Abstract
For the first time, the results of investigations of ion transport phenomena in high-temperature modifications of single-crystalline copper selenide are presented depending on the temperature and the composition within the homogeneity region as well as the effect of the degree of perfection of single-crystalline samples on the ion transfer. It is found that the activation energy estimated from the temperature dependences of the ionic conductivity for perfect single crystals is significantly higher than in polycrystalline samples and increases with a deviation from stoichiometry. For single crystals, lower values of ionic conductivity are observed. The ionic conductivity in the temperature range of 573–723 K is 1.5–2 times higher for polycrystalline samples than for single crystals.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS1028335820080017/MediaObjects/11446_2020_1235_Fig1_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS1028335820080017/MediaObjects/11446_2020_1235_Fig2_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS1028335820080017/MediaObjects/11446_2020_1235_Fig3_HTML.gif)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1134%2FS1028335820080017/MediaObjects/11446_2020_1235_Fig4_HTML.gif)
Similar content being viewed by others
REFERENCES
C. Wagner, J. Chem. Phys. 21 (10), 1819–1827 (1953).
R. D. Heuding, Can. J. Chem. 44, 1233–1236 (1966).
G. N. Asylgushina, N. N. Bikkulova, S. G. Titova, and D. I. Kochubey, Nucl. Instrum. Methods Phys. Res., Sect. A 543 (1), 194–195 (2005). https://doi.org/10.1016/j.nima.2005.01.170
N. N. Bikkulova, Yu. M. Stepanov, L. V. Bikkulova, A. R. Kurbangulov, A. Kh. Kutov, and R. F. Karagulov, Crystallogr. Rep. 58, 622–627 (2013). https://doi.org/10.1134/S1063774513040068
Y. Okada, T. Ohtani, Y. Yokota, Y. Tachibana, and K. Morishige, J. Electron Microsc. 49 (1), 25–29 (2000). https://doi.org/10.1093/oxfordjournals.jmicro.a023788
H. Liu, X. Shi, F. Xu, L. Zhang, W. Zhang, L. Chen, Q. Li, C. Uher, T. Day, and G. J. Snyder, Nat. Mater. 11 (5), 422–425 (2012). https://doi.org/10.1038/nmat3273
S. A. Danilkin, A. N. Skomorochov, A. Hoser, H. Fuess, V. Rajevas, and N. N. Bickulova, J. Alloys Compd. 361 (1–2), 57–61 (2003). https://doi.org/10.1016/S0925-8388(03)00439-0
N. N. Bikkulova, Yu. M. Stepanov, A. D. Davletshina, and L. V. Bikkulova, Lett. Mater. 3 (2), 87–90 (2013). https://doi.org/10.22226/2410-3535-2013-2-87-90
N. N. Bikkulova, K. N. Mikhalev, R. A. Yakshibaev, G. R. Akmanova, L. V. Tsygankova, A.R. Kurbangulov, A. K. Kutov, and A. V. Bikkulova, Ionics 25 (2), 887–890 (2019). https://doi.org/10.1007/s11581-018-2722-0
G. R. Akhmanova, R. A. Yakshibaev, A. D. Davletshina, and N. N. Bikkulova, Neorg. Mater. 56 (1), 3–8 (2020). https://doi.org/10.31857/S0002337X20010017
Funding
This study was supported by the Russian Foundation for Basic Research, project no. 18-32-00675, “Computer Design of the Structure of the Nanocrystalline State, Model Calculations of the Band Structure and Lattice Dynamics of Copper Selenide and Silver Telluride.”
Author information
Authors and Affiliations
Corresponding authors
Additional information
Translated by V. Bukhanov
Rights and permissions
About this article
Cite this article
Bikkulova, N.N., Gorbunov, V.A., Akmanova, G.R. et al. Ionic Conductivity in Copper Selenides. Dokl. Phys. 65, 265–268 (2020). https://doi.org/10.1134/S1028335820080017
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1028335820080017