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Aggregation and catalysis in a nonionic surfactant-polyethylenimine-chloroform system

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Abstract

The formation of polymer-colloid complexes (PCCs) of hydroxybenzylated polyethylenimines (PEIs) with poly(ethylene glycol-600) monolaurate (PM) in chloroform is established through dielcometric titration, light scattering, and viscometry. The effect of PCC on the PEI reactivity in phosphorylation with 4-nitrophenyl bis(chloromethyl)phosphinate is studied with spectrophotometry. It is found that the character of aggregates and the degree of their influence depend on the PM-to-PEI concentration ratio, polymer structure, and reaction temperature.

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Akademika Arbuzova 8, Kazan, 420088, Tatarstan, Russia

    G. A. Gainanova, E. P. Zhil’tsova, L. A. Kudryavtseva, S. S. Lukashenko, A. P. Timosheva, V. E. Kataev & A. I. Konovalov

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  1. G. A. Gainanova
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  2. E. P. Zhil’tsova
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  3. L. A. Kudryavtseva
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  4. S. S. Lukashenko
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  5. A. P. Timosheva
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  6. V. E. Kataev
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  7. A. I. Konovalov
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Original Russian Text © G.A. Gainanova, E.P. Zhil’tsova, L.A. Kudryavtseva, S.S. Lukashenko, A.P. Timosheva, V.E. Kataev, A.I. Konovalov, 2006, published in Kolloidnyi Zhurnal, 2006, Vol. 68, No. 5, pp. 585–592.

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Gainanova, G.A., Zhil’tsova, E.P., Kudryavtseva, L.A. et al. Aggregation and catalysis in a nonionic surfactant-polyethylenimine-chloroform system. Colloid J 68, 533–540 (2006). https://doi.org/10.1134/S1061933X06050024

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  • DOI: https://doi.org/10.1134/S1061933X06050024

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