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Structure of Diffusion Polymer Membranes for Molecular and Ionic Transport

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Abstract

Neutron studies of the channels for molecular and ionic transports in membranes modified with different nanoparticles were carried out. In the polyphenylene oxide film modified with polymers composed of fullerene with grafted with polystyrene and poly-2-vinylpyridine arms, the formation of linear channels for diffusion at the modifier–matrix interfaces was detected. In the membranes of perfluorinated copolymers with SO3H ionic groups, embedded detonation nanodiamonds induced the expansion of the channels for better proton conductivity. The discovered subtle mechanisms of membranes structuring by different modifiers are relevant for advanced membrane design.

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FUNDING

The work was supported by the Russian Foundation for Basic Researches (grant no. 19-03-00249a) and partially by the Ministry of Science and Higher Education of Russia (Government Order, Project no. АААА-А20-120070890042-1).

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Authors and Affiliations

  1. Petersburg Nuclear Physics Institute named by B.P. Konstantinov of NRC “Kurchatov Institute”, 188300, Gatchina, Russia

    V. T. Lebedev & Yu. V. Kulvelis

  2. Atomic Energy Research Institute, MTA, KFKI, 1121, Budapest, Hungary

    Gy. Török

  3. Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, 141980, Dubna, Russia

    O. I. Ivankov

  4. Institute of Macromolecular Compounds of RAS, 199004, St. Petersburg, Russia

    G. A. Polotskaya, L. V. Vinogradova, O. N. Primachenko, E. A. Marinenko & A. S. Odinokov

  5. Ioffe Institute, 194021, St. Petersburg, Russia

    A. Ya. Vul

  6. Russian Research Center of Applied Chemistry, 193232, St. Petersburg, Russia

    A. S. Odinokov

Authors
  1. V. T. Lebedev
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  2. Yu. V. Kulvelis
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  3. Gy. Török
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  4. O. I. Ivankov
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  5. G. A. Polotskaya
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  6. L. V. Vinogradova
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  7. A. Ya. Vul
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  8. O. N. Primachenko
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  9. E. A. Marinenko
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  10. A. S. Odinokov
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Correspondence to V. T. Lebedev.

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Lebedev, V.T., Kulvelis, Y.V., Török, G. et al. Structure of Diffusion Polymer Membranes for Molecular and Ionic Transport. J. Surf. Investig. 15, 939–946 (2021). https://doi.org/10.1134/S1027451021050098

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