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Estimation of Silica Material Pore Sizes from IR Spectra of Adsorbed Water

Abstract

A technique for estimating the diameter of nanosize pores has been developed. It consists in filling a substance with liquid water, recording the absorption spectra of the substance with water, compiling a database of spectroscopic data which characterized the substance with different pore sizes, and retrieving the pore diameter of an arbitrary substance using an algorithm based on the regression analysis. The technique has been tested on silica samples of different porosity.

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REFERENCES

  1. V. I. Serdyukov, L. N. Sinitsa, and A. A. Lugovskoi, “Influence of gas humidity on the reflection coefficient of multilayer dielectric mirrors,” Appl. Opt. 55 (17), 4763–4768 (2016).

    ADS  Article  Google Scholar 

  2. M. V. Panchenko, M. V. Kabanov, Yu. A. Pkhalagov, B. D. Belan, V. S. Kozlov, S. M. Sakerin, D. M. Kabanov, V. N. Uzhegov, N. N. Shchelkanov, V. V. Polkin, S. A. Terpugova, G. N. Tolmachev, E. P. Yausheva, M. Yu. Arshinov, D. V. Simonenkov, V. P. Shmargunov, D. G. Chernov, Yu. S. Turchinovich, Vas. V. Pol’kin, T. B. Zhuravleva, I. M. Nasrtdinov, and P. N. Zenkova, “Integrated studies of tropospheric aerosol at the Institute of Atmospheric Optics (development stages),” Atmos. Ocean. Opt. 33 (1), 27–41 (2020).

    Article  Google Scholar 

  3. E. A. Tutov, A. Yu. Andryukov, and E. N. Bormontov, “Adsorption-based porosimetry using capacitance measurements,” Semiconductors 35 (7), 816–820 (2001).

    ADS  Article  Google Scholar 

  4. RF Patent No. 2150101 S1, G01N 15/08 (May 2000).

  5. Auwera J. Vander, N. H. Ngo, H. El Hamzaoui, B. Capoen, M. Bouazaoui, P. Ausset, C. Boulet, and J.-M. Hartmann, “Infrared absorption by molecular gases as a probe of nanoporous silica xerogel and molecule-surface collisions: low-pressure results,” Phys. Rev. A: 88, 042506 (2013).

    ADS  Article  Google Scholar 

  6. T. M. Petrova, Yu. N. Ponomarev, A. A. Solodov, A. M. Solodov, and A. F. Danilyuk, “Spectroscopic nanoporometry of aerogel,” JTEP Lett. 101 (1), p. 65–67.

  7. T. Svensson, E. Adolfsson, M. Burresi, R. Savo, C. Xu, D. S. Wiersma, and S. Svanberg, “Pore size assessment based on wall collision broadening of spectral lines of confined gas: experiments on strongly scattering nanoporous ceramics with fine-tuned pore sizes,” Appl. Phys. B 110, 147–154 (2013).

    ADS  Article  Google Scholar 

  8. L. N. Sinitsa and A. A. Lugovskoy, “Dynamic registration of the absorption spectrum of water in the SiO2 nanopores in high frequency range,” J. Chem. Phys. 133 (1-5), 204506 (2010).

    ADS  Article  Google Scholar 

  9. L. N. Sinitsa, V. I. Serdyukov, A. F. Danilyuk, and A. A. Lugovskoy, “Observation of water dimers in nanopores of silicon aerogel,” JETP Lett. 102 (1), 32–35 (2015).

    ADS  Article  Google Scholar 

  10. V. Crupi, F. Longo, D. Majolino, and V. Venuti, “Raman spectroscopy: Probing dynamics of water molecules confined in nanoporous silica glasses,” Eur. Phys. J. Special Top. 141, 61–64 (2007).

    Article  Google Scholar 

  11. J. Crupi, D. Majolino, and V. Venutti, “Diffusional and vibrational dynamics of water in NaA zeolites by neutron and Fourier transform infrared spectroscopy,” J. Phys.: Condens. Matter 16, 5297 (2004).

    ADS  Google Scholar 

  12. N. M. Emel’yanov, L. N. Sinitsa, V. I. Serdyukov, A. A. Lugovskoi, and V. V. Annenkov, “Study of nanoporous silica structure by spectral analysis,” Proc. SPIE—Int. Soc. Opt. Eng. (2020). https://doi.org/10.1117/12.2576125

  13. A. A. Lugovskoy, Yu. A. Poplavskii, V. I. Serdyukov, and L. N. Sinitsa, “Experimental setup for spectrophotometric study of water clusters in nanoporous material,” Atmos. Ocean. Opt. 24 (5), 502–507 (2011).

    Article  Google Scholar 

  14. J.-B. Brubach, A. Mermet, A. Filabozzi, A. Gerschel, and P. Roy, “Signatures of the hydrogen bonding in the infrared bands of water,” J. Chem. Phys. 122, 184509-1–7 (2005).

    ADS  Article  Google Scholar 

  15. M. Erko, G. H. Findenegg, N. Cade, A. G. Michette, and O. Paris, “Confinement-induced structural changes of water studied by Raman scattering,” Phys. Rev. B: 84 (10), 104205 (2011).

    ADS  Article  Google Scholar 

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Funding

The work was supported by the Ministry of Science and Higher Education of the Russian Federation (V.E. Zuev Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences, and the Limnological Institute, Siberian Branch, Russian Academy of Sciences, topic no. AAAA-A19-119100490016-4, in part of manufacturing the silica samples).

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Correspondence to L. N. Sinitsa, N. M. Emel’yanov or A. A. Lugovskoi.

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Sinitsa, L.N., Emel’yanov, N.M., Shcherbakov, A.P. et al. Estimation of Silica Material Pore Sizes from IR Spectra of Adsorbed Water. Atmos Ocean Opt 34, 542–546 (2021). https://doi.org/10.1134/S1024856021060221

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  • DOI: https://doi.org/10.1134/S1024856021060221

Keywords:

  • nanopores
  • water vapor
  • absorption spectrum
  • regression analysis