Abstract
The effect of humic acid on absorption-release processes in the bottom sediments-Yenisei river water system was studied by dual-column ion chromatography and γ-ray spectrometry. With the use of ion chromatography, it was found that processes related to the absorption of SO 2−4 and Cl− anions by a solid phase with the release of NO −3 , PO 3−4 , and F− to a liquid phase competed in the test systems as the concentration of water-soluble organic carbon (WSOC) was increased. Only the test anions were released in the systems without the introduction of an additional amount of WSOC as humic acid. With the use of γ-ray spectrometry, it was found that the release of 60Co, 152Eu, and 241Am radionuclides to the liquid phase in the systems with added humic acid began much earlier than in the system without the addition of humic acid. In this case, the amount of released radionuclides was greater than the amount of radioisotopes released in the system without the addition of humic acid: ∼25% 241Am, ∼3% 152Eu, and ∼0.8% 60Co in the system with added humic acid or 0.8% 152Eu and <0.1% 60Co in the system without the addition of humic acid. The 241Am radionuclide was not determined in the system without the addition of humic acid. An increase in the concentration of WSOC in the experimental system of bottom sediments-Yenisei river water initiated the release of 60Co, 152Eu, and 241Am anthropogenic radionuclides from bottom sediments because of the formation of soluble complexes capable of migration. An increase in the concentration of WSOC had almost no effect on the release of 40K and 137Cs radionuclides.
Similar content being viewed by others
References
Bolsunovskii, A.Ya., Ermakov, A.I., Myasoedov, B.F., et al., Dokl. Akad. Nauk, 2002, vol. 387, no. 2, p. 233.
Denisova, A.I., et al., Donnye otlozheniya vodokhranilishch i ikh vliyanie na kachestvo vody (Bottom Sediments of Water Reservoirs and Their Effect on Water Quality), Kiev: Naukova Dumka, 1987.
The Chemistry of the Actinide Elements, Katz J.J., Seaborg G.T., and Morss L.R., Eds., New York: Wiley, 1986. Translated under the title Khimiya aktinoidov, Moscow: Mir, 1999, vol. 3.
Chromatography: Fundamentals and Applications of Chromatographic and Electrophoretic Methods, Heftmann, E., Ed., Amsterdam: Elsevier, 1983. Translated under the title Khromatografiya: Prakticheskoe prilozhenie metoda, Moscow: Mir, 1986, vol. 2.
Dolgonosov, A.M., USSR Inventor’s Certificate No. 1 161 513, Byull. Izobret., 1985, no. 22.
Zhang, Y.J. et al., Environ. Pollut., 1997, vol. 96, no. 3, p. 361.
Gu, B. and Chen, J., Geochim. Cosmochim. Acta, 2003, vol. 67, no. 19, p. 3575.
Pavlotskaya, F.I., Migratsiya radioaktivnykh produktov global’nykh vypadenii v pochvakh (Migration of Radioactive Products of Global Fallouts in Soils), Moscow: Atomizdat, 1974.
Molchanova, I.V. and Karavaeva, E.N., Ekologogeokhimicheskie aspekty migratsii radionuklidov v pochvenno-rastitel’nom pokrove (Ecological-Geochemical Aspects of Radionuclide Migration in the Soil-Plant Cover), Yekaterinburg, 2001.
Guminovye veshchestva v biosfere (Humic Substances in the Biosphere), Orlov, D.S., Ed., Moscow: Nauka, 1993.
Choppin, G.R. and Wong, P.J., Aquat. Geochem., 1998, no. 4, p. 77.
Author information
Authors and Affiliations
Additional information
Original Russian Text © L.G. Bondareva, O.P. Kalyakina, A.Ya. Bolsunovskii, 2006, published in Zhurnal Analiticheskoi Khimii, 2006, Vol. 61, No. 4, pp. 388–392.
Rights and permissions
About this article
Cite this article
Bondareva, L.G., Kalyakina, O.P. & Bolsunovskii, A.Y. Effect of humic acid on absorption-release processes in the bottom sediments-Yenisei river water system as studied by dual-column ion chromatography and γ-ray spectrometry. J Anal Chem 61, 354–358 (2006). https://doi.org/10.1134/S1061934806040101
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1134/S1061934806040101