Abstract
The swelling kinetics of polymer gels has been studied in water and aqueous solutions by optical micrometry. Cross-linked hydrophilic polymers based on polystyrene and poly(vinyl alcohol) have been used as gel-forming materials. The effects of the natures of the matrices and polar groups of the polymers and their cross-linking densities and granule sizes, as well as the properties of external phase, on the swelling kinetics of the polymer gels have been investigated. The experimental results have been processed in terms of a heterophase kinetic model. The applicability of the model to describing the behavior of all studied systems has been shown.
Similar content being viewed by others
References
Mushkambarov, N.N., Fizicheskaya i kolloidnaya khimiya (Physical and Colloid Chemistry), Moscow: Geotar-Med, 2001.
Budtova, T. and Navard, P., Macromolecules, 1998, vol. 31, p. 8845.
Tanaka, T. and Fillmore, D.J., J. Chem. Phys., 1979, vol. 70, p. 1214.
Li, Y. and Tanaka, T., J. Chem. Phys., 1990, vol. 92, p. 1365.
Schott, H., J. Macromol. Sci., B, 1992, vol. 31, p. 1.
Karpov, S.I., Matveeva, M.V., and Selemenev, V.F., Russ. J. Phys. Chem., 2001, vol. 75, p. 266.
Tikhonov, N.A., Sorbts. Khromatogr. Protsessy, 2005, vol. 5, p. 779.
Kavalerskaya, N.E., Strusovskaya, N.L., and Ferapontov, N.B., Sorbts. Khromatogr. Protsessy, 2009, vol. 9, p. 796.
Tokmachev, M.G., Ferapontov, N.B., and Gagarin, A.N., J. Math. Chem., 2017, vol. 55, p. 142.
Ferapontov, N.B., Gorshkov, V.I., Parbuzina, L.R., Trobov, H.T., and Strusovskaya, N.L., React. Funct. Polym., 1999, vol. 41, p. 213.
Pitzer, K.S. and Mayorga, G., J. Phys. Chem., 1973, vol. 77, p. 2300.
Kovaleva, S.S. and Ferapontov, N.B., Sorbts. Khromatogr. Protsessy, 2007, vol. 7, p. 883.
Aquilanti, V., Cappelletti, D., and Pirani, F., Chem. Phys., 1996, vol. 209, p. 299.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.N. Gagarin, N.B. Ferapontov, M.G. Tokmachev, 2017, published in Kolloidnyi Zhurnal, 2017, Vol. 79, No. 6, pp. 705–712.
Rights and permissions
About this article
Cite this article
Gagarin, A.N., Ferapontov, N.B. & Tokmachev, M.G. Swelling kinetics of cross-linked polymer gels based on polystyrene and poly(vinyl alcohol) in aqueous solutions of electrolytes and sucrose. Colloid J 79, 740–747 (2017). https://doi.org/10.1134/S1061933X17060096
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061933X17060096