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A study of cetylpyridinium cation sorption on Na-vermiculite

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Abstract

The sorption of cetylpyridinium on Na-vermiculite has been studied by the adsorption, calorimetry, and X-ray diffraction methods. The ion-exchange component of cetylpyridinium sorption on Na-vermiculite has been distinguished and analyzed. Variations in the integral heat of ion exchange of cetylpyridinium cations on Na-vermiculite have been determined as depending on the amount of absorbed cetylpyridinium by the calorimetry method. X-ray diffraction analysis of cetylpyridinium-Na-vermiculite organomineral complexes with different contents of exchange cations has been carried out in parallel. The formation of monolayer (interlayer spacing Δd = 20.25 Å) and bilayer (Δd = 37.27 Å) intercalation structures with a tilt angle of cetylpyridinium ions to the silicate basal surface of ≈57° has been revealed.

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Authors and Affiliations

  1. Dumanskii Institute of Colloid and Water Chemistry, National Academy of Sciences of Ukraine, bul’v. Akademika Vernadskogo 42, Kyiv, 03680, Ukraine

    Yu. I. Tarasevich, D. A. Krysenko, V. E. Polyakov & V. Ya. Demchenko

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  1. Yu. I. Tarasevich
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  2. D. A. Krysenko
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  3. V. E. Polyakov
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  4. V. Ya. Demchenko
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Original Russian Text © Yu.I. Tarasevich, D.A. Krysenko, V.E. Polyakov, V.Ya. Demchenko, 2013, published in Kolloidnyi Zhurnal, 2013, Vol. 75, No. 5, pp. 662–666.

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Tarasevich, Y.I., Krysenko, D.A., Polyakov, V.E. et al. A study of cetylpyridinium cation sorption on Na-vermiculite. Colloid J 75, 606–610 (2013). https://doi.org/10.1134/S1061933X13040157

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  • DOI: https://doi.org/10.1134/S1061933X13040157

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