Skip to main content
Log in

Interpretation of X-ray photoelectron spectra with regard to multiple elastic and inelastic scattering

  • Published:
Journal of Surface Investigation. X-ray, Synchrotron and Neutron Techniques Aims and scope Submit manuscript

Abstract

X-ray photoelectron spectroscopy data are analyzed by solving the problem of the photoemission-current density function using the invariant immersion method. X-ray photoelectron spectra in a wide energy loss range are described on the basis of exact solution of the problem of elastic photoelectron scattering in solids using the discrete ordinate technique. The X-ray photoelectron spectrum is recorded in the form of a series of inelastic scattering orders. Comparison of the results of the exact solution with the data of transport and small-angle approximations reveals significant errors in the approximate solutions in X-ray photoelectron spectroscopy. The spectra calculated using different approximations are presented and compared with the experiment. The errors of the traditional background subtraction procedures are considered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. C. J. Powell and A. Jablonsky, J. Electron. Spectrosc. Relat. Phenom. 178179, 331 (2010).

    Article  Google Scholar 

  2. S. Tougaard, J. Electron. Spectrosc. Relat. Phenom. 178179, 128 (2010).

    Article  Google Scholar 

  3. NIST XPS Database. http://www.nist.gov/srdata/xps

  4. I. S. Tilinin and W. S. M. Werner, Phys. Rev. B 46, 13739 (1992).

    Article  Google Scholar 

  5. V. P. Afanas’ev, D. S. Efremenko, D. A. Ivanov, et al., J. Surf. Invest.: X-Ray, Synchrotr. Neutron Tech. 7, 382 (2013).

    Article  Google Scholar 

  6. S. Goudsmit and J. L. Saunderson, Phys. Rev. 57, 24 (1940); Phys. Rev. 58, 36 (1940).

    Article  Google Scholar 

  7. V. P. Afanas’ev, D. S. Efremenko, and A. V. Lubenchenko, in Light Scattering Reviews 8 (Springer, 2013), vol. XXV, p. 632.

    Google Scholar 

  8. V. P. Afanas’ev, D. S. Efremenko, A. V. Lubenchenko, et al., Bull. Russ. Acad. Sci.: Phys. 74, 170 (2010).

    Article  Google Scholar 

  9. S. Hajati and S. Tougaard, J. Surf. Anal. 15, 220 (2009).

    Google Scholar 

  10. S. Tougaard, J. Electron Spectrosc. Relat. Phenom. 52, 243 (1990).

    Article  Google Scholar 

  11. A. Jablonski, F. Salvat, and C. J. Powell, NIST Electron Elastic Scattering Cross-Section Database, Vers. 3.2, Standard Reference Data Program Database 64; http://www.nist.gov/srd/nist64.cfm

  12. V. P. Afanas’ev, D. S. Efremenko, and A. V. Lubenchenko, J. Surf. Invest.: X-Ray, Synchrotr. Neutron Tech. 5, 375 (2011).

    Article  Google Scholar 

  13. A. N. Tikhonov and V. Ya. Arsenin, Methods of Solving Incorrect Problems (Nauka, Moscow, 1980) [in Russian].

    Google Scholar 

  14. W. S. M. Werner, Appl. Phys. Lett. 89, 213106 (2006).

    Article  Google Scholar 

  15. S. Tougaard and I. Chorkendorff, Phys. Rev. B 35, 6570 (1987).

    Article  Google Scholar 

  16. S. Tougaard and J. Kraaer, Phys. Rev. B 43, 1651 (1991).

    Article  Google Scholar 

  17. V. P. Afanas’ev and A. V. Lubenchenko, Surf. Invest.: X-Ray, Synchrotr. Neutron Tech. 13, 1087 (1998).

    Google Scholar 

  18. C. Biswas, S. Shukla, V. K. Ahire, et al., Phys. Rev. B 67, 165416 (2003).

    Article  Google Scholar 

  19. F. Yubero and S. Tougaard, Phys. Rev. B 71, 045414 (2005).

    Article  Google Scholar 

  20. V. A. Ambartsumyan, Izv. Akad. Nauk SSSR, Ser. Geogr. Geofiz. 97, 3 (1942).

    Google Scholar 

  21. S. Chandrasekar, Radiative Transfer (Dover, New York, 1960; Inostr. Liter., Moscow, 1953).

    Google Scholar 

  22. V. V. Sobolev, Light Scattering in Atmospheres of Planets (Nauka, Moscow, 1972) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. P. Afanas’ev.

Additional information

Original Russian Text © V.P. Afanas’ev, P.S. Kaplya, O.Yu. Golovina, A.S. Gryazev, 2015, published in Poverkhnost’. Rentgenovskie, Sinkhrotronnye i Neitronnye Issledovaniya, 2015, No. 1, pp. 68–73.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Afanas’ev, V.P., Kaplya, P.S., Golovina, O.Y. et al. Interpretation of X-ray photoelectron spectra with regard to multiple elastic and inelastic scattering. J. Surf. Investig. 9, 62–66 (2015). https://doi.org/10.1134/S1027451015010036

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1027451015010036

Keywords

Navigation