Skip to main content
SpringerLink
Log in

Fine Crystal Structure, Spectral Properties, and Surface Micromorphology of 1,3,5-Triamino-2,4,6-trinitrobenzene, 1,1-Diamino-2,2-dinitroethylene, and Benzotrifuroxan Films Obtained by Gas-Phase Crystallization

  • Published:
Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Aims and scope Submit manuscript

Abstract

We study the structure of thin films of benzotrifuroxan, 1,3,5-triamino-2,4,6-trinitrobenzene, and 1,1-diamino-2,2-dinitroethylene, obtained by gas-phase deposition on various substrates: aluminum, polyethylene terephthalate, imitation parchment, quartz glass, polymer resin, silicon, and sapphire. The gaseous products obtained by thermal vacuum sublimation are subjected to preliminary preparation. The molecular structure of the obtained thin films corresponds to the studied substances. The texture of the films is determined. Their morphology is determined by particles that have a columnar shape, nonequilibrium faceting, and a developed surface. X-ray diffractometry, Raman spectroscopy, IR spectroscopy, spectrophotometry in the visible, ultraviolet, and near-infrared regions, and optical and electron microscopy are used in the measurements. The surface topology and electronic properties of the obtained textured films are studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. Yu. A. Lebedev and E. A. Miroshnichenko, Thermochemistry of Vaporization of Organic Substances (Nauka, Moscow, 1981) [in Russian].

    Google Scholar 

  2. V. E. Minaichev, Film Deposition in Vacuum, Vol. 6 of Technology of Semiconductor Devices and Microelectronic Products (Vysshaya Shkola, Moscow, 1989) [in Russian].

  3. K. F. Grebenkin, in Proc. V Int. Conf. “Zababakhin Scientific Readings” (Snezhinsk, 1998), part 1, p. 189.

  4. D. V. Mil’chenko, V. A. Gubachev, L. A. Andreevskikh, S. A. Vakhmistrov, A. L. Mikhailov, V. A. Burnashov, E. V. Khaldeev, A. I. Pyatoikina, S. S. Zhuravlev, and V. N. German, Combust., Explos. Shock Waves 51, 80 (2015).

    Article  Google Scholar 

  5. V. N. German, A. K. Fisenko, and N. P. Khokhlov, in Proc. 1998 Life Cycles of Energetic Material Conf. (USA, 1998), p. 67.

  6. D. V. Mil’chenko, V. A. Gubachev, A. L. Mikhailov, S. A. Vakhmistrov, and N. N. Titova, in Proc. Sci.-Pract. Conf. “Additive Technologies in the Russian Industry” (Moscow, 2015), p. 197.

  7. N. P. Taibinov, A. V. Stankevich, O. V. Kostitsyn, B. G. Loboiko, and A. Yu. Garmashev, in Proc. Sci.-Pract. Conf. “Additive Technologies in the Russian Industry” (Moscow, 2015), p. 217.

  8. B. L. Deopura and V. D. Gupta, J. Chem. Phys. 54, 4013 (1971). https://doi.org/10.1063/1.1675458

    Article  CAS  Google Scholar 

  9. T. G. Towns, Spectrochim. Acta, Part A 39, 801 (1983).

    Article  Google Scholar 

  10. G. Vergoten, G. Fleury, M. Blain, and S. Odiot, J. Raman Spectrosc. 16, 143 (1985).

    Article  CAS  Google Scholar 

  11. N. V. Latypov, J. Bergman, A. Langlet, U. Wellmar, and U. Bemm, Tetrahedron 54, 11525 (1998).

    Article  CAS  Google Scholar 

  12. M. M. Bishop, R. S. Chellappa, M. Pravica, J. Coe, Zh. Liu, D. Dattlebaum, Y. Vohra, and N. Velisavljevic, J. Chem. Phys. 137, 174304 (2012).

