Advertisement

Colloid Journal

, Volume 79, Issue 5, pp 577–587 | Cite as

Computer simulation of structuring in aqueous L-cysteine–silver-nitrate solutions under the action of initiating salt

  • P. O. Baburkin
  • P. V. Komarov
  • M. D. Malyshev
  • S. D. Khizhnyak
  • P. M. Pakhomov
Article
  • 23 Downloads

Abstract

Structural transformations occurring in aqueous L-cysteine−silver-nitrate mixed solutions (CSSs) upon the addition of an initiating salt have been studied within the framework of mesoscopic simulation using the dissipative particle-dynamics method. Diffusion of silver mercaptide clusters is decelerated, and metastable chain aggregates thereof are formed in a narrow concentration range of the salt, probably due to the transition into a gel-like state. The results obtained are in qualitative agreement with the experimentally observed behavior of CSSs.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Brunsveld, L., Folmer, B.J.B., Meijer, E.W., and Sijbesma, R.P., Chem. Rev., 2001, vol. 101, p. 4071.CrossRefGoogle Scholar
  2. 2.
    Estroff, L. and Hamilton, A.D., Chem. Rev., 2004, vol. 104, p. 1201.CrossRefGoogle Scholar
  3. 3.
    Sangeetha, N.M. and Maitra, U., Chem. Soc. Rev., 2005, vol. 34, p. 821.CrossRefGoogle Scholar
  4. 4.
    Peppas, N.A., Hilt, J.Z., Khademhosseini, A., and Langer, R., Adv. Mater. (Weinheim), 2006, vol. 18, p. 1345.CrossRefGoogle Scholar
  5. 5.
    Serpe, M.J. and Craig, S.L., Langmuir, 2007, vol. 23, p. 1626.CrossRefGoogle Scholar
  6. 6.
    Maity, G.C., J. Phys. Sci., 2007, vol. 11, p. 156.Google Scholar
  7. 7.
    Loos, M., Feringa, B.L., and Esch, J.H., Eur. J. Org. Chem., 2005, vol. 2005, p. 3615.CrossRefGoogle Scholar
  8. 8.
    Liu, K., Kang, Y., Wang, Z., and Zhang, X., Adv. Mater. (Weinheim), 2013, vol. 25, p. 5530.CrossRefGoogle Scholar
  9. 9.
    Pakhomov, P.M., Ovchinnikov, M.M., Khizhnyak, S.D., Lavrienko, M.V., Nierling, W., and Lechner, M.D., Colloid J., 2004, vol. 66, p. 65.CrossRefGoogle Scholar
  10. 10.
    Pakhomov, P.M., Ovchinnikov, M.M., Khizhnyak, S.D., Roshchina, O.A., and Komarov, P.V., Vysokomol. Soedin., Ser. A, 2011, vol. 53, p. 1574.Google Scholar
  11. 11.
    Baranova, O.A., Kuz’min, N.I., Samsonova, T.I., Rebetskaya, I.S., Petrova, O.P., Pakhomov, P.M., Khizhnyak, S.D., Komarov, P.V., and Ovchinnikov, M.M., Khim. Volokna, 2011, no. 1, p. 74.Google Scholar
  12. 12.
    Alekseev, V.G., Semenov, A.N., and Pakhomov, P.M., Russ. J. Inorg. Chem., 2012, vol. 57, p. 1041.CrossRefGoogle Scholar
  13. 13.
    Komarov, P.V., Sannikov, I.P., Khizhnyak, S.D., Ovchinnikov, M.M., and Pakhomov, P.M., Nanotechnol. Russ., 2008, vol. 3, nos. 11–12, p. 716.CrossRefGoogle Scholar
  14. 14.
    Komarov, P.V., Alekseev, V.G., Khizhnyak, S.D., Ovchinnikov, M.M., and Pakhomov, P.M., Nanotechnol. Russ., 2010, vol. 5, nos. 3–4, p. 165.CrossRefGoogle Scholar
  15. 15.
    Komarov, P.V., Mikhailov, I.V., Alekseev, V.G., Khizhnyak, S.D., and Pakhomov, P.M., Colloid J., 2011, vol. 71, p. 482.CrossRefGoogle Scholar
  16. 16.
    Komarov, P.V., Mikhailov, I.V., Alekseev, V.G., Khizhnyak, S.D., and Pakhomov, P.M., J. Struct. Chem., 2012, vol. 53, p. 988.CrossRefGoogle Scholar
  17. 17.
