Abstract
High residual porosity in superplastically deformed brass carries the risk of reducing the mechanical properties. Multicomponent brasses demonstrate lower residual porosity, associated with a lower grain size and more effective accommodation of grain boundary sliding. In this paper, the microstructural evolution of the surface and bulk structure of the binary brass and aluminum-bearing brass during steady-state superplastic deformation is compared. After superplastic deformation, dislocation pile-ups and dislocation walls are revealed in the α grains of both alloys, indicating the activation of the dislocation slip/creep mechanism. It is shown that aluminum reduces the contribution of grain boundary sliding along the phase boundaries from ~75 to ~30% and causes strain localization in the β-phase region with the formation of ultrafine grains with the size below ~300 nm as a result of dynamic recrystallization. Alloying with 0.4% Al reduces the flow stress by 20%, increases the relative elongation by a factor of 1.5, and decreases the fraction of residual porosity by a factor of 3. This leads to a much lower loss of room temperature strength in superplastically deformed alloys.
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REFERENCES
Liu, F.C. and Ma, Z.Y., Superplasticity Governed by Effective Grain Size and Its Distribution in Fine-Grained Aluminum Alloys, Mater. Sci. Eng. A, 2011, vol. 530, pp. 548–558. https://doi.org/10.1016/j.msea.2011.10.018
Langdon, T.G., Seventy-Five Years of Superplasticity: Historic Developments and New Opportunities, J. Mater. Sci., 2009, vol. 44, no. 22, pp. 5998–6010. https://doi.org/10.1007/s10853-009-3780-5
Yakovtseva, O.A., Mikhailovskaya, A.V., Kotov, A.D., Mamzurina, O.I., and Portnoy, V.K., Effect of the Strain and Strain Rate on Microstructure Evolution and Superplastic Deformation Mechanisms, Phys. Met. Metallogr., 2019, vol. 120, no. 1, pp. 87–94. https://doi.org/10.1134/S0031918X18110224
Humphries, C.W. and Ridley, N., Cavitation during the Superplastic Deformation of an α/β Brass, J. Mater. Sci., 1978, vol. 13, no. 11, pp. 2477–2482. https://doi.org/10.1007/BF00808064
Ridley, N., Patterson, W.J.D., and Livesey, D.W., Superplastic Flow and Cavitation Behaviour in alpha/ beta Copper Alloys during Compressive Deformation, in Energy Technology Review, Pergamon Press Ltd., 1980, pp. 393–398. https://doi.org/10.1016/b978-1-4832-8412-5.50071-0
Pollatsek, A., Lima, S., and Well, A.D., Normalization of Cavitation in Superplastic α/β Brasses with Different Phase Proportions, J. Scripta Metall., 1981, vol. 15, pp. 895–898. https://doi.org/10.1007/BF00305621
Blandin, J.J., Hong, B., Varloteaux, A., Suery, M., and L'Esperance, G., Effect of the Nature of Grain Boundary Regions on Cavitation of a Superplastically Deformed Aluminium Alloy, Acta Mater., 1996, vol. 44, no. 6, pp. 2317–2326. https://doi.org/10.1016/1359-6454(95)00340-1
Blandin, J.J., Superplasticity of Metallic Alloys: Some Current Findings and Open Questions, Mater. Sci. Forum, 2016, vol. 838–839, pp. 13–22. https://doi.org/10.4028/www.scientific.net/MSF.838-839.13
Sotoudeh, K. and Bate, P.S., Diffusion Creep and Superplasticity in Aluminium Alloys, Acta Mater., 2010, vol. 58, no. 6, pp. 1909–1920. https://doi.org/10.1016/j.actamat.2009.11.034
Chen, C.L. and Tan, M.J., Effect of Grain Boundary Character Distribution (GBCD) on the Cavitation Behaviour during Superplastic Deformation of Al 7475, Mater. Sci. Eng. A, 2002, vol. 338, no. 1–2, pp. 243–252. https://doi.org/10.1016/S0921-5093(02)00083-7
Mikhaylovskaya, A.V., Mosleh, A.O., Mestre-Rinn, P., Kotov, A.D., Sitkina, M.N., Bazlov, A.I., and Louzguine-Luzgin, D.V., High-Strength Titanium-Based Alloy for Low-Temperature Superplastic Forming, Metall. Mater. Trans. A. Phys. Metall. Mater. Sci., 2020, vol. 52, no. 1, pp. 293–302.
