Skip to main content
SpringerLink
Log in

On the feasibility of using sodium octyl sulfate micelles for template polymerization of a cationic monomer

  • Published:
Colloid Journal Aims and scope Submit manuscript

Abstract

Spin probe EPR spectroscopy has been employed to study the effect of a cationic monomer, trimethyl(methacryloxyethyl)ammonium methyl sulfate, on the formation, local structure, and dynamics of sodium octyl sulfate micelles in aqueous solutions. It has been established that the monomer does not affect significantly the parameters of probe rotation in micelles of this surfactant, thereby indicating a weak interaction between the studied monomer and surfactant micelles. The absence of a template effect upon monomer polymerization in micellar sodium octyl sulfate solutions, which has been confirmed by unchanged molecular-mass characteristics of obtained polymers, indicates that it is inefficient to use sodium octyl sulfate micelles as a template for radical polymerization of cationic monomers in aqueous media, in contrast to sodium dodecyl sulfate micelles studied previously.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Polowinski, S., Prog. Polym. Sci., 2002, vol. 27, p. 537.

    Article  CAS  Google Scholar 

  2. Papisov, I.M., Polym. Sci., Ser. B, 1997, vol. 39, p. 122.

    Google Scholar 

  3. Tan, Y.Y., Prog. Polym. Sci., 1994, vol. 19, p. 561.

    Article  CAS  Google Scholar 

  4. Shulevich, Yu.V., Navrotskii, A.V., Kovaleva, O.Yu., Navrotskii, V.A., and Novakov, I.A., Russ. J. Appl. Chem., 2005, vol. 78, p. 1185.

    Article  CAS  Google Scholar 

  5. Shulevich, Yu.V., Kovaleva, O.Yu., Navrotskii, A.V., Zakharova, Yu.A., Zezin, A.B., and Novakov, I.A., Polym. Sci., Ser. A, 2007, vol. 49, p. 1284.

    Article  Google Scholar 

  6. Novakov, I.A., Shulevich, Yu.V., Zakharova, Yu.A., Le Tkhi Doan Chang, Dukhanina, E.G., and Navrotskii, A.V., Izv. Ross. Acad. Sci., Ser. Khim., 2015, p. 597.

    Google Scholar 

  7. Shulevich, Y.V., Petzold, G., Navrotskii, A.V., and Novakov, I.A., Colloids Surf. A, 2012, vol. 415, p. 148.

    Article  CAS  Google Scholar 

  8. Petzold, G., Mende, M., and Kochurova, N., Colloids Surf. A, 2007, vol. 298, p. 139.

    Article  CAS  Google Scholar 

  9. Kabanov, V.A., Polym. Sci., Ser. A, 2004, vol. 46, p. 451.

    Google Scholar 

  10. Shulevich, Y.V., Nguyen, T.H., Tutaev, D.S., Navrotskii, A.V., and Novakov, I.A., Sep. Purif. Technol., 2013, vol. 113, p. 18.

    Article  CAS  Google Scholar 

  11. Motyakin, M.V., Shulevich, Yu.V., Zakharova, Yu.A., Vasserman, A.M., Navrotskii, A.V., and Novakov, I.A., Colloid J., 2009, vol. 71, p. 672.

    Article  CAS  Google Scholar 

  12. Shulevich, Yu.V., Motyakin, M.V., Zakharova, Yu.A., Dukhanina, E.G., Vasserman, A.M., Navrotskii, A.V., and Novakov, I.A., Colloid J., 2015, vol. 77, p. 108.

    Article  CAS  Google Scholar 

  13. Pisárcik, M., Devínsky, F., and Pupák, M., Open Chem., 2015, vol. 13, p. 922.

    Article  Google Scholar 

  14. Quina, F.H., Nassar, P.M., Bonilha, J.B.S., and Bales, B.L., J. Phys. Chem., 1995, vol. 99, p. 17028.

    Article  CAS  Google Scholar 

  15. Hassan, P.A., Fritz, G., and Kaler, E.W., J. Colloid Interface Sci., 2003, vol. 257, p. 154.

    Article  CAS  Google Scholar 

  16. Patel, T., Ghosh, G., Aswal, V., and Bahadur, P., Colloid Polym. Sci., 2009, vol. 287, p. 1175.

    Article  CAS  Google Scholar 

  17. Holmberg, K., Jonsson, B., Kronberg, B., and Lindman, B., Surfactants and Polymers in Aqueous Solution, Chichester Wiley, 2002.

    Book  Google Scholar 

  18. Vasserman, A.M., Usp. Khim., 1994, vol. 63, p. 391.

    Google Scholar 

  19. Dzikovski, B.G. and Livshits, V.A., Phys. Chem. Chem. Phys., 2003, vol. 5, p. 5271.

    Article  CAS  Google Scholar 

  20. Budil, D.E., Lee, S., Saxena, S., and Freed, J.H., J. Magn. Reson. A, 1996, vol. 120, p. 155.

    Article  CAS  Google Scholar 

  21. Buchachenko, A.L. and Vasserman, A.M., Stabil’nye radikaly (Stable Radicals), Moscow Khimiya, 1973.

    Google Scholar 

  22. Spin Labeling. Theory and Applications, Berliner, L., Ed., New York Academic, 1976.

  23. Vasserman, A.M. and Kovarskii, A.L., Spinovye metki i zondy v fizikokhimii polimerov (Spin Labels and Probes in Polymer Physics and Chemistry), Moscow Nauka, 1986.

    Google Scholar 

  24. Kovarski, A.L. in Polymer Yearbook, Pethrick, B.A., Ed., New York: Harwood Academic, 1996, vol. 13, p. 113.

    CAS  Google Scholar 

  25. Shulevich, Yu.V., Il’in, S.O., Dukhanina, E.G., Ozerin, A.S., Tutaev, D.S., Navrotskii, A.V., Kulichikhin, V.G., and Novakov, I.A., Bull. Russ. Acad. Sci.: Chem. (in press).

  26. Wasserman, A.M., Kasaikin, V.A., and Timofeev, V.P., Spectrochim. Acta, Part A, 1998, vol. 54, p. 2295.

    Article  Google Scholar 

  27. Aniansson, E.A.G., Wall, S.N., Almgren, M., Hoffmann, H., Kielmann, I., Ulbricht, W., Zana, R., Lang, J., and Tondre, C., J. Phys. Chem., 1976, vol. 80, p. 905.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Volgograd State Technical University, pr. Lenina 28, Volgograd, 400005, Russia

    Yu. V. Shulevich, E. G. Dukhanina, A. V. Navrotskii & I. A. Novakov

  2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia

    M. V. Motyakin & A. M. Wasserman

  3. Department of Chemistry, Moscow State University, Moscow, 119992, Russia

    Yu. A. Zakharova

Authors
  1. Yu. V. Shulevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. V. Motyakin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. M. Wasserman
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yu. A. Zakharova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. G. Dukhanina
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. V. Navrotskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. I. A. Novakov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yu. V. Shulevich.

Additional information

Original Russian Text © Yu.V. Shulevich, M.V. Motyakin, A.M. Wasserman, Yu.A. Zakharova, E.G. Dukhanina, A.V. Navrotskii, I.A. Novakov, 2016, published in Kolloidnyi Zhurnal, 2016, Vol. 78, No. 6, pp. 807–815.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shulevich, Y.V., Motyakin, M.V., Wasserman, A.M. et al. On the feasibility of using sodium octyl sulfate micelles for template polymerization of a cationic monomer. Colloid J 78, 808–815 (2016). https://doi.org/10.1134/S1061933X16060156

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061933X16060156

Search

Navigation