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Interfacial and micellar properties of anionic azo dye-surfactant binary systems

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Abstract

The association of an anionic dye C.I. Reactive Orange 16 (RO16) and different types of surfactants, i.e., anionic surfactant sodium dodecylsulfate, nonionic surfactants poly(oxyethylene) ethers (C m POE10, m = 12, 16, and 18; C12POE n , n = 4, 10, and 23), was investigated using tensiometry in a certain micellar concentration range. RO16 was shown to aggregate in water when its concentration is above the threshold value. The surface tension lowering and critical micellar concentration (CMC) values were interpreted on the same grounds as those for surfactants mixtures. The tensiometric measurements of dye-surfactant systems are carried out as a function of the molar concentration of solution at 25°C. Using Rubingh’s regular solution theory, the values of interaction parameters were found to be negative for all studied binary mixtures. These negative values indicate that there is an attractive interaction of the surfactants in mixed micelles and reflect synergistic behavior of a mixture. In all studied systems, deviations from ideal behavior were observed depending on the type of surfactant. Interaction parameters calculated using regular solution theory are changed from −2.62 to −12.43. The smallest deviation from ideal behavior is obtained for the RO16-C12POE4 mixed system; i.e., in the case when nonionic surfactant has the shortest alkyl chain and the smallest number of ethylene oxide units.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Sciences and Letters, Trakya University, 22030, Trakya, Turkey

    Halide Akbaş & Melike Aydemir

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  1. Halide Akbaş
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  2. Melike Aydemir
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Akbaş, H., Aydemir, M. Interfacial and micellar properties of anionic azo dye-surfactant binary systems. Colloid J 70, 541–548 (2008). https://doi.org/10.1134/S1061933X08050025

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  • DOI: https://doi.org/10.1134/S1061933X08050025

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