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Polarized-neutron scattering in aqueous solutions of fullerenols in a magnetic field

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Abstract

The aqueous solutions of mixtures (T = 25°C) of paramagnetic Gd@C82(OH) x and diamagnetic C82(OH) x fullerenols, where x ∼ 30, are studied via small-angle polarized-neutron scattering under the conditions of transition from diluted to concentrated systems whose solubility threshold is close to that of fullerenols. When the induction B of an external field varies from 0.001 to 1.0 T, the molecular correlation radius of solutions is R C ∼ 15–20 nm and the aggregation number reaches ∼5 × 104 with increasing fullerenol content (C = 0.04−2.0 wt %). Such changes are coupled with both paramagnetic Gd@C82(OH) x molecules and interactions between the induced diamagnetic moments of fullerenols introduced into aggregates.

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Authors and Affiliations

  1. Petersburg Nuclear Physics Institute, National Research Center Kurchatov Institute, Gatchina, St. Petersburg, 188300, Russia

    V. T. Lebedev, Yu. V. Kulvelis, V. V. Runov, V. P. Sedov & A. A. Szhogina

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  1. V. T. Lebedev
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  2. Yu. V. Kulvelis
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  3. V. V. Runov
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  4. V. P. Sedov
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  5. A. A. Szhogina
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Correspondence to V. T. Lebedev.

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Original Russian Text © V.T. Lebedev, Yu.V. Kulvelis, V.V. Runov, V.P. Sedov, A.A. Szhogina, 2014, published in Poverkhnost’. Rentgenovskie, Sinkhrotronnye i Neitronnye Issledovaniya, 2014, No. 10, pp. 88–99.

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Lebedev, V.T., Kulvelis, Y.V., Runov, V.V. et al. Polarized-neutron scattering in aqueous solutions of fullerenols in a magnetic field. J. Surf. Investig. 8, 1044–1054 (2014). https://doi.org/10.1134/S1027451014050358

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  • DOI: https://doi.org/10.1134/S1027451014050358

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