Roy, S. and Suwas, S., Enhanced Superplasticity for (α + β)-Hot Rolled Ti-6Al-4V-0.1B Alloy by Means of Dynamic Globularization, Mater. Des., 2014, vol. 58, pp. 52–64. https://doi.org/10.1016/j.matdes.2014.01.033
Alabort, E., Kontis, P., Barba, D., Dragnevski, K., and Reed, R.C., On the Mechanisms of Superplasticity in Ti-6Al-4V, Acta Mater., 2016, vol. 105, pp. 449–463. https://doi.org/10.1016/j.actamat.2015.12.003
Sagat, S. and Taplin, D.M.R., Fracture of a Superplastic Ternary Brass, Acta Metall., 1976, vol. 24, no. 4, pp. 307–315. https://doi.org/10.1016/0001-6160(76)90005-5
Campbell, J., Cavitation during Superplastic Forming, Materials (Basel), 2011, vol. 4, no. 7, pp. 1271–1286. https://doi.org/10.3390/ma4071271
Langdon, T.G., Grain Boundary Sliding Revisited: Developments in Sliding over Four Decades, J. Mater. Sci., 2006, vol. 41, no. 3, pp. 597–609. https://doi.org/10.1007/s10853-006-6476-0
Li, H., Liu, X., Sun, Q., Ye, L., and Zhang, X., Superplastic Deformation Mechanisms in Fine-Grained 2050 Al-Cu-Li Alloys, Materials (Basel), 2020, vol. 13, no. 12, p. 2705. https://doi.org/10.3390/ma13122705
Korznikova, G.F., Khalikova, G.R., Mironov, S.Yu., Aletdinov, A.F., Korznikova, E.A., Konkova, T.N., and Myshlyaev, M.M., Superplastic Behavior of Fine-Grained Al-Mg-Li Alloy, Phys. Mesomech., 2022, vol. 25, no. 4, pp. 318–325. https://doi.org/10.1134/S1029959922040051
Chokshi, A.H., Grain Boundary Processes in Strengthening, Weakening, and Superplasticity, Adv. Eng. Mater., 2020, vol. 22, no. 1, pp. 1–9. https://doi.org/10.1002/adem.201900748
Masuda, H. and Sato, E., Diffusional and Dislocation Accommodation Mechanisms in Superplastic Materials, Acta Mater., 2020, vol. 197, pp. 235–252. https://doi.org/10.1016/j.actamat.2020.07.042
Blackwell, P.L. and Bate, P.S., Superplastic Deformation without Relative Grain Translation?, Mater. Sci. Forum, 1999, vol. 304–306, pp. 189–194. https://doi.org/10.4028/www.scientific.net/msf.304-306.189
Langdon, T.G., A Lifetime of Research in Creep, Superplasticity, and Ultrafine-Grained Materials, Adv. Eng. Mater., 2020, vol. 22, no. 1, pp. 1–8. https://doi.org/10.1002/adem.201900442
Rust, M.A. and Todd, R.I., Surface Studies of Region II Superplasticity of AA5083 in Shear: Confirmation of Diffusion Creep, Grain Neighbour Switching and Absence of Dislocation Activity, Acta Mater., 2011, vol. 59, no. 13, pp. 5159–5170. https://doi.org/10.1016/j.actamat.2011.04.051
Chandra, T., Jonas, J.J., and Taplin, D.M.R., Note on the Relationship between Cavitation and Ductility in Microduplex Brasses, J. Aust. Inst. Met. Incl. Met. Forum, 1975, vol. 20, no. 4, pp. 220–225.
