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Special Features of the Interaction between Asymmetric Dimethylhydrazine and Thiocontaining Schungite

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Abstract

The interaction between asymmetric dimethylhydrazine and thiocontaining mineral schungite-III has been studied. Chromatography–mass spectrometry has been used to identify alkyl polysulfides as the products of desorption of asymmetric dimethylhydrazine from schungite surface. The interaction of asymmetric dimethylhydrazine with crystalline sulfur has been investigated in a model system. Dimethyl polysulfides, CH3SnCH3; (dimethylamino)methyl polysulfides, (CH3)2NSnCH3; and bis(dimethylamino) polysulfides, (CH3)2NSnN(CH3)2, with 2 ≤ n ≤ 4 have been detected. Gas-chromatographic retention indices have been determined for the products of the interaction of asymmetric dimethylhydrazine with sulfur and the schungite material.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071, Russia

    A. V. Ul’yanov, I. A. Polunina, K. E. Polunin & A. K. Buryak

  2. St. Petersburg State University, St. Petersburg, 198504, Russia

    I. G. Zenkevich

Authors
  1. A. V. Ul’yanov
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  2. I. G. Zenkevich
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  3. I. A. Polunina
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  4. K. E. Polunin
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  5. A. K. Buryak
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Correspondence to A. K. Buryak.

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Original Russian Text © A.V. Ul’yanov, I.G. Zenkevich, I.A. Polunina, K.E. Polunin, A.K. Buryak, 2018, published in Kolloidnyi Zhurnal, 2018, Vol. 80, No. 5, pp. 601–609.

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Ul’yanov, A.V., Zenkevich, I.G., Polunina, I.A. et al. Special Features of the Interaction between Asymmetric Dimethylhydrazine and Thiocontaining Schungite. Colloid J 80, 569–577 (2018). https://doi.org/10.1134/S1061933X18050186

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  • DOI: https://doi.org/10.1134/S1061933X18050186

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