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Local Atomic Structure and Magnetic Properties of Cu(II), Co(II), and Zn(II) 1-(2-Hydroxybenzylidenamino)benzimidazolinone-2 Complexes

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Abstract

New azomethine 1-(2-hydroxybenzylidenamino)benzimidazolinone-2 and Cu(II), Co(II) and Zn(II) complexes based on it are synthesized and studied. The structure of azomethine and metal complexes is found from the data of elemental analysis, infrared (IR) spectroscopy, 1H NMR spectroscopy, X-ray absorption spectroscopy, and magnetochemistry. It is shown that all complexes have a mononuclear structure with the general formula M(HL)2. For the copper complex, the weak antiferromagnetic-type exchange between copper ions is observed due to the formation of intermolecular hydrogen bonds N–H···O=C.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation (State task in the field of scientific activities of the Southern Federal University, project no. 0852-2020-0031).

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Authors and Affiliations

  1. Institute of Physical and Organic Chemistry, Southern Federal University, 344090, Rostov-on-Don, Russia

    I. S. Vasilchenko, T. A. Kuzmenko, L. N. Divaeva, G. S. Borodkin, S. B. Zaichenko, E. V. Korshunova, B. V. Chalsev & A. S. Burlov

  2. Research Institute of Physics, Southern Federal University, 344090, Rostov-on-Don, Russia

    V. G. Vlasenko

  3. Southern Research Center, Russian Academy of Sciences, 344006, Rostov-on-Don, Russia

    S. I. Levchenkov

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  1. I. S. Vasilchenko
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  2. V. G. Vlasenko
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  3. T. A. Kuzmenko
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  4. L. N. Divaeva
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Correspondence to V. G. Vlasenko or A. S. Burlov.

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Translated by V. Selikhanovich

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Vasilchenko, I.S., Vlasenko, V.G., Kuzmenko, T.A. et al. Local Atomic Structure and Magnetic Properties of Cu(II), Co(II), and Zn(II) 1-(2-Hydroxybenzylidenamino)benzimidazolinone-2 Complexes. J. Surf. Investig. 15, 1004–1011 (2021). https://doi.org/10.1134/S1027451021050414

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