The content and evolution of brown carbon (BrC) in smokes from Siberian forest fires were analyzed using measurements of the aerosol absorption optical depth (AAOD) at three Russian AERONET stations located in Tomsk, Zvenigorod, and Yekaterinburg. Estimates are obtained of the relative contribution of BrC in fine aerosol particles to the absorption of solar radiation at a wavelength of 440 nm (ηBrC) and, in particular, for an anomalous episode of long-range transport of smokes from Siberia to the European part of Russia in summer 2016. A considerable BrC content is found in smokes in Tomsk and Zvenigorod (where ηBrC is estimated to be 15 and 18% on average). It is noteworthy that no significant ηBrC values were revealed during passage of smokes from Siberian fires over Yekaterinburg. The ηBrC values were found to decrease with aerosol aging under sunlit conditions on the characteristic timescale of about 30 h. At the same time, the measurements in Zvenigorod indicate that the absorption properties of the organic component of smoke aerosol increase during a much longer evolution.
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G. R. Van der Werf, J. T. Randerson, L. Giglio, T. T. van Leeuwen, Y. Chen, B. M. Rogers, M. Mu, M. J. E. van Marle, D. C. Morton, G. J. Collatz, R. J. Yokelson, and P. S. Kasibhatla, “Global fire emissions estimates during 1997-2016,” Earth Syst. Sci. Data 9 (2), 697–720 (2017).
V. G. Bondur, K. A. Gordo, and V. L. Kladov, “Spatiotemporal distribution of the wild fire areas and emissions of carbon gases and aerosols over the Northern Eurasia according to satellite monitoring data,” Issledovanie Zemli iz Kosmosa, No. 6, 3–20 (2016).
M. Sand, T. Berntsen, K. von Salzen, M. Flanner, J. Langner, and D. Victor, “Response of Arctic temperature to changes in emissions of short-lived climate forcers,” Nat. Clim. Change, No. 6, 286–289 (2015).
T. C. Bond, S. J. Doherty, D. W. Fahey, et al., “Bounding the role of Black Carbon in the climate system: A scientific assessment,” J. Geophys. Res.: Atmos 118 (11), 5380– 5552 (2013).
V. S. Kozlov, M. V. Panchenko, and E. P. Yausheva, “Mass fraction of Black Carbon in submicrometer aerosol as an indicator of influence of smokes from remote forest fires in Siberia,” Atmos. Environ. 42 (11), 2611–2620 (2008).
N. Chubarova, Ye. Nezval’, I. Sviridenkov, A. Smirnov, and I. Slutsker, “Smoke aerosol and its radiative effects during extreme fire event over Central Russia in summer 2010,” Atmos. Meas. Tech 5 (3), 557–568 (2012).
V. S. Kozlov, E. P. Yausheva, S. A. Terpugova, M. V. Panchenko, D. G. Chernov, and V. P. Shmargunov, “Optical-microphysical properties of smoke haze from Siberian forest fires in summer 2012,” Int. J. Remote Sens. 35 (15), 5722–5741 (2014).
T. B. Zhuravleva, D. M. Kabanov, I. M. Nasrtdinov, T. V. Russkova, S. M. Sakerin, A. Smirnov, and B. N. Holben, “Radiative characteristics of aerosol during extreme fire event over Siberia in summer 2012,” At-mos. Meas. Tech 10 (1), 179–198 (2017).
V. S. Kozlov, E. P. Yausheva, M. V. Panchenko, and V. P. Shmargunov, “Annual behavior of Angstrom exponent of the aerosol absorption coefficients in the visible wavelength range upon the results of measurements at the Aerosol Station of IAO SB RAS,” Proc. SPIE—Int. Soc. Opt. Eng. 10833 (2018).
P. N. Antokhin, V. G. Arshinova, M. Y. Arshinov, B. D. Belan, S. B. Belan, D. K. Davydov, G. A. Ivlev, A. V. Fofonov, A. V. Kozlov, J. -D. Paris, P. Nedelec, T. M. Rasskazchikova, D. E. Savkin, D. V. Simonenkov, T. K. Sklyadneva, and G. N. Tolmachev, “Distribution of trace gases and aerosols in the troposphere over Siberia during wildfires of summer 2012,” J. Geophys. Res.: Atmos 123, 2285–2297 (2018).
