Abstract
The crystal and magnetic structures of TlFeS2 and TlFeSe2 are studied by neutron diffraction in the temperature range of 10–320 K. The structures of TlFeS2 and TlFeSe2 have monoclinic symmetry with the space group C2/m at room temperature. TlFeS2 displays an antiferromagnetic phase at temperature below 200 K. The antiferromagnetic phase transition in TlFeSe2 takes place at a temperature below 290 K. The temperature dependence of the unit-cell parameters and volume are obtained. The coefficients of thermal and linear expansion are calculated. The temperature dependences of the interatomic distances are presented.
Similar content being viewed by others
References
V. I. Fistul’, New Materials. State. Problems. Prospects (MISIS, Moscow, 1995) [in Russian].
A. Kutoglu, Naturwissench. B 61, 125 (1974).
M. Rosenberg, A. Knulle, H. Sabrowsky, and C. Platte, Phys. Chem. Sol. 43, 87 (1982).
R. G. Veliyev, R. Z. Sadykhov, Yu. G. Asadov, et al., Crystallogr. Rep. 53, 130 (2008).
Z. Seidov, H. A. Krug von Nidda, J. Hemberger, et al., Phys. Rev. B 65, 014433 (2001).
K. Klepp and H. Boller, J. Mater. Chem. B 110, 1045 (1979).
G. I. Makovetskii and E. I. Kasinskii, Neorg. Mater. 20, 1752 (1984).
R. G. Veliyev, Semiconductors 45, 158 (2011).
D. Welz, P. Deppe, W. Schafer, et al., Phys. Chem. Sol. 50, 297 (1989).
E. M. Kerimova, Crystal Physics of Low-Dimensional Chalcogenides (Elm, Baku, 2012) [in Russian].
A. M. Balagurov, Sov. J. Part. Nucl. 23, 481 (1992).
V. B. Zlokazov and V. V. Chernyshev, J. Appl. Crystallogr. 25, 447 (1992).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.B. Asgerov, A.I. Madadzada, A.I. Beskrovnyy, D.I. Ismayilov, R.N. Mehdieva, S.H. Jabarov, E.M. Kerimova, D. Neov, 2014, published in Poverkhnost’. Rentgenovskie, Sinkhrotronnye i Neitronnye Issledovaniya, 2014, No. 12, pp. 5–10.
Rights and permissions
About this article
Cite this article
Asgerov, E.B., Madadzada, A.I., Beskrovnyy, A.I. et al. Neutron-diffraction study in TlFeS2 and TlFeSe2 at low temperatures. J. Surf. Investig. 8, 1193–1197 (2014). https://doi.org/10.1134/S1027451014060238
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1027451014060238