Abstract
Preliminary results of investigation of the possibility of developing the method of air express analysis for detecting the isotope composition of atmospheric water vapors with the use of subterahertz and terahertz nonstationary spectroscopy methods are presented. Particular attention is paid to the real time detection of the background and minimally detectable concentrations of heavy water vapors in the atmosphere.
Similar content being viewed by others
References
Industrial Ecology and Global Change, Ed. by R. Socolow, C. Andrews, F. Berkhout, and V. Thomas (Cambridge Univ., Cambridge, 1994).
N. N. Ponomarev-Stepnoi, V. V. Kuznetsov, A. Y. Gagarinskii, E. J. Moniz, R. Gottemoeller, and D. Poneman, “The Future of Nuclear Power: Energy, Ecology, and Safety,” At. Energy 93, 855–865 (2002).
Safety and Ecology, Official Web-Site of ‘Rosenergoatom’ FGUP Concerne, http://www.rosenergoatom.ru/rus/safety-and-ecology/
O. I. Vasilenko, Radiation Ecology (Meditsina, Moscow, 2004) [in Russian].
A. I. Nadezhdinskii, Sh. Sh. Nabiev, G. Yu. Grigoriev, I. E. Vyazov, S. L. Malyugin, Yu. N. Ponomarev, Ya. Ya. Ponurovskii, D. B. Stavrovskii, and D. A. Bolyasov, “Express-Methods of Measurement of the Degree of Enrichment of Uranium Hexafluoride and Trace Quantities of UF6 and NF in Atmosphere on the Basse of Diod Lasers in Near and Mean IR Range,” Opt. Atmos. Okeana 18, 797–806 (2005).
B. Ya. Galkin, L. I. Gedeonov, and N. N. Demidovich, “Outlet Into Atmosphere of Volatile Fission Products during NPP Work and Regeneration Devices of Exhaust Fuel and Prospects of Their Catching,” Atom. Energ. 44, 145–149 (1978).
V. C. Marshall, Major Chemical Hazards (Ellis Horwood, Chichester, 1987).
Sh. Sh. Nabiev and Yu. N. Ponomarev, “Spectrochemical Aspects of Remote Laser Control of Emergency Ejection on Objects of Nuclear Fuel Cycle,” Opt. Atmos. Okeana 11, 1274–1280 (1998).
Nuclear Security: Global Directions for the Future (IAEA, London, 2006).
Isotopes. Properties, Production, Application, in 2 Vols., Ed. by V. Yu. Baranov (Fizmatlit, Moscow, 2005) [in Russian].
G. Yu. Grigoriev, S. L. Malyugin, Sh. Sh. Nabiev, A. I. Nadezhdinskii, Ya. Ya. Ponurovskii, and M. A. Sukhanova, “On Possibility of Using of Laser-Spectral Method for Control for Hazard Substance Emissions on NFC Objects,” At. Energ. 105, 217–225 (2008) [At. Energy 1005, 280 (2008)].
E. P. Magomedbekov, M. B. Rozenkevich, and N. G. Zhavoronkova Physico-Chemical Methods of Isotope Analysis and Very Pure Substances (RKhTU, Moscow, 2002) [in Russian].
Yu. A. Barbalat, I. P. Kalinkin, V. I. Mosichev, G. V. Saidov, and O. V. Sverdlova, New Handbook of Chemist’s and Technologist, Analytical Chemistry, Pt. III, Ed. by I. P. Kalinkin (Professional, St.-Petersburg, 2004) [in Russian].
