Journal of Analytical Chemistry

, Volume 61, Issue 3, pp 253–257 | Cite as

Gas chromatographic analysis of gas emissions containing impurities of hydrocyanic acid and carbon oxysulfide

  • V. I. Zheivot
  • S. I. Afanas’eva
  • A. V. Simakov


Gas chromatography was used for studying the retention of HCN, COS, H2S, H2O, CO2, CO, and H2 on organic porous polymer sorbents Chromosorb-104 and Hayesep C either unmodified or modified with different amounts of H3PO4. The effect of water on the signal of the thermionic detector was studied, and the conditions of the determination of 6–23 ppm HCN in aqueous solutions were found: column (3 m × 2 mm) with Hayesep C containing 15 wt % H3PO4. A procedure was developed for the determination of 15–1000 ppm COS in the presence of high concentrations (up to 1 vol %) of H2S on a column (3 m × 2 mm) packed with Chromosorb-104 modified with 0.5 wt % H3PO4 with a flame photometric detector (396 nm). A basic scheme was proposed for the gas chromatographic analysis of the products of the catalytic detoxication of gas emissions in the process of coal gasification.


Polymer Chromatography Aqueous Solution Gasification H3PO4 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    Macak, J., Kubat, Ja., Dobal, V., and Mizera, J., J. Chromatogr., 1984, vol. 286, p. 69.Google Scholar
  2. 2.
    Golovnya, R.V., Aerov, A.F., and Garbuzov, V.G., Zh. Anal. Khim., 1981, vol. 36, p. 364.Google Scholar
  3. 3.
    Tesarik, K., Gas-Chromatographie: Vortrage des V Symposium über Gas-Chromatographie in Berlin, 1965, p. 89.Google Scholar
  4. 4.
    Valentour, J.C., Aggarwal, V., and Sunsliine, I., Anal. Chem., 1974, vol. 246, p. 924.Google Scholar
  5. 5.
    Zheivot, V.I., Nikoro, T.A., Sazonova, N.N., and Panina, L.I., Izv. Akad. Nauk, Ser. Khim., 1996, no. 10, p. 2508.Google Scholar
  6. 6.
    Darr, R.W., Capson, T.L., and Hileman, F.D., Anal. Chem., 1980, vol. 252, p. 1379.Google Scholar
  7. 7.
    Donike, M., Z. Naturforsch., 1973, vol. 228, p. 533.Google Scholar
  8. 8.
    Novotny, M. and Muller, A., J. Chromatogr., 1978, vol. 148, p. 211.Google Scholar
  9. 9.
    Hartigan, M.J., Purcell, E., Novotny, M., McConnell, M.L., and Lee, M.L., J. Chromatogr., 1974, vol. 299, p. 339.Google Scholar
  10. 10.
    Di Corcia, A., Samperi, R., Sebastiani, E., and Severini, C., Anal. Chem., 1980, vol. 252, p. 1345.Google Scholar
  11. 11.
    Zheivot, V.I., Zarodysheva, M.V., and Zibarev, P.V., Zh. Anal. Khim., 1996, vol. 51, no. 7, p. 773 [J. Anal. Chem. (Engl. Transl.), vol. 51, no. 7, p. 712].Google Scholar
  12. 12.
    Shalaeva, M.E., Zheivot, V.I., Fenelonov, V.B., Fridman, L.I., and Malakhov, V.V., Zh. Anal. Khim., 1993, vol. 48, p. 1608.Google Scholar

Copyright information

© Pleiades Publishing, Inc. 2006

Authors and Affiliations

  • V. I. Zheivot
    • 1
  • S. I. Afanas’eva
    • 1
  • A. V. Simakov
    • 1
  1. 1.Boreskov Institute of Catalysis, Siberian DivisionRussian Academy of SciencesNovosibirskRussia

Personalised recommendations