    Ovchinnikov, M.M., Perevozova, T.V., Khizhnyak, S.D., and Pakhomov, P.M., in Fizikokhimiya polimerov (Physical Chemistry of Polymers), Tver: Izd. TGU, 2014, no. 20, p. 104.Google Scholar
  18. 18.
    Mandal, S., Gole, A., Lala, N., Gonnade, R., Ganvir, V., and Sastry, M., Langmuir, 2001, vol. 17, p. 6262.CrossRefGoogle Scholar
  19. 19.
    Petean, I., Tomoaia, G.H., Horovitz, O., Mocanu, A., and Tomoaia-Cotisel, M., J. Optoelectron. Adv. M, 2008, vol. 10, p. 2289.Google Scholar
  20. 20.
    Baburkin, P.O., Komarov, P.V., Khizhnyak, S.D., and Pakhomov, P.M., Colloid J., 2015, vol. 77, p. 561.CrossRefGoogle Scholar
  21. 21.
    Pattanayak, S.K. and Chowdhuri, S., J. Mol. Liq., 2012, vol. 172, p. 102.CrossRefGoogle Scholar
  22. 22.
    Pattanayak, S.K. and Chowdhuri, S., J. Theor. Comput. Chem., 2012, vol. 11, p. 361.CrossRefGoogle Scholar
  23. 23.
    Pattanayak, S.K. and Chowdhuri, S., Mol. Phys., 2013, vol. 111, p. 3297.CrossRefGoogle Scholar
  24. 24.
    Manning, G.S., J. Chem. Phys., 1969, vol. 51, p. 924.CrossRefGoogle Scholar
  25. 25.
    Koelman, J.M.V.A. and Hoogerbrugge, P.J., Europhys. Lett., 1993, vol. 21, p. 363.CrossRefGoogle Scholar
  26. 26.
    Espanol, P. and Warren, P., Europhys. Lett., 1995, vol. 30, p. 191.CrossRefGoogle Scholar
  27. 27.
    Groot, R.D. and Madden, T.J., J. Chem. Phys., 1997, vol. 107, p. 4423.CrossRefGoogle Scholar
  28. 28.
    Groot, R.D. and Warren, P.B., J. Chem. Phys., 1998, vol. 108, p. 8713.CrossRefGoogle Scholar
  29. 29.
    Becke, A.D., J. Chem. Phys., 1988, vol. 88, p. 2547.CrossRefGoogle Scholar
  30. 30.
    Lee, C., Yang, W., and Parr, R.G., Phys. Rev. B, 1988, vol. 37, p. 785.CrossRefGoogle Scholar
  31. 31.
    Delley, B., J. Chem. Phys., 1990, vol. 92, p. 508.CrossRefGoogle Scholar
  32. 32.
    Delley, B., J. Chem. Phys., 2000, vol. 113, p. 7756.CrossRefGoogle Scholar
  33. 33.
    Shankar, R., Kolandaivel, P., and Senthilkumar, L., J. Phys. Org. Chem., 2011, vol. 24, p. 553.CrossRefGoogle Scholar
  34. 34.
    Doi, M. and Edwards, S.F., The Theory of Polymer Dynamics, Oxford: Oxford Science, 1986.Google Scholar
  35. 35.
    Miller-Chou, B.A. and Koenig, J.L., Prog. Polym. Sci., 2003, vol. 28, p. 1223.CrossRefGoogle Scholar
  36. 36.
    Allen, M.P. and Tildesley, D.J., Computer Simulation of Liquids, Oxford: Clarendon, 1987.Google Scholar
  37. 37.
    Groot, R.D., J. Chem. Phys., 2001, vol. 118, p. 11265.CrossRefGoogle Scholar
  38. 38.
    www.researchgate.net/project/DPDChem-Software.Google Scholar
  39. 39.
    Berezkin, A.V., Papadakis, C.M., and Potemkin, I.I., Macromolecules, 2016, vol. 49, p. 415.CrossRefGoogle Scholar
  40. 40.
    Poon, W.C.K. and Haw, M.D., Adv. Colloid Interface Sci., 1997, vol. 73, p. 71.CrossRefGoogle Scholar
  41. 41.
    Pedersen, J.S., Adv. Colloid Interface Sci., 1997, vol. 70, p. 171.CrossRefGoogle Scholar
  42. 42.
    Mokshin, A.V., Zabegaev, R.M., and Khusnutdinoff, R.M., Phys. Solid State, 2011, vol. 53, p. 570.CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2017

Authors and Affiliations

  • P. O. Baburkin
    • 1
  • P. V. Komarov
    • 1
    • 2
  • M. D. Malyshev
    • 1
  • S. D. Khizhnyak
    • 1
  • P. M. Pakhomov
    • 1
  1. 1.Tver State UniversityTverRussia
  2. 2.Nesmeyanov Institute of Organoelement CompoundsRussian Academy of SciencesMoscowRussia

Personalised recommendations