I. B. Konovalov, D. A. Lvova, M. Beekmann, H. Jethva, E. F. Mikhailov, J.-D. Paris, B. D. Belan, V. S. Kozlov, P. Ciais, and M. O. Andreae, “Estimation of black carbon emissions from Siberian fires using satellite observations of absorption and extinction optical depths,” Atmos. Chem. Phys. 18 (20), 14 889–14 924 (2018).
I. B. Konovalov, M. Beekmann, E. V. Berezin, P. Formenti, and M. O. Andreae, “Probing into the aging dynamics of biomass burning aerosol by using satellite measurements of aerosol optical depth and carbon monoxide,” Atmos. Chem. Phys. 17 (7), 4513–4537 (2017).
K. Tsigaridis and M. Kanakidou, “The present and future of secondary organic aerosol direct forcing on climate,” Cur. Clim. Change Rep. 4 (2), 84–98 (2018).
I. B. Konovalov, M. Beekmann, N. A. Golovushkin, and M. O. Andreae, “Nonlinear behavior of organic aerosol in biomass burning plumes: A microphysical model analysis,” Atmos. Chem. Phys. 19 (19), 2091–12119 (2019).
M. O. Andreae and A. Gelencser, “Black carbon or brown carbon? The nature of light-absorbing carbonaceous aerosols,” Atmos. Chem. Phys. 6 (10), 3131–3148 (2006).
A. A. Vinogradova, N. S. Smirnov, and V. N. Korotkov, “Anomalous wildfires in 2010 and 2012 on the territory of Russia and supply of black carbon to the Arctic,” Atm-os. Oceanic Opt. 29 (6), 545–550 (2016).
H. Brown, X. Liu, Y. Feng, Y. Jiang, M. Wu, Z. Lu, C. Wu, S. Murphy, and R. Pokhrel, “Radiative effect and climate impacts of brown carbon with the Community Atmosphere Model (CAM5),” Atmos. Chem. Phys. 18 (24), 7745–17768 (2018).
R. Saleh, M. Marks, J. Heo, P. J. Adams, N. M. Donahue, and A. L. Robinson, “Contribution of brown carbon and lensing to the direct radiative effect of carbonaceous aerosols from biomass and biofuel burning emissions,” J. Geophys. Res.: Atmos. 120 (19), 10285–10296 (2015).
X. Wang, C. L. Heald, J. Liu, R. J. Weber, P. Campuzano-Jost, J. L. Jimenez, J. P. Schwarz, and A. E. Perring, “Exploring the observational constraints on the simulation of brown carbon,” Atmos. Chem. Phys. 18 (2), 635–653 (2018).n
R. P. Pokhrel, E. R. Beamesderfer, N. L. Wagner, J. M. Langridge, D. A. Lack, T. Jayarathne, E. A. Stone, C. E. Stockwell, R. J. Yokelson, and S. M. Murphy, “Relative importance of black carbon, brown carbon, and absorption enhancement from clear coatings in biomass burning emissions,” Atmos. Chem. Phys. 17 (8), 5063–5078 (2017).
G. I. Gorchakov, A. V. Karpov, N. V. Pankratova, E. G. Semutnikova, A. V. Vasil’ev, and I. A. Gorchakova, “Brown carbon and black carbon in smoke-filled atmosphere during boreal forest fires,” Issledovanie Zemli Kosmosa. No. 3, 11–21 (2017).
H. Forrister, J. Liu, E. Scheuer, J. Dibb, L. Ziemba, K. L. Thornhill, B. Anderson, G. Diskin, A. E. Perring, J. P. Schwarz, P. Campuzano-Jost, D. A. Day, B. B. Palm, J. L. Jimenez, A. Nenes, and R. J. Weber, “Evolution of brown carbon in wildfire plumes,” Geophys. Rev. Lett. 42 (11), 4623–4630 (2015).
M. Zhong and M. Jang, “Dynamic light absorption of biomass-burning organic carbon photochemically aged under natural sunlight,” Atmos. Chem. Phys. 14 (3), 1517–1525 (2014).
J. P. S. Wong, A. Nenes, and R. J. Weber, “Changes in light absorptivity of molecular weight separated brown carbon due to photolytic aging,” Environ. Sci. Technol. 51 (15), 8414–8421 (2017).
