Skip to main content

Aggregation and catalysis in a nonionic surfactant-polyethylenimine-chloroform system

Colloid Journal volume 68, pages 533–540 (2006)Cite this article

Abstract

The formation of polymer-colloid complexes (PCCs) of hydroxybenzylated polyethylenimines (PEIs) with poly(ethylene glycol-600) monolaurate (PM) in chloroform is established through dielcometric titration, light scattering, and viscometry. The effect of PCC on the PEI reactivity in phosphorylation with 4-nitrophenyl bis(chloromethyl)phosphinate is studied with spectrophotometry. It is found that the character of aggregates and the degree of their influence depend on the PM-to-PEI concentration ratio, polymer structure, and reaction temperature.

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

USD 39.95

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

References

  1. Cacciapaglia, R. and Mandolini, L., in Calixarenes in Action, Mandolini, L. and Ungano, R., Eds., London: Imperial College Press, 2000, p. 241.

    Google Scholar 

  2. Karakhanov, E.A., Kardasheva, Y.S., Maximov, A.L., et al., Polym. Adv. Technol., 2001, vol. 12, nos. 3–4, p. 161.

    Article  CAS  Google Scholar 

  3. Zhil’tsova, E.P., Kudryavtseva, L.A., Timosheva, A.P., et al., Zh. Obshch. Khim., 2004, vol. 74, no. 4, p. 687.

    Google Scholar 

  4. Reetz, M.T. and Waldvogel, S.R., Angew. Chem., Int. Ed. Engl., 1997, vol. 36, no. 8, p. 865.

    Article  CAS  Google Scholar 

  5. Wenz, G., Angew. Chem., Int. Ed. Engl., 2003, vol. 33, no. 8, p. 803.

    Article  Google Scholar 

  6. Roberta, C., Di Stefano, D.S., and Luigi, M., J. Am. Chem. Soc., 2003, vol. 125, no. 8, p. 2224.

    Article  Google Scholar 

  7. Janeczek, H. and Jedlinski, Z., Polymer, 2002, vol. 43, no. 25, p. 7219.

    Article  CAS  Google Scholar 

  8. Ooe, M., Murata, M., Mizugaki, T., et al., J. Am. Chem. Soc., 2004, vol. 126, no. 6, p. 1604.

    CAS  Google Scholar 

  9. De Groot, D., De Waal, B.F.M., Reek, J.N.H., et al., J. Am. Chem. Soc., 2001, vol. 123, no. 35, p. 8453.

    Article  Google Scholar 

  10. Therrien, B., Vieille-Petit, L., Tschan, M., et al., Chimia, 2003, vol. 57, no. 10, p. 593.

    Article  CAS  Google Scholar 

  11. Owsik, I.A. and Kolarz, B.N., Wiad. Chem., 2003, vol. 57, no. 1, p. 21.

    CAS  Google Scholar 

  12. Zakharova, L.Ya., Valeeva, F.G., Kudryavtsev, D.B., et al., Izv. Ross. Akad. Nauk, Ser. Khim., 2005, no. 3, p. 630.

  13. Zakharova, L.Ya., Valeeva, F.G., Kudryavtsev, D.B., et al., Kinet. Katal., 2003, vol. 44, no. 4, p. 599.

    Google Scholar 

  14. Brackman, J.C. and Engberts, J.B.F.N., Chem. Soc. Rev., 1993, vol. 22, no. 2, p. 85.

    Article  CAS  Google Scholar 

  15. Kabanov, V.A., Zezin, A.B., Kasaikin, V.A., et al., Usp. Khim., 1991, vol. 60, no. 3, p. 595.

    CAS  Google Scholar 

  16. Kotz, J., Kosmella, S., and Beitz, T., Prog. Polym. Sci., 2001, vol. 26, no. 8, p. 1199.

    Article  CAS  Google Scholar 

  17. Thunemann, A.F., Prog. Polym. Sci., 2002, vol. 27, no. 8, p. 1473.

    Article  CAS  Google Scholar 

  18. Bakeev, K.N., Chugunov, S.A., Larina, T.A., et al., Vysokomol. Soedin., Ser. A, 1994, vol. 36, no. 2, p. 247.

    CAS  Google Scholar 

  19. Lezov, A.V., Mel’nikov, A.B., Polushina, G.E., et al., Vysokomol. Soedin., Ser. A, 2001, vol. 43, no. 9, p. 1481.

    CAS  Google Scholar 

  20. Lezov, A.V., Mel’nikov, A.B., Polushina, G.E., et al., Vysokomol. Soedin., Ser. A, 2002, vol. 44, no. 7, p. 1137.

    CAS  Google Scholar 

  21. Zhil’tsova, E.P., Kudryavtsev, D.B., Zakharova, L.Ya., et al., Zh. Fiz. Khim., 2002, vol. 76, no. 11, p. 2037.

    CAS  Google Scholar 

  22. Kudryavtsev, D.B., Zakharova, L.Ya., and Kudryavtseva, L.A., Zh. Fiz. Khim., 2003, vol. 77, no. 3, p. 443.

    CAS  Google Scholar 

  23. Bel’skii, V.E., Novikova, L.S., Kudryavtseva, L.A., and Ivanov, B.E., Zh. Obshch. Khim., 1978, vol. 48, no. 7, p. 1512.

