Skip to main content
SpringerLink
Log in

SEM diagnostics of the surface of MK-40 and MA-40 heterogeneous ion-exchange membranes in the swollen state after thermal treatment

  • Published:
Journal of Surface Investigation. X-ray, Synchrotron and Neutron Techniques Aims and scope Submit manuscript

Abstract

The morphology of the surface of MK-40 and MA-40 ion-exchange membranes in the swollen state after chemical and thermal treatment is studied using scanning electron microscopy. The distribution of portions of the ion exchanger on the surface of heterogeneous membranes is found to be of a complex stochastic nature; their sizes for the MK-40 and MA-40 membranes are 5–30 and 8–40 μm, respectively, while the sizes typical for the secondary porous structure are 2–8 μm. An increase in the share of the ion-exchange component of the surface (by 20–40%), the sizes of the ion-exchange portions (by 20%), and the surface porosity (by two-three times) in the samples subjected to thermal treatment is revealed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. V. I. Zabolotskii, V. V. Nikonenko, M. Kh. Urtenov, et al., Russ. J. Electrochem. 48, 692 (2012).

    Article  CAS  Google Scholar 

  2. G. K. Saldadze, in Ion-Selective Membranes and Electromembrane Processes (NIITEKhim, Moscow, 1986), p. 18 [in Russian].

    Google Scholar 

  3. V. F. Selemenev, M. V. Matveeva, G. A. Chikin, et al., Zh. Fiz. Khim. 70, 370 (1990).

    Google Scholar 

  4. V. F. Selemenev, A. N. Zyablov, V. N. Chikanov, et al., Sorbtsion. Khromatogr. Protsessy 1, 905 (2001).

    Google Scholar 

  5. N. D. Pis’menskaya, V. V. Nikonenko, N. A. Mel’nik, et al., Membr. Membr. Tekhnol. 1(3), 201 (2011).

    Google Scholar 

  6. V. V. Bugakov, V. I. Zabolotskii, and M. V. Sharafan, Sorbtsion. Khromatogr. Protsessy 10, 870 (2010).

    Google Scholar 

  7. G. Yu. Lopatkova, Candidate’s Dissertation in Chemistry (Krasnodar, 2006).

  8. W. Sun, T. Chen, C. Chen, et al., J. Membr. Sci. 305, 93 (2007).

    Article  CAS  Google Scholar 

  9. A. Lehmani, S. Durand-Vidal, and P. Turg, J. Appl. Polym. Sci. 68, 503 (1998).

    Article  CAS  Google Scholar 

  10. O. V. D’yakonova, S. A. Sokolova, A. N. Zyablov, and Yu. A. Zhibrova, Sorbtsion. Khromatogr. Protsessy 8, 863 (2008).

    Google Scholar 

  11. E. V. Krisilova, T. V. Eliseeva, and G. Yu. Oros, Fizikokhim. Poverkhn. Zashchita Mater. 47(1), 36 (2011).

    Google Scholar 

  12. V. I. Vasil’eva, L. A. Bityutskaya, N. A. Zaichenko, et al., Sorbtsion. Khromatogr. Protsessy 8, 260 (2008).

    Google Scholar 

  13. V. I. Vasil’eva, N. A. Kranina, M. D. Malykhin, et al., J. Surf. Invest.: X-Ray, Synchrotron Neutron Tech. 7, 144 (2013).

    Article  Google Scholar 

  14. N. P. Berezina, O. P. Ivina, and D. V. Rubinina, Available from ONIITEKhim Cherkassy, No. 166-xn 90 (Kuban. Gos. Univ., Krasnodar, 1990).

    Google Scholar 

  15. N. P. Gnusin and V. D. Grebenyuk, Electrochemistry of Granulated Ion-Exchangers (Naukova Dumka, Kiev, 1972) [in Russian].

    Google Scholar 

  16. T. I. Garshina and L. P. Markova, in Proceedings of the Russian Scientific Conference on Ion Transport in Organic and Inorganic Membranes (Kuban. Gos. Univ., Tuapse, Krasnodar, 2006), p. 44.

    Google Scholar 

  17. N. P. Berezina, N. A. Kononenko, G. A. Dvorkina, et al., Physicochemical Properties of Ion-Exchangers (Kuban. Gos. Univ., Krasnodar, 1999) [in Russian].

    Google Scholar 

  18. N. A. Skibitskaya, V. A. Kuzmin, and A. V. Garshev, J. Surf. Invest.: X-Ray, Synchrotron Neutron Tech. 4, 77 (2010).

    Article  Google Scholar 

  19. V. A. Kuzmin and N. A. Skibitskaya, J. Surf. Invest.: X-Ray, Synchrotron Neutron Tech. 6, 187 (2012).

    Article  CAS  Google Scholar 

  20. S. J. B. Reed, Electron Microprobe Analysis and Scanning Electron Microscopy in Geology (Cambridge Univ. Press, 2010; Tekhnosfera, Moscow, 2008).

    Google Scholar 

  21. V. V. Uglov, N. N. Koval’, A. K. Kuleshov, et al., J. Surf. Invest.: X-Ray, Synchrotron Neutron Tech. 5, 350 (2011).

    Article  CAS  Google Scholar 

  22. E. A. Sirota, N. A. Kranina, V. I. Vasil’eva, et al., Vestn. Voronezh. Uni., Ser. Khim. Biol. Farmats., No. 2, 53 (2011).

    Google Scholar 

  23. E. A. Sirota, N. A. Kranina, and V. I. Vasil’eva, Certificate of State Registration of Computer Software No. 2012610185 (Ru) (Voronezh. State Univ., 2012).

    Google Scholar 

  24. M. F. Yudin, M. N. Selivanov, O. F. Tishchenko, et al., Fundamental Terms of Metrology: Dictionary and Handbook, Ed. by Yu. V. Tarbeev (Izd. Standartov, Moscow, 1989) [in Russian].

  25. E. Volodina, N. Pismenskaya, V. Nikonenko, et al., J. Colloid Interface Sci. 285, 247 (2005).

    Article  CAS  Google Scholar 

  26. N. P. Berezina, N. A. Kononenko, and Yu. M. Vol’fkovich, Elektrokhimiya 30, 366 (1994).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Voronezh State University, Voronezh, Russia

    V. I. Vasil’eva, E. M. Akberova, A. V. Zhiltsova, E. I. Chernykh, E. A. Sirota & B. L. Agapov

Authors
  1. V. I. Vasil’eva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. M. Akberova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Zhiltsova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. I. Chernykh
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. A. Sirota
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. B. L. Agapov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © V.I. Vasil’eva, E.M. Akberova, A.V. Zhiltsova, E.I. Chernykh, E.A. Sirota, B.L. Agapov, 2013, published in Poverkhnost’. Rentgenovskie, Sinkhrotronnye i Neitronnye Issledovaniya, 2013, No. 9, pp. 27–34.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vasil’eva, V.I., Akberova, E.M., Zhiltsova, A.V. et al. SEM diagnostics of the surface of MK-40 and MA-40 heterogeneous ion-exchange membranes in the swollen state after thermal treatment. J. Surf. Investig. 7, 833–840 (2013). https://doi.org/10.1134/S1027451013050194

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1027451013050194

Keywords

Search

Navigation