    Article  Google Scholar 

  13. B. Gao, P. Wu, and B. Huang, New J. Chem. 38, 2334 (2014).

    Article  CAS  Google Scholar 

  14. X. Zhao, D. He, X. Ma, X. Liu, Z. Xu, L. Chen, J. Wang, RSC Adv. 11, 33522 (2021).

  15. E. A. Chugunova, R. E. Timasheva, E. M. Gibadullina, A. R. Burilov, and R. Goumont, Propellants, Explos., Pyrotech. 37, 390 (2012). https://doi.org/10.1002/prep.201200080

    Article  CAS  Google Scholar 

  16. H. H. Cady and A. C. Larson, Acta Crystallogr. 18, 485 (1965).

    Article  CAS  Google Scholar 

  17. A. V. Stankevich, E. B. Smirnov, O. V. Kostitsyn, K. A. Ten, A. N. Shmakov, and B. P. Tolochko, in Proc. School for Young Specialists “The Use of Synchrotron and Terahertz Radiation to Study of High-Energy Materials” (Novosibirsk, 2015), p. 46.

  18. A. V. Stankevich, P. A. Slepukhin, B. G. Loboiko, G. L. Rusinov, O. V. Kostitsyn, and N. P. Taibinov, in Proc. XII Int. Conf. “Zababakhin Scientific Readings” (Snezhinsk, 2017), p. 99.

  19. H. H. Cady, A. C. Larson, and D. T. Cromer, Acta Crystallogr. 20, 336 (1966).

    Article  CAS  Google Scholar 

  20. A. V. Stankevich, B. G. Loboilko, A. Yu. Garmashev, O. V. Kostitsyn, N. P. Taibinov, J. Phys.: Conf. Ser 1147, 012009 (2019).

    Google Scholar 

  21. U. Bemm and H. Ostmark, Acta Crystallogr. 54, 1997.

  22. A. V. Stankevich, O. V. Kostitsyn, N. P. Taibinov, A. Yu. Garmashev, and D. V. Petrov, J. Phys.: Conf. Ser. 1787, 012006 (2021).

    CAS  Google Scholar 

  23. A. Le Bail, J. Solid State Chem. 83, 267 (1989).

    Article  CAS  Google Scholar 

  24. G. S. Pawley, J. Appl. Crystallogr. 14, 357 (1981).

    Article  CAS  Google Scholar 

  25. V. K. Pecharsky and P. Y. Zavalij, Fundamentals of Powder Diffraction and Structural Characterization of Materials (Springer, New York, 2003).

    Google Scholar 

  26. P. Scardi and M. Leoni, Acta Crystallogr., Sect. A 58, 190 (2002).

    Article  CAS  Google Scholar 

  27. J. W. Eaton, D. Bateman, S. Hauberg, and R. Wehbring, GNU Octave. A High-Level Interactive Language for Numerical Computations, Ed. 4 for Octave Version 4.2.1 (2017).

  28. A. V. Stankevich, O. V. Kostitsyn, and N. P. Taibinov, RF Patent No. 2 566 399 (2014).

  29. A. V. Stankevich, N. P. Taibinov, O. V. Kostitsyn, and B. G. Loboiko, in Proc. All-Russian Sci. Conf. “II Baikal Materials Science Forum” (Ulan-Ude, 2015), part 2, p. 195.

Download references

Author information

Authors and Affiliations

  1. Russian Federal Nuclear Center—Zababakhin All-Russian Research Institute of Technical Physics, 456770, Snezhinsk, Russia

    A. V. Stankevich, A. V. Sobolevskaya, M. S. Streltsova, A. N. Gretsova & O. A. Frolova

Authors
  1. A. V. Stankevich
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Sobolevskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. S. Streltsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. N. Gretsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. A. Frolova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Stankevich.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by O. Zhukova

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Stankevich, A.V., Sobolevskaya, A.V., Streltsova, M.S. et al. Fine Crystal Structure, Spectral Properties, and Surface Micromorphology of 1,3,5-Triamino-2,4,6-trinitrobenzene, 1,1-Diamino-2,2-dinitroethylene, and Benzotrifuroxan Films Obtained by Gas-Phase Crystallization. J. Surf. Investig. 17, 1043–1051 (2023). https://doi.org/10.1134/S1027451023050336

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1027451023050336

Keywords:

Search

Navigation