Abstract
The water-in-oil high internal phase emulsions were the subject of the study. The emulsions consisted of a super-cooled aqueous solution of inorganic salt as a dispersed phase and industrial grade oil as a continuous phase. The influence of the industrial grade oil type on a water-in-oil high internal phase emulsion stability was investigated. The stability of emulsions was considered in terms of the crystallization of the dispersed phase droplets (that are super-cooled aqueous salt solution) during ageing. The oils were divided into groups: one that highlighted the effect of oil/aqueous phase interfacial tension and another that investigated the effect of oil viscosity on the emulsion rheological properties and shelf-life. For a given set of experimental conditions the influence of oil viscosity for the emulsion stability as well as the oil/aqueous interfacial tension plays an important role. Within the frames of our experiment it was found that there are oil types characterized by optimal parameters: oil/aqueous phase interfacial tension being in the region of 19–24 mN/m and viscosity close to 3 mPa s; such oils produced the most stable high internal phase emulsions. It was assumed that the oil with optimal parameters kept the critical micelle concentration and surfactant diffusion rate at optimal levels allowing the formation of a strong emulsifier layer at the interface and at the same time creating enough emulsifier micelles in the inter-droplet layer to prevent the droplet crystallization.
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References
Masalova, I. and Malkin, A.Ya., Colloid J., 2007, vol. 69, p. 220.
Masalova, I., Malkin, A.Ya., Ferg, E., Kharatiyan, E., Taylor, M., and Haldenwang, R., J. Rheol., 2006, vol. 50, p. 435.
Tshilumbu, N.N., Ferg, E.E., and Masalova, I., Colloid J., 2010, vol. 72, p. 569.
Drelich, A., Gomez, F., Clausse, D., and Pezron, I., Colloids Surf. A, 2010, vol. 365, p. 171.
Kim, J., Lee, D., Shum, H.C., and Weitz, D.A., Adv. Mater., 2008, vol. 20, p. 3239.
Encyclopedia of Emulsion Technology, Vol. 2, Applications, Ed. by Becher P., New York: Marcel Dekker, 1985.
Encyclopedia of Emulsion Technology, Vol. 3, Basic Theory, Measurements and Applications, Ed. by Becher P., New York: Marcel Dekker, 1988.
Emulsions: Fundamentals and Application in the Petroleum Industry, Ed. by Schramm L.L. Adv. Chem. Ser. 231, Washington, DC: Am. Chem. Soc., 1992.
McClements, D.J., Food Emulsions: Principles, Practice and Technologies, CRC Press, 1999.
Hunter, R.J., Introduction to Modern Colloid Science, Oxford: Oxford Univ. Press, 1993.
Hunter, R.J., Fundamentals of Colloid Science, Vol. 1, Oxford: Clarendon, 1989.
Fingas, M., Fieldhouse, B., and Mullin, J.V., In: Proc. of the 20th Arctic and Marine Oilspill Program (AMOP) Technical Seminar, Environment Canada, 1997, p. 21.
Binks, B.P. and Whitby, C.P., Colloid Surf. A, 2005, vol. 253, p. 105.
Binks, B.P., Curr. Opin. Colloid Interface Sci., 2002, vol. 7, p. 21.
Binks, B.P. and Rodrigues, J.A., Angew. Chem. Int. Ed., 2005, vol. 44, p. 441.
Bobra, M., Fingas, M., and Tennyson, E., Chem. Tech., 1992, vol. 22. p. 236.
Fingas, M., Fieldhouse, B., Bier, I., Conrod, D., and Tennyson, E., In: Proc. of the Workshop on Emulsions, Washington, DC: Marine Spill Response Corporation, 1993, p. 9.
Fingas, M., Fieldhouse, B., Bobra M., and Tennyson, E., In: Proc. of the Workshop on Emulsions, Washington, DC: Marine Spill Response Corporation, 1993, p. 7.
Midmore, B.R., J. Colloid Interface Sci., 1999, vol. 213, p. 352
Weiss, J., Herrmann, N., and McClements, D.J., Langmuir, 1999, vol. 15, p. 6652.
Wagner, C., Z. Elektrochem., 1961, vol. 65, p. 581.
Lifshitz, I.M. and Slyozov, V.V., J. Phys. Chem. Solids, vol. 19, p. 35.
Yu, R.J. and van Scott, E.J., US Patent 4 252 796, 1981.
Yu, R.J. and van Scott, E.J., US Patent 4 252 630, 1981.
Chanamai, R., Horn, G., and McClements, D.J., J. Colloid Interface Sci., 2002, vol. 247, p. 167.
El-Mahrab-Robert, M., Rosilio, V., Bolzinger, M.-A., Chaminade, P., and Grossiord, J.-L., Int. J. Pharm., 2008, vol. 348, p. 89.
Krishnakumar, S. and Somasundaran, P., Langmuir, 1994, vol. 10, p. 2786.
Chatterjee, M., Naskar, M.K., Siladitya, B., and Ganguli, D., J. Mater. Res., 2000, vol. 15, p. 176.
Muto, S. and Meguro, K., Bull. Chem. Soc. Jpn., 1973, vol. 46, p. 1316.
Santhanalakshmi, J. and Imaya, S.I., Proc. Indian Acad. Sci. (Chem. Sci.), 1997, vol. 109, p. 3.
Shiao, S.Y., Patist, A., Free, M.L., Chhabra, V., Huibers, P.D.T, Gregory, A., Patel, S., and Shah, D.O., Colloids Surf. A, 1997, vol. 128, p. 200.
Masalova, I., Foundazi, R., and Malkin, A.Y., Colloids Surf. A., 2011, vol. 375, p. 82.
Henderson, M.J., White, J.W., and Perriman, A., ISIS Experimental Report 14591, 2004.
Reynolds, A.P., McGillivray, D.J., Mata, J.P., Yaron, P.N., and White, J.W., J. Colloid Interface Sci., 2010, vol. 349, p. 552.
Wen, L. and Papadopoulos, K.D., Langmuir, 2000, vol. 16, p. 7615.
Opawale, F.O. and Burgess, D., J. Colloid Interface Sci., 1998, vol. 197, p. 142.
Fingas, M., Fieldhouse, B., and Mullin, J.V., In: Proc. of the 19th Arctic and Marine Oilspill Program (AMOP) Technical Seminar, Environment Canada, 1996, p. 73.
Binks, B.P. and Whitby, C.P., Langmuir, 2004, vol. 20, p. 1130.
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Masalova, I., Kharatyan, E. & Tshilumbu, N.N. Effect of the type of the oil phase on stability of highly concentrated water-in-oil emulsions. Colloid J 75, 579–585 (2013). https://doi.org/10.1134/S1061933X13050098
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DOI: https://doi.org/10.1134/S1061933X13050098