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Kinetic determination of Ag+ using a novel Belousov-Zhabotinskii oscillating system catalyzed by a macrocyclic complex

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Abstract

A new methodological approach for the determination of Ag+ by the perturbations caused by different amounts of Ag+ on a novel Belousov-Zhabotinskii oscillating system is proposed. Such a novel oscillating system involves the participation of an unsaturated macrocyclic Cu(II) complex, [CuL](ClO4)2, as catalyst and malic acid as substrate. The ligand L in the complex is 5,7,7,12,14,14-hexemethyl-1,4,8,11-tetraazacy-clotetradeca-4,11-diene. The linear relationship between the change in the oscillating period of the chemical system and the logarithm of [Ag+] is found in the range 6.25 × 10−5 to 1.00 × 10−7 M. The obtained RSD is 0.8%. The probable mechanism involving the perturbation of Ag+ is also discussed.

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Authors and Affiliations

  1. Institute of Applied Chemistry, East China Jiaotong University, Nanchang, 330013, China

    L. Hu

  2. Department of Chemistry, Anhui University, Hefei, 230039, China

    G. Hu

  3. Key Lab of Pesticide and Chemical Biology, South China Agricultural University, Guangdong Province, Guangzhou, 510642, China

    H. -H. Xu

Authors
  1. L. Hu
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  2. G. Hu
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  3. H. -H. Xu
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Hu, L., Hu, G. & Xu, H.H. Kinetic determination of Ag+ using a novel Belousov-Zhabotinskii oscillating system catalyzed by a macrocyclic complex. J Anal Chem 61, 1021–1025 (2006). https://doi.org/10.1134/S1061934806100133

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  • DOI: https://doi.org/10.1134/S1061934806100133

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