Abstract
A “homologous” series of mesoporous silica materials of MSM-41 type whose X-ray characteristics change in proportion to the length of hydrocarbon radical of template surfactant is synthesized using alkylpyridinium halides and sodium silicate. The correspondence principle of the state of the aggregation of micellar templates is used on synthesis for the first time. The influence of colloidochemical properties of surfactant solubilizer and solubilizate on the structuring ability of bitemplate (solubilization) composition is analyzed.
Similar content being viewed by others
References
Kresge, C.T., Leonowicz, M.E., Roth, W.J., et al., Nature (London), 1992, vol. 359, p. 710.
Tanev, P.T. and Pinnavaia, T.J., Science (Washington, D.C.), 1995, vol. 267, p. 865.
Tian, Z.-R., Tong, W., Wang, J.-Y., et al., Science (Washington, D. C.), 1997, vol. 276, p. 926.
Yaroshenko, N.A., Shvets, A.V., Strelko, V.V., and Il’in, V.G., Kolloidn. Zh., 2003, vol. 65, p. 563.
Zhao, D., Feng, J., Huo, Q., et al., Science (Washington, D.C.), 1998, vol. 279, p. 548.
Lettow, J.S., Han, Y.J., Schmidt-Winkel, P., et al., Langmuir, 2000, vol. 16, p. 8291.
Kipkemboi, P., Fogden, A., Alfredsson, V., and Flodström, K., Langmuir, 2001, vol. 17, p. 5398.
Tolbert, S.H., Landry, C.C., Stucky, G.D., et al., Chem. Mater., 2001, vol. 13, p. 2247.
Shvets, A.V., Kas’yan, N.V., Bezuglaya, E.M., et al., Teor. Eksp. Khim., 2001, vol. 37, p. 372.
Yaroshenko, N.A., and Il’in, V.G., Zh. Prikl. Khim. (S.-Peterburg), 2004, vol. 77, p. 1787.
Kryukova, G.N., Kasaikin, V.A., Markina, Z.N., and Sineva, A.V., Kolloidn. Zh., 1981, vol. 43, p. 660.
Sonwane, C.G., Bathia, S.K., and Calos, N., Ind. Eng. Chem. Res., 1998, vol. 37, p. 2271.
Berenguer-Murcia, A., Garcia-Martinez, J., Cazorla-Amoros, D., et al., Abstracts of Papers, 6 Int. Symp. on the Characterization of Porous Solids, Alicante, Spain, 2002, p. 21.
Stewart, J.J.P., J. Comput. Chem., 1989, vol. 10, p. 209.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © N.A. Yaroshenko, V.V. Strelko, V.G. Il’in, 2008, published in Kolloidnyi Zhurnal, 2008, Vol. 70, No. 3, pp. 420–428.
Rights and permissions
About this article
Cite this article
Yaroshenko, N.A., Strelko, V.V. & Il’in, V.G. Effect of colloidochemical properties of template on the formation of the structure of mesoporous silica molecular sieves. Colloid J 70, 384–391 (2008). https://doi.org/10.1134/S1061933X08030186
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1061933X08030186