Hong, H.L., Wang, Q., Dong, C., and Liaw, P.K., Understanding the Cu-Zn Brass Alloys Using a Short-Range-Order Cluster Model: Significance of Specific Compositions of Industrial Alloys, Sci. Rep., 2015, vol. 4, no. 1, p. 7065. https://doi.org/10.1038/srep07065
Moshkovich, A., Perfilyev, V., Lapsker, I., and Rapoport, L., Friction, Wear and Plastic Deformation of Cu and α/β Brass under Lubrication Conditions, Wear, 2014, vol. 320, no. 1, pp. 34–40. https://doi.org/10.1016/j.wear.2014.08.016
Smirnov, S.V., Pugacheva, N.B., Myasnikova, M.V., Matafonov, P.P., and Polkovnikova, T.V., Micromechanics of Fracture and Deformation of Brass, Fiz. Mesomeh., 2004, vol. 7, spec. iss., part 1, pp. 165–168. https://doi.org/10.24411/1683-805X-2004-00230
Chen, C.L. and Tan, M.J., Cavity Growth and Filament Formation of Superplastically Deformed Al 7475 Alloy, Mater. Sci. Eng. A, 2001, vol. 298, no. 1–2, pp. 235–244. https://doi.org/10.1016/s0928-4931(00)00193-4
Mabao, L. and Shichun, W., A Model for Cavity Growth in a Superplastic Material during Uniaxial Tension, J. Mater. Process. Tech., 1994, vol. 41, no. 1, pp. 115–124. https://doi.org/10.1016/0924-0136(94)90180-5
Zelin, M.G., Processes of Microstructural Evolution during Superplastic Deformation, Mater. Charact., 1996, vol. 37, no. 5, pp. 311–329. https://doi.org/10.1016/S1044-5803(96)00127-1
Ma, Z.Y. and Mishra, R.S., Cavitation in Superplastic 7075 Al Alloys Prepared Via Friction Stir Processing, Acta Mater., 2003, vol. 51, no. 12, pp. 3551–3569. https://doi.org/10.1016/S1359-6454(03)00173-3
Ragab, A.R., Modeling of the Effect of Cavitation on Tensile Failure of Superplastic Alloys, Mater. Sci. Eng. A, 2007, vol. 454–455, pp. 614–622. https://doi.org/10.1016/j.msea.2006.11.093
Yakovtseva, O.A., Mikhaylovskaya, A.V., Pozdniakov, A.V., Kotov, A.D., and Portnoy, V.K., Superplastic Deformation Behaviour of Aluminium Containing Brasses, Mater. Sci. Eng. A, 2016, vol. 674, pp. 135–143. https://doi.org/10.1016/j.msea.2016.07.053
Farabi, E., Zarei-Hanzaki, A., Pishbin, M.H., and Moallemi, M., Rationalization of Duplex Brass Hot Deformation Behavior: The Role of Microstructural Components, Mater. Sci. Eng. A, 2015, vol. 641, pp. 360–368. https://doi.org/10.1016/j.msea.2015.06.042
Yakovtseva, O.A., Mikhailovskaya, A.V., Kotov, A.D., and Portnoi, V.K., Effect of Alloying on Superplasticity of Two-Phase Brasses, Phys. Met. Metallogr., 2016, vol. 117, no. 7, pp. 742–748. https://doi.org/10.1134/S0031918X16070188
Chuvil'deev, V.N., Gryaznov, M.Y., Shotin, S.V., Kopylov, V.I., Nokhrin, A.V., Likhnitskii, C.V., Murashov, A.A., Bobrov, A.A., Tabachkova, N.Y., and Pirozhnikova, O.E., Investigation of Superplasticity and Dynamic Grain Growth in Ultrafine-Grained Al–0.5%Mg–Sc Alloys, J. Alloys Compd, 2021, vol. 877, p. 160099. https://doi.org/10.1016/j.jallcom.2021.160099
Raj, R. and Ashby, M.F., Grain Boundary Sliding, and the Effects of Particles on Its Rate, Metall. Trans., 1972, vol. 3, no. 7, pp. 1937–1942. https://doi.org/10.1007/BF02642582
Yakovtseva, O.A., Sitkina, M.N., Kotov, A.D., Rofman, O.V., and Mikhailovskaya, A.V., Experimental Study of the Superplastic Deformation Mechanisms of High-Strength Aluminum-Based Alloy, Mater. Sci. Eng. A, 2020, vol. 788, p. 139639. https://doi.org/10.1016/j.msea.2020.139639
Sherby, O.D. and Taleff, E.M., Influence of Grain Size, Solute Atoms and Second-Phase Particles on Creep Behavior of Polycrystalline Solids, Mater. Sci. Eng. A, 2002, vol. 322, no. 1–2, pp. 89–99. https://doi.org/10.1016/S0921-5093(01)01121-2
Yakovtseva, O.A., Mikhaylovskaya, A.V., Irzhak, A.V., Kotov, A.D., and Medvedeva, S.V., Comparison of Contributions of the Mechanisms of the Superplastic Deformation of Binary and Multicomponent Brasses, Phys. Met. Metallogr., 2020, vol. 121, no. 6, pp. 582–589. https://doi.org/10.1134/S0031918X20060186
Higashi, K., Ohnishi, T., and Nakatani, Y., Superplastic Behavior of Commercial Aluminum Bronze, Scripta Metall., 1985, vol. 19, no. 7, pp. 821–823.