X. Fan, X. Yu, Y. Wang, X. Xiao, F. Li, Y. Xie, S. Wei, J. Song, and P. Peng, “The aging behaviors of chromophoric biomass burning brown carbon during dark aqueous hydroxyl radical oxidation processes in laboratory studies,” Atmos. Environ. 205, 9–18 (2019).
R. Bahadur, P. S. Praveen, Y. Xu, and V. Ramanathan, “Solar absorption by elemental and brown carbon determined from spectral observations,” Proc. Nat.: Acad. Sci. USA 109 (43), 17 366–17 371 (2012).
G. I. Gorchakov, A. V. Vasil’ev, K. S. Verichev, E. G. Semutnikova, and A. V. Karpov, “Finely dispersed brown carbon in a smoggy atmosphere,” Dokl. Earth Sci. 471 (1), 1158–1163 (2016).
X. Wang, C. L. Heald, A. J. Sedlacek, S. S. de Sa, S. T. Martin, M. L. Alexander, T. B. Watson, A. C. Aiken, S. R. Springston, and P. Artaxo, “Deriving brown carbon from multiwavelength absorption measurements: Method and application to AERONET and aethalometer observations,” Atmos. Chem. Phys. 16 (19), 12733–12752 (2016).
S. A. Sitnov, I. I. Mokhov, and G. I. Gorchakov, “Connection of smoke in air in the European Russia in summer 2016 with Siberian forest fires and abnormal atmospheric circulation,” Dokl. Akad. Nauk 472 (4), 456–461 (2017).
E. G. Semutnikova, G. I. Gorchakov, S. A. Sitnov, V. M. Kopeikin, A. V. Karpov, I. A. Gorchakova, T. Ya. Ponomareva, A. A. Isakov, R. A. Gushchin, O. I. Datsenko, G. A. Kurbatov, and G. A. Kuznetsov, “Siberian smoke haze over European territory of Russia in July 2016: Atmospheric pollution and radiative effects,” Atmos. Ocean. Opt. 31 (2), 171–180 (2018).
S. Mailler, L. Menut, D. Khvorostyanov, M. Valari, F. Couvidat, G. Siour, S. Turquety, R. Briant, P. Tuccella, B. Bessagnet, A. Colette, L. Letinois, K. Markakis, and F. Mereux, “CHIMERE-2017: From urban to hemispheric chemistry transport modeling,” Geosci. Model. Dev. 10 (6), 2397–2423 (2017).
I. B. Konovalov, E. V. Berezin, P. Ciais, G. Broquet, M. Beekmann, J. Hadji-Lazaro, C. Clerbaux, M. O. Andreae, J. W. Kaiser, and E.-D. Schulze, “Constraining CO2 emissions from open biomass burning by satellite observations of co-emitted species: A method and its application to wildfires in Siberia,” Atmos. Chem. Phys. 14 (19), 10383–10410 (2014).
I. B. Konovalov, D. A. Lvova, and M. Beekmann, “Estimation of the elemental to organic carbon ratio in biomass burning aerosol using AERONET retrievals,” Atmosphere 8 (7), 122 (2017).
C. Wu, D. Wu, and J. Z. Yu, “Quantifying black carbon light absorption enhancement with a novel statistical approach,” Atmos. Chem. Phys. 18 (1), 289–309 (2018).
K. C. Barsanti and J. F. Pankow, “Thermodynamics of the formation of atmospheric organic particulate matter by accretion reactions—Part 1: Aldehydes and ketones,” Atmos. Environ. 8 (26), 4371–4382 (2004).
E. Yousif and R. Haddad, “Photodegradation and photostabilization of polymers, especially polystyrene: Review,” Springerplus 2, 398 (2013).
H. Tang and J. E. Thompson, “Light-absorbing products form during the aqueous phase reaction of phenolic compounds in the presence of nitrate and nitrite with UV illumination,” Open J. Air Pollut. 1 (2), 13–21 (2012).
This work was supported by Russian Science Foundation (grant no. 19-77-20109). Model calculations for period of 2012 were performed under the support of the Russian Foundation for Basic Research (grant no. 18-05-00911).
The authors declare that they have no conflicts of interest.
Translated by O. Bazhenov
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Golovushkin, N.A., Kuznetsova, I.N., Konovalov, I.B. et al. Analysis of Brown Carbon Content and Evolution in Smokes from Siberian Forest Fires Using AERONET Measurements. Atmos Ocean Opt 33, 267–273 (2020). https://doi.org/10.1134/S1024856020030045