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Collisional broadening of CO2 lines by N2O pressure

  • Spectroscopy of Ambient Medium
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Abstract

Carbon dioxide line broadening coefficients by N2O pressure, as well as their temperature exponents, were calculated for a wide range of rotational quantum numbers in the 0001–1000 band. A semiempiric method that is based on the semiclassical broadening theory was used. It showed good results in calculations of half-widths and shifts of lines by pressure for H2O-N2(O2), CO2-N2(O2), and O3-N2(O2) systems. The calculated collisional half-widths were compared with the measured data obtained with a frequency-stabilized tunable CO2 laser for 11 vibrational-rotational transitions with rotational quantum numbers of the lower state to 38 at room temperature and for three transitions R(10), R(22), and R(32) in the temperature interval of 300 ≤ T ≤ 700 K in the 0001–1000 band. The calculated and measured data are in a good agreement.

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Authors and Affiliations

  1. V.E. Zuev Institute of Atmospheric Optics, Siberian Branch, Russian Academy of Sciences, pl. Akademika Zueva 1, Tomsk, 634021, Russia

    A. S. Dudaryonok & N. N. Lavrentieva

  2. Institute of Technical Acoustics, National Academy of Sciences, pr. Lyudnikova 13, Vitebsk, 210023, Belarus

    K. I. Arshinov

  3. Belarus National Technical University, ul. Ya. Kolasa 22, Minsk, 220027, Belarus

    V. V. Nevdakh

Authors
  1. A. S. Dudaryonok
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  2. N. N. Lavrentieva
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  3. K. I. Arshinov
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  4. V. V. Nevdakh
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Correspondence to A. S. Dudaryonok.

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Original Russian Text © A.S. Dudaryonok, N.N. Lavrentieva, K.I. Arshinov, V.V. Nevdakh, 2012, published in Optica Atmosfery i Okeana.

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Dudaryonok, A.S., Lavrentieva, N.N., Arshinov, K.I. et al. Collisional broadening of CO2 lines by N2O pressure. Atmos Ocean Opt 25, 12–18 (2012). https://doi.org/10.1134/S1024856012010034

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