Abstract
A method is proposed for electrostatic functionalization of substrates used to prepare ordered structures composed of closely spaced plasmon-resonant nanoparticles. The method ensures selective deposition of nanoparticles from the bulk of a colloidal system onto the substrates. This method is based on placing a metal nanotemplate of a required configuration at the opposite side of a substrate, with an electric potential being applied to the template. A mathematical model is developed to ensure that the system parameters responsible for the deposition of metal nanoparticles into ordered single-domain structures on the substrate from a bulk sol in a nonuniform electric field generated by the nanotemplate correspond to the real experimental conditions. Since the degree of imperfection of the synthesized chains governs the applicability of these structures to transmission of the optical excitation at the frequency of the surface plasmon of the particles, the dependence of the degree of imperfection on the physicochemical and electrical parameters of the system is studied using the Brownian-dynamics model. The calculations of the spectral and transmission properties of nanowaveguides of this type are exemplified.
Similar content being viewed by others
References
Maier, S.A., Kik, P.G., Atwater, H.A., Meltzer, S., Harel, E., Koel, B.E., and Requicha, A.G., Nature Mater., 2003, vol. 2, p. 229.
Sarychev, A.K. and Shalaev, V.M., Phys. Rep., 2000, vol. 335, p. 275.
Stockman, M.I., Phys. Rev. Lett., 2004, vol. 93, p. 137404.
Engheta, N., Salandrino, A., and Alu, A., Phys. Rev. Lett., 2005, vol. 95, p. 095504.
Podolskiy, V.A., Sarychev, A.K., and Shalaev, V.M., Laser Phys., 2002, vol. 12, p. 292.
Stockman, M.I., Bergman, D.J., and Kobayashi, T., Phys. Rev. B: Condens. Matter, 2004, vol. 69, p. 054202.
Gilani, T.H., Dushkina, N., Freeman, W.L., Numan, M.Z., Talwar, D.N., and Pulsifer, D.P., Opt. Eng., 2010, vol. 49, p. 120503.
Faryad, M., Polo, J.A., and Lakhtakia, A., J. Nanophoton., 2010, vol. 4, p. 043505.
Burin, A.L., Cao, H., Schatz, G.C., and Ratner, M.A., J. Opt. Soc. Am. B, 2004, vol. 21, p. 121.
Quidant, R., Girard, C., Weeber, J.-C., and Dereux, A., Phys. Rev. B: Condens. Matter, 2004, vol. 69, p. 085407.
Simovski, C.R., Viitanen, A.J., and Tretyakov, S.A., Phys. Rev. E: Stat. Phys., Plasmas, Fluids, Relat. Interdiscip. Top., 2005, vol. 72, p. 066606.
Markel, V.A., J. Mod. Opt., 1993, vol. 40, p. 2281.
Zou, S., Janel, N., and Schatz, G.C., J. Chem. Phys., 2004, vol. 120, p. 10871.
Zou, S. and Schatz, G.C., Nanotechnology, 2006, vol. 17, p. 2813.
Harnack, O., Ford, W., Yasuda, A., and Wesels, J., Nano Lett., 2002, vol. 2, p. 919.
Croizier, K., Togan, E., Simsek, E., and Yang, T., Opt. Exp., 2007, vol. 15, p. 17482.
Terekhin, V.V., Dement’eva, O.V., and Rudoy, V.M., Usp. Khim., 2011, vol. 80, p. 477.
Roldughin, V.I., Usp. Khim., 2004, vol. 73, p. 123.
Karpov, S.V., Isaev, I.L., Gavrilyuk, A.P., Grachev, A.S., and Gerasimov, V.S., Kolloidn. Zh., 2009, vol. 71, p. 314.
Shchukin, E.D., Pertsov, A.V., and Amelina, E.A., Kolloidnaya khimiya (Colloid Chemistry), Moscow: Mosk. Gos. Univ., 1982.
Karpov, S.V. and Ershov, A.E., Kolloidn. Zh., 2011, vol. 73, p. 788.
Landau, L.D. and Lifshitz, E.M., Teoriya uprugosti (Theory of Elasticity), Moscow: Nauka, 1987.
Sivukhin, D.V., Obshchii kurs fiziki. T. 3. Elektrichestvo (General Physics. Vol. 3. Electricity), Moscow: Fizmatlit, 1996.
Landau, L.D. and Lifshitz, E.M., Teoriya polya (Field Theory), Moscow: Nauka, 1987.
Karpov, S.V., Isaev, I.L., Gavrilyuk, A.P., Grachev, A.S., and Gerasimov, V.S., Kolloidn. Zh., 2009, vol. 71, p. 330.
Maier, S.A., Kik, P.G., Atwater, H.A., Meltzer, S., Harel, E., Koel, B.E., and Requicha, A.G., Nature Mater., 2003, vol. 2, p. 229.
Markel, V.A., Shalaev, V.M., Stechel, E.B., Kim, W., and Armstrong, R.L., Phys. Rev. B: Condens. Matter, 1996, vol. 53, p. 2425.
Markel, V.A. and Sarychev, A.K., Phys. Rev. B: Condens. Matter, 2007, vol. 75, p. 085426.
Weber, W.H. and Ford, G.W., Phys. Rev. B: Condens. Matter, 2004, vol. 70, p. 125429.
Ruting, F., Phys. Rev. B: Condens. Matter, 2011, vol. 83, p. 115447.
Author information
Authors and Affiliations
Additional information
Original Russian Text © S.V. Karpov, I.L. Rasskazov, 2013, published in Kolloidnyi Zhurnal, 2013, Vol. 75, No. 3, pp. 308–318.
Rights and permissions
About this article
Cite this article
Karpov, S.V., Rasskazov, I.L. Simulation of conditions for fabrication of optical nanowaveguides in the form of chains of spherical metal nanoparticles by electrostatic functionalization of the process substrate. Colloid J 75, 279–288 (2013). https://doi.org/10.1134/S1061933X13030083
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061933X13030083