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Influence of Preliminary UV Irradiation on the Formation of Carbon Nanofibers on the Surface of Chlorinated Polyvinyl Chloride Under the Action of a High-Power Ion Beam

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Abstract

The influence of preliminary ultraviolet (UV) irradiation on the formation of carbon nanofibers on the surface of chlorinated polyvinyl chloride with the addition of ferrocene (10% of the polymer mass) is studied under the action of a high-power ion beam of nanosecond duration. Ultraviolet irradiation provides partial dehydrochlorination of the chloropolymer surface layer, causing a change in its thermodynamic properties, and due to this it affects the formation of carbon nanofibers during subsequent irradiation with a high-power ion beam. In contrast to thermal dehydrochlorination in air, ultraviolet irradiation makes it possible to reduce the temperature of the surface layer and thus reduce the negative effect of chloropolymer oxidation. The possible mechanisms of the influence of preliminary ultraviolet irradiation on the formation of carbon nanofibers on the surface of the chloropolymer under study are considered.

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ACKNOWLEDGMENTS

The work was carried out the equipment of the Omsk Regional Center for Collective Use, Siberian Branch, Russian Academy of Sciences.

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  1. Dostoevsky Omsk State University, 644077, Omsk, Russia

    V. S. Kovivchak & A. A. Parygin

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  1. V. S. Kovivchak
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Correspondence to V. S. Kovivchak.

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Kovivchak, V.S., Parygin, A.A. Influence of Preliminary UV Irradiation on the Formation of Carbon Nanofibers on the Surface of Chlorinated Polyvinyl Chloride Under the Action of a High-Power Ion Beam. J. Surf. Investig. 15 (Suppl 1), S37–S41 (2021). https://doi.org/10.1134/S1027451022020112

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