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Investigation of the ro-vibrational energy structure of (0101, F1) and (0101, F2) states of the 28SiH4 molecule

  • Spectroscopy of Ambient Medium
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Abstract

An analysis of the high-resolution vibrational-rotational IR spectrum of ν2 + ν4 (F1) and ν2 + ν4 (F2) bending absorption bands of the 28SiH4 molecule is carried out for the first time using the SPHETOM software. Approximately 618 experimental transitions with Jmax = 8 are assigned to ν2 + ν4 (F1) and ν2 + ν4 (F2) bands. Rotational, centrifugal distortion, tetrahedral splitting, and resonance interaction parameters for these vibrational bands are derived from the weighted fit of experimental line positions. The set of parameters obtained reproduces the initial experimental data with an accuracy close to the experimental uncertainties drms = 8 × 10–4 cm–1.

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Authors and Affiliations

  1. Tomsk Polytechnic University, Tomsk, 634050, Russia

    N. I. Raspopova

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Original Russian Text © N.I. Raspopova, 2017, published in Optika Atmosfery i Okeana.

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Raspopova, N.I. Investigation of the ro-vibrational energy structure of (0101, F1) and (0101, F2) states of the 28SiH4 molecule. Atmos Ocean Opt 30, 502–507 (2017). https://doi.org/10.1134/S1024856017060124

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