Skip to main content
SpringerLink
Log in

Physical and mathematical model of the surface segregation in binary alloys of transition metals

  • Published:
Journal of Surface Investigation. X-ray, Synchrotron and Neutron Techniques Aims and scope Submit manuscript

Abstract

The surface segregation in binary alloys of transition metals based on platinum and palladium with different surface-face orientations are simulated via the electron-density functional method. The concentrations of the surface-active components of the binary alloys and displacements of the surface ion planes thereof are calculated self-consistently. The influence of surface segregation and lattice relaxation on the surface energy and electron work function on the surface of alloys of transition metals with various concentrations is investigated. The simulation results are compared with experimental data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C. Creemers, P. Deurinck, S. Helfensteyn, and J. Luyten, Appl. Surf. Sci. 219, 11 (2003).

    Article  CAS  Google Scholar 

  2. R. V. Gulyaev, Extended Abstract of Candidate’s Dissertation in Chemistry (IK im. G. K. Boreskova SO RAN, Novosibirsk, 2010).

    Google Scholar 

  3. E. V. Vasil’eva, R. M. Volkova, M. I. Zakharova, et al., Platinum, its Alloys and Composite Materials (Metallurgiya, Moscow, 1980) [in Russian].

    Google Scholar 

  4. A. I. Gusev, Nanocrystalline Materials: Production Methods and Properties (UrO RAN, Yekaterinburg, 1998) [in Russian].

    Google Scholar 

  5. S. L. Granevskii, N. V. Dalakova, A. Z. Kashezhev, et al., Vopr. At. Nauki Tekh., Ser. Vakuum, Chist. Mater., Sverkhprovodn., No. 6, 149 (2009).

    Google Scholar 

  6. M. Prutton, Introduction to Surface Physics (Oxford Science, 1994; Regulyar. Khaotich. Dinamika, Izhevsk, 2000).

    Google Scholar 

  7. K. Oura, V. G. Lifshits, A. A. Saranin, et al., Surface Science: An Introduction (Springer, New York, 2003; Nauka, Moscow, 2006).

    Google Scholar 

  8. A. V. Matveyev, Vestn. Omsk. Univ., No. 4, 57 (2010).

    Google Scholar 

  9. B. J. Bood and H. Bise, Surf. Sci. 52, 151 (1975).

    Article  Google Scholar 

  10. S. V. Rempel’ and A. I. Gusev, Phys. Solid State 44, 68 (2002).

    Article  Google Scholar 

  11. N. V. Fedorenko, Development of Platinum Metal Researches in Russia (Nauka, Moscow, 1985) [in Russian].

    Google Scholar 

  12. M. Scheffler and C. Stampfl, Handbook of Surface Science: Electronic Structure, Ed. by K. Horn and M. Scheffler (Elsevier, Amsterdam, 2000), p. 286.

  13. A. N. Vakilov, M. V. Mamonova, A. V. Matveev, et al., Theoretic Models and Methods in Surface Physics, The School-Book (Omsk. Gos. Univ., Omsk, 2005) [in Russian].

    Google Scholar 

  14. Theory of the Inhomogeneous Electron Gas, Ed. by S. Lundquist and H. March (New York, London, 1983; Mir, Moscow, 1989).

    Google Scholar 

  15. R. M. Digilov and V. A. Sozaev, Poverkhnost: Fiz., Khim., Mekh., No. 7, 42 (1988).

    Google Scholar 

  16. A. V. Matveyev, M. V. Mamonova, and V. V. Prudnikov, Phys. Met. Metallogr. 97, 562 (2004).

    Google Scholar 

  17. A. V. Matveyev and M. V. Kruglov, Vestn. Omsk. Univ., No. 4, 31 (2006).

    Google Scholar 

  18. A. V. Matveyev, Poverkhnost’, No. 8, 89 (2007).

    Google Scholar 

  19. A. V. Matveyev, Russ. Phys. J. 50, 646 (2007).

    Article  Google Scholar 

  20. A. V. Matveyev, J. Surf. Invest. 5, 90 (2011).

    Article  Google Scholar 

  21. R. M. Kobeleva, B. R. Gel’chinskii, and V. F. Ukhov, Fiz. Met. Metalloved. 45, 25 (1978).

    CAS  Google Scholar 

  22. A. V. Matveyev, Phys. Met. Metallogr. 105, 427 (2008).

    Article  Google Scholar 

  23. A. V. Matveyev, J. Surf. Invest. 3, 644 (2009).

    Article  Google Scholar 

  24. A. V. Matveyev, Vestn. Omsk. Univ., No. 2, 29 (2010).

    Google Scholar 

  25. J. Ferrante and J. R. Smith, Surf. Sci. 38, 77 (1973).

    Article  CAS  Google Scholar 

  26. Yu. N. Demin, Physics of Metals, The School-Book (MGIU, Moscow, 2003) [in Russian].

    Google Scholar 

  27. Physical Values, The Handbook, Ed. by I. S. Grigor’ev and E. Z. Meilikhov (Energoatomizdat,, Moscow, 1991) [in Russian].

    Google Scholar 

  28. A. Adamson, The Physical Chemistry of Surfaces (Wiley, New York, 1976).

    Google Scholar 

  29. C. Creemers, Surf. Sci. 360, 10 (1996).

    Article  CAS  Google Scholar 

  30. D. V. Lyustritskaya, Candidate’s Dissertation in Chemistry (Samar. State Univ., Samara, 2007).

    Google Scholar 

  31. S. Yu. Davydov, Tech. Phys. 47, 92 (2002).

    Article  CAS  Google Scholar 

  32. Y. Gauthier, R. Baudoing, J. Rundgren, and M. Lundberg, Phys. Rev. B 35, 7867 (1987).

    Article  CAS  Google Scholar 

  33. R. H. Bergmans, M. van de Grift, A. W. Denier van der Gon, and H. H. Brongersma, Surf. Sci. 345, 303 (1996).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Omsk State University, Omsk, Russia

    A. V. Matveev

Authors
  1. A. V. Matveev
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © A.V. Matveev, 2013, published in Poverkhnost’. Rentgenovskie, Sinkhrotronnye i Neitronnye Issledovaniya, 2013, No. 8, pp. 75–85.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Matveev, A.V. Physical and mathematical model of the surface segregation in binary alloys of transition metals. J. Surf. Investig. 7, 774–783 (2013). https://doi.org/10.1134/S1027451013040344

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1027451013040344

Keywords

Search

Navigation