Mikhaylovskaya, A.V., Yakovtseva, O.A., Tabachkova, N.Yu., and Langdon, T.G., Formation of Ultrafine Grains and Twins in the β-Phase during Superplastic Deformation of Two-Phase Brasses, Scripta Mater., 2022, vol. 218, p. 114804. https://doi.org/10.1016/j.scriptamat.2022.114804
Mikhaylovskaya, A.V., Yakovtseva, O.A., Sitkina, M.N., Krymskiy, S.V., and Portnoy, V.K., Comparison between Superplastic Deformation Mechanisms at Primary and Steady Stages of the Fine Grain AA7475 Aluminium Alloy, Mater. Sci. Eng. A, 2018, vol. 718, pp. 277–286. https://doi.org/10.1016/j.msea.2018.01.102
Hsiao, I.C. and Huang, J.C., Deformation Mechanisms during Low- and High-Temperature Superplasticity in 5083 Al-Mg Alloy, Metall. Mater. Trans. A. Phys. Metall. Mater. Sci., 2002, vol. 33, pp. 1373–1384.
Liu, X., Ye, L., Tang, J., Shan, Z., Ke, B., Dong, Y., and Chen, J., Superplastic Deformation Mechanisms of an Al–Mg–Li Alloy with Banded Microstructures, Mater. Sci. Eng. A, 2021, vol. 805, p. 140545.
Mikhaylovskaya, A.V., Yakovtseva, O.A., and Irzhak, A.V., The Role of Grain Boundary Sliding and Intragranular Deformation Mechanisms for a Steady Stage of Superplastic Flow for Al–Mg-Based Alloys, Mater. Sci. Eng. A, 2022, vol. 833, p. 142524.
Portnoy, V.K. and Novikov, I.I., Evaluation of Grain Boundary Sliding Contribution to the Total Strain during Superplastic Deformation, Scripta Mater., 1998, vol. 40, no. 1, pp. 39–43. https://doi.org/10.1016/S1359-6462(98)00394-7
Mikhaylovskaya, A.V., Yakovtseva, O.A., Mochugovskiy, A.G., Cifre, J., and Golovin, I.S., Influence of Minor Zn Additions on Grain Boundary Anelasticity, Grain Boundary Sliding, and Superplasticity of Al-Mg-Based Alloys, J. Alloys Compd, 2022, vol. 926, p. 166785.
Funding
The work was carried out under the grant of the President of the Russian Federation for leading scientific schools NSh-1752.2022.4. The TEM study of the structure was performed using the equipment of the Materials Science and Metallurgy CUC funded by the Ministry of Education and Science of the Russian Federation under the Government statement of work No. 075-15-2021-696.
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Yakovtseva, O.A., Kaboyi, P.K., Irzhak, A.V. et al. Influence of Minor Aluminum Addition on the Superplastic Deformation of a Microduplex Cu-Zn Alloy. Phys Mesomech 26, 533–541 (2023). https://doi.org/10.1134/S1029959923050065
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DOI: https://doi.org/10.1134/S1029959923050065