Abstract
Heating sodium 3-thiophenemalonic acid-noble metal salt aqueous solution at 100°C, without the extra step of introducing other reducing agents and protective agents, results in the formation of well-stable noble metal that includes Au, Ag, Pt, or Pd nanoparticles. As-formed colloidal solutions were characterized by UV-vis absorption spectra and transmission electron microscopy and the nanoparticle formation process was also traced by time-dependent UV-vis absorption spectra.
References
Nanoparticles and Nanostructured Films, Fendler, J.H., Ed., Weinheim: VCH, 1998.
Nanoscale Materials in Chemistry, Klabunde, K.J., Ed., Weinheim: VCH, 2001.
Kiwi, J. and Gratzel, M., J. Am. Chem. Soc., 1979, vol. 101, p. 7214.
Schmid, G., Chem. Rev., 1992, vol. 92, p. 1709.
Brust, M., Walker, M., Bethell, D., et al., J. Chem. Soc., Chem. Commun., 1994, p. 801.
See, for example: Roucoux, A., Schulz, J., and Patin, H., Chem. Rev., 2002, vol. 102, p. 3757 and references cited therein.
Rao, N.R., Kulkarni, G.U., Thomas, P.J., and Edwards, P.P., Chem. Soc. Rev., 2000, vol. 29, p. 27.
Templeton, A.C., Wuelfing, W.P., and Murray, R.W., Acc. Chem. Res., 2000, vol. 33, p. 27.
Maynor, B.W., Filocamo, S.F., Grinstaff, M.W., and Liu, J., J. Am. Chem. Soc., 2002, vol. 124, p. 522.
Youk, J.H., Locklin, J., Xia, C., and Park, M.-K., Langmuir, 2001, vol. 17, p. 4681.
Sun, X., Jiang, X., Dong, S., and Wang, E., Macromol. Rapid Commun., 2003, vol. 24, p. 1024.
Sun, X., Dong, S., and Wang, E., Macromolecules, 2004, vol. 37, p. 7105.
Sun, X., Du, Y., Zhang, L., et al., Anal. Chem., 2006, vol. 78, p. 6674.
Teranishi, T., Hosoe, M., Tanaka, T., and Miyake, M., J. Phys. Chem., B, 1999, vol. 103, p. 3818.
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Luo, Y. A general thermal process for the one-step preparation of well-stable noble metal nanoparticles. Colloid J 70, 669–672 (2008). https://doi.org/10.1134/S1061933X08050189
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DOI: https://doi.org/10.1134/S1061933X08050189