    CAS  Google Scholar 

  24. Arcelli, A. and Concilio, C., J. Chem. Soc., Perkin Trans. 2, 1983, no. 9, p. 1327.

  25. Gordon, A. and Ford, R., The Chemist’s Companion: A Handbook of Practical Data, Techniques and References, New York: Wiley, 1972.

    Google Scholar 

  26. Tishkova, E.P. and Kudryavtseva, L.A., Izv. Ross. Akad. Nauk, Ser. Khim., 1998, no. 2, p. 280.

  27. Gur’yanova, E.N., Gol’dshtein, I.P., and Room, I.P., Donorno-aktseptornaya svyaz’ (Donor-Acceptor Bond), Moscow: Khimiya, 1973.

    Google Scholar 

  28. Nigmatullin, R.Sh., Vyaselev, M.R., and Shatunov, V.S., Zavod. Lab., 1964, vol. 30, no. 4, p. 500.

    CAS  Google Scholar 

  29. Zhil’tsova, E.P., Garifullina, G.A., Timosheva, A.P., et al., Abstracts of Papers, 4 Mezhdunarodnaya konferentsiya “Khimiya vysokoorganizovannykh veshchestv i nauchnye osnovy nanotekhnologii” (4 Int. Conf. “Chemistry of High-Organized Substances and Fundamentals of Nanotechnology”), St. Petersburg: S.-Peterb. Gos. Univ., 2004, p. 192.

    Google Scholar 

  30. Zhil’tsova, E.P., Timosheva, A.P., Shagidullina, R.A., et al., Zh. Obshch. Khim., 2001, vol. 71, no. 3, p. 419.

    Google Scholar 

  31. Vasilescu, M., Anghel, D.F., Almgren, M., et al., Langmuir, 1997, vol. 13, no. 26, p. 6951.

    Article  CAS  Google Scholar 

  32. Anghel, D.F., Saito, S., Baran, A., and Iovescu, A., Langmuir, 1998, vol. 14, no. 19, p. 5342.

    Article  CAS  Google Scholar 

  33. Bilalov, A.V., Manyurov, I.R., Tret’yakova, A.Ya., and Barabanov, V.P., Vysokomol. Soedin., Ser. A, 1996, vol. 38, no. 1, p. 94.

    CAS  Google Scholar 

  34. Garifullina, G.A. and Zhil’tsova, E.P., Zhidk. Krist. Ikh Prakt. Ispol’zovanie, 2004, no. 2, p. 23.

  35. Berezin, I.V., Martinek, K., and Yatsimirskii, A.K., Usp. Khim., 1973, vol. 42, no. 10, p. 1729.

    CAS  Google Scholar 

  36. Lawin, L.R., Fife, W.K., and Tian, C.X., Langmuir, 2000, vol. 16, no. 8, p. 3883.

    Article  Google Scholar 

  37. Fendler, E. and Fendler, J., in Advances in Physical Organic Chemistry, Gold, V., Ed., New York: Academic, 1970.

    Google Scholar 

  38. Loshadkin, N.A., Toksichnye efiry kislot fosfora (Toxic Esters of Phosphorus Acids), Moscow: Mir, 1964.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Akademika Arbuzova 8, Kazan, 420088, Tatarstan, Russia

    G. A. Gainanova, E. P. Zhil’tsova, L. A. Kudryavtseva, S. S. Lukashenko, A. P. Timosheva, V. E. Kataev & A. I. Konovalov

Authors
  1. G. A. Gainanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. P. Zhil’tsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. A. Kudryavtseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. S. Lukashenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. P. Timosheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. E. Kataev
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. I. Konovalov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © G.A. Gainanova, E.P. Zhil’tsova, L.A. Kudryavtseva, S.S. Lukashenko, A.P. Timosheva, V.E. Kataev, A.I. Konovalov, 2006, published in Kolloidnyi Zhurnal, 2006, Vol. 68, No. 5, pp. 585–592.

Rights and permissions

Reprints and Permissions

About this article

Cite this article

Gainanova, G.A., Zhil’tsova, E.P., Kudryavtseva, L.A. et al. Aggregation and catalysis in a nonionic surfactant-polyethylenimine-chloroform system. Colloid J 68, 533–540 (2006). https://doi.org/10.1134/S1061933X06050024

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061933X06050024

Keywords

  • Surfactant
  • Surfactant Concentration
  • Colloid Journal
  • Apparent Rate Constant
  • Micellar Phase