciation for Environment, Food and Health. Cambridge (UK): The Royal Society of Chemistry; 176 (2001).

    Chapter  Google Scholar 

  5. Boch, K., Schuster, M., Risse, G., Schwarzer, M., Anal. Chim. Acta, 2002, vol. 459, p. 257.

    Article  CAS  Google Scholar 

  6. Jensen, K.H., Rauch, S., Morrison, G.M., Lindberg, P., Arch. Environ. Contam. Toxicol., 2002, vol. 42, p. 338.

    Article  CAS  Google Scholar 

  7. Rauch, S., Hemond, H.F., Environ. Sci. Technol., 2003, vol. 37, p. 3283.

    Article  CAS  Google Scholar 

  8. Ek, K.H., Morrison, G.M., Rauch, S., Sci. Total Environ., 2004, vol. 334–335, p. 21.

    Google Scholar 

  9. Ravindra, K., Bencs, L., Van Grieken, R., Sci. Total Environ., 2004, vol. 318, p. 1.

    Article  CAS  Google Scholar 

  10. Lee, M.L., Tölg, G., Beinrohr, E., Tschöpel, P., Anal. Chim. Acta, 1993, vol. 272, p. 193.

    Article  CAS  Google Scholar 

  11. Lasztity, A., Kelko-Levai, A., Zih-Perenyi, K., Varga, I., Talanta, 2003, vol. 59, p. 393.

    Article  CAS  Google Scholar 

  12. Su, X., Wang, M., Zhang, Y., Zhang, J., Zhang, H., Jin, Q., J. Anal. At. Spectrom., 2001, vol. 16, p. 1341.

    Article  CAS  Google Scholar 

  13. Ivanova, E., Adams, F., Fresenius J. Anal. Chem., 1998, vol. 361, p. 445.

    Article  CAS  Google Scholar 

  14. Levai, A., Laszity, A., Zih-Perenyi, K., Horvath, Zs., Microchem. J., 1998, vol. 58, p. 272.

    Article  CAS  Google Scholar 

  15. Schuster, M., Schwarzer, M., Anal. Chim. Acta, 1996, vol. 328, p. 1.

    Article  CAS  Google Scholar 

  16. Gonzalez Garcia, M.M., Sánchez Rojas, F., Bosch Ojeda, C., Garcia de Torres, A., Cano Pavon, J.M., Anal. Bioanal. Chem., 2003, vol. 375, p. 1229.

    CAS  Google Scholar 

  17. Cantarero, A., Gomez, M.M., Camara, C., Palacios, M.A., Anal. Chim. Acta, 1994, vol. 296, p. 205.

    Article  CAS  Google Scholar 

  18. Limbeck, A., Rendl, J., Puxbaum, H., J. Anal. At. Spectrom., 2003, vol. 18, p. 161.

    Article  CAS  Google Scholar 

  19. Cañada, P., Garcia, A., Cano, J.M., Sanchez, F., Talanta, 1998, vol. 46, p. 1095.

    Article  Google Scholar 

  20. Bosch Ojeda, C., Sánchez Rojas, F., Cano Pavón J.M., Microchim. Acta, 2007, vol. 158, p. 103.

    Article  CAS  Google Scholar 

  21. Sánchez Rojas, F., Bosch Ojeda, C., Cano Pavón, J.M., Talanta, 2004, vol. 64, p. 230.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Analytical Chemistry, Faculty of Sciences, University of Málaga, E-29071, Málaga, Spain

    F. Sánchez Rojas, C. Bosch Ojeda & J. M. Cano Pavón

Authors
  1. F. Sánchez Rojas
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. Bosch Ojeda
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. M. Cano Pavón
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to F. Sánchez Rojas.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sánchez Rojas, F., Bosch Ojeda, C. & Cano Pavón, J.M. Simultaneous determination of palladium and rhodium using on-line column enrichment and electrothermal atomic absorption spectrometric detection. J Anal Chem 64, 241–246 (2009). https://doi.org/10.1134/S106193480903006X

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S106193480903006X

Keywords

Search

Navigation