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Atmospheric and Oceanic Optics

, Volume 28, Issue 3, pp 240–244 | Cite as

Consideration of high surface concentrations of hydrochloric acid vapors in ground-based spectroscopic measurements

  • A. V. PolyakovEmail author
  • Yu. M. Timofeyev
  • A. V. Poberovskii
  • Ya. A. Virolainen
Inverse Problems of Atmospheric and Ocean Optics

Abstract

Spectral measurements show that solar radiation can contain information on extremely high surface concentrations of hydrochloric acid vapors, which leads to the impossibility of estimation of their total content using the background a priori information. An alternative specification of a priori information is suggested, which allows an increase in the number of retrieved values of hydrochloric acid vapor by 10%. The existence of high surface concentrations of the gas is confirmed by the spectral data processing results. A good agreement between estimates of the stratospheric content of hydrochloric acid vapors retrieved from ground-based measurements using the proposed a priori information and independent satellite data is shown: mean differences between data received by the two methods are 4.4%, standard deviation of the differences is 5.7%, and the correlation coefficient is 0.85.

Keywords

ground-based spectroscopic measurements gas total content hydrochloric acid vapors in the atmosphere near-surface pollution of the atmosphere 

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References

  1. 1.
  2. 2.
    M. I. Levinskii, A. F. Mazanko, and I. N. Novikov, Hydrogen Chloride and Hydrochloric Acid (Khimiya, Moscow, 1985) [in Russian].Google Scholar
  3. 3.
    A. V. Poberovskii, “High-resolution ground measurements of the IR spectra of solar radiation,” Atmos. Ocean. Opt. 23(2), 161–164 (2010).CrossRefGoogle Scholar
  4. 4.
    A. V. Poberovskii, M. V. Makarova, A. V. Rakitin, D. V. Ionov, and Yu. M. Timofeev, “Variability of the total column amounts of climate influencing gases obtained from ground-based high resolution spectroscope measurements,” Trans. Rus. Acad. Sci./Earth Sci. 432(1), 656–658 (2010).Google Scholar
  5. 5.
    A. V. Polyakov, Yu. M. Timofeev, and A. V. Poberovskii, “Ground-based measurements of total column of hydrogen chloride in the atmosphere near St. Petersburg,” Izv., Atmos. Ocean. Phys. 49(4), 411–419 (2013).CrossRefGoogle Scholar
  6. 6.
  7. 7.
    R. R. Garcia, D. R. Marsh, D. E. Kinnison, B. A. Boville, F. Sassi, “Simulation of secular trends in the middle atmosphere, 1950–2003,” J. Geophys. Res. 112, D09301 (2007). doi: 0.1029/2006JD007485.ADSGoogle Scholar
  8. 8.
  9. 9.
    J. W. Waters, L. Froidevaux, R. S. Harwood, R. F. Jarnot, H. M. Pickett, W. G. Read, P. H. Siegel, R. E. Cofield, M. J. Filipiak, D. A. Flower, J. R. Holden, G. K. Lau, N. J. Livesey, G. L. Manney, H. C. Pumphrey, M. L. Santee, D. L. Wu, D. T. Cuddy, R. R. Lay, M. S. Loo, V. S. Perun, M. J. Schwartz, P. C. Stek, R. P. Thurstans, M. A. Boyles, K. M. Chandra, M. C. Chavez, Chen. Gun-Shing, B. V. Chudasama, R. Dodge, R. A. Fuller, M. A. Girard, J. H. Jiang, Jiang. Yibo, B. W. Knosp, R. C. LaBelle, J.C. Lam, K. A. Lee, D. Miller, J. E. Oswald, N. C. Patel, D. M. Pukala, O. Quintero, D. M. Scaff, W. van Snyder, M. C. Tope, P. A. Wagner, and M. J. Walch, “The Earth Observing System Microwave Limb Sounder (EOS MLS) on the Aura satellite,” IEEE Trans. Geosci. Remote Sens. 44(5), 1075–1092 (2006).ADSCrossRefGoogle Scholar
  10. 10.
    G. Kopp, H. Berg, T. Blumenstock, H. Fischer, F. Hase, G. Hochschild, M. Hopfner, W. Kouke, T. Reddmann, R. Ruhnke, U. Raffalsk, Y. Kondo, “Evolution of ozone and ozone-related species over Kiruna during the SOLVE/THESEO 2000 campaign retrieved from ground-based millimeter-wave and infrared observations,” J. Geoph. Res., D 108(5), 8308 (2003). doi 10.1029/2001JD001064ADSGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2015

Authors and Affiliations

  • A. V. Polyakov
    • 1
    Email author
  • Yu. M. Timofeyev
    • 1
  • A. V. Poberovskii
    • 1
  • Ya. A. Virolainen
    • 1
  1. 1.St. Petersburg State UniversitySt. Petersburg, PetrodvoretsRussia

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