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Association of sodium dodecyl sulfate in aqueous solutions according to chemical shifts in 1H NMR spectra

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Abstract

Proton chemical shifts of different atomic groups in sodium dodecyl sulfate (SDS) have been studied by 1H NMR spectroscopy as functions of surfactant concentration in aqueous solutions. Three surfactant concentration ranges of the chemical shifts have been revealed. The first range corresponds to the premicellar solutions, the second one is in the vicinity of critical micelle concentration (CMC1), and the third range corresponds to high surfactant concentrations, at which intermicellar interactions play a significant role. The parameters of SDS association (CMC1 and CMC2) determined based on the concentration dependences of the chemical shifts are in satisfactory agreement with the data available from the literature. The concept of critical dimerization concentration (CDC) has been introduced for the first concentration range. The values of CDC and dimerization constant K 2 (210 × 60 dm3/mol) have been estimated within the framework of the two-state model.

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Authors and Affiliations

  1. Kazan Institute of Biochemistry and Biophysics, Kazan Scientific Center, Russian Academy of Sciences, ul. Lobachevskogo 2/31, Kazan, 420111, Russia

    B. Z. Idiyatullin & Yu. F. Zuev

  2. Department of Chemistry, St. Petersburg State University, Universitetskii pr. 26, Staryi Peterhof, St. Petersburg, 198504, Russia

    K. S. Potarikina & O. G. Us’yarov

  3. Kazan State Energetic University, ul. Krasnosel’skaya 51, Kazan, 420066, Russia

    O. S. Zueva

Authors
  1. B. Z. Idiyatullin
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  2. K. S. Potarikina
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  3. Yu. F. Zuev
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  4. O. S. Zueva
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  5. O. G. Us’yarov
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Original Russian Text © B.Z. Idiyatullin, K.S. Potarikina, Yu.F. Zuev, O.S. Zueva, O.G. Us’yarov, 2013, published in Kolloidnyi Zhurnal, 2013, Vol. 75, No. 5, pp. 585–590.

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Idiyatullin, B.Z., Potarikina, K.S., Zuev, Y.F. et al. Association of sodium dodecyl sulfate in aqueous solutions according to chemical shifts in 1H NMR spectra. Colloid J 75, 532–537 (2013). https://doi.org/10.1134/S1061933X13050037

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  • DOI: https://doi.org/10.1134/S1061933X13050037

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