Abstract
Measurement results of the concentration of H2 molecules into aerogel (SiO2) nanopores with diameter 20 nm are presented. The standard gasometric method is used. The experimental data on H2 molecule concentration together with the data on integral intensity of collision-induced H2 absorption 0–1 band are used for estimation of the absorption cross section at the band maximum.
This is a preview of subscription content,
to check access.


Similar content being viewed by others
REFERENCES
Yu. N. Ponomarev, T. M. Petrova, A. M. Solodov, and A. A. Solodov, “IR spectroscopy of water vapor confined in nanoporous silica aerogel,” Opt. Exp. 18 (25), 26062–26067 (2010).
J. V. Auwera, N. H. Ngo, H. El. Hamzaoui, B. Capoen, M. Bouazaoui, P. Ausset, C. Boulet, and J.-M. Hartmann, “Infrared absorption by molecular gases as a probe of nanoporous silica xerogel and molecule-surface collisions: Low-pressure results,” Phys. Rev. A88 (4), 042506 (2013).
Yu. N. Ponomarev, T. M. Petrova, A. M. Solodov, A. A. Solodov, and A. F. Danilyuk, “Experimental study by the IR spectroscopy method of the interaction between ethylene and nanopores of various densities,” Atmos. Ocean. Opt. 23 (4), 266–269 (2010).
A. A. Solodov, T. M. Petrova, Yu. N. Ponomarev, and A. M. Solodov, “Influence of nanoconfinement on the rotational dependence of line half-widths for 2-0 band of carbon oxide,” Chem. Phys. Lett. 637, 18–21 (2015).
Yu. N. Ponomarev, T. M. Petrova, A. A. Solodov, and A. M. Solodov, “Observation of a forbidden vibrational absorption band of H2 in nanoporous aerogel,” JETP Lett. 99 (11), 619–621 (2014).
Yu. N. Kharzheev, ”Use of silica aerogels in Cherenkov counters,” Phys. Part. Nuclei 39 (1), 107–135 (2008).
http://www.ngpedia.ru/id149767p1.html. Cited November 9, 2019.
A. A. Lugovskoi, K. Yu. Osipov, and B. A. Tikhomirov, “Sorption of water molecules by silicon (SiO2) airgel nanopores,” Opt. Atmos. Okeana 30 (2), 124–127 (2017).
A. M. Solodov, T. M. Petrova, Yu. N. Ponomarev, A. A. Solodov, and V. I. Starikov, “Fourier spectroscopy of water vapor in the volume of aerogel nanopores. Part 1. Measurements and calculations,” Atmos. Ocean. Opt. 27 (4), 372–380 (2014).
Yu. N. Ponomarev, I. V. Ptashnik, A. A. Solodov, and A. M. Solodov, “Main sources of uncertainties in measuring weak near-infrared water vapor continuum absorption with a Fourier spectrometer with a long optical path,” Atmos. Ocean. Opt. 30 (5), 481–484 (2017).
Funding
This work was carried out within the Basic Research Program of the State Academies of Sciences (project no. AAAA-A17-117033019937-0).
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
The authors declare that they have no conflict of interest.
Rights and permissions
About this article
Cite this article
Ageev, B.G., Ponomarev, Y.N. Estimation of the Absorption Cross Section of the Forbidden Vibrational Band of Hydrogen in Nanoporous Aerogel. Atmos Ocean Opt 33, 321–323 (2020). https://doi.org/10.1134/S102485602004003X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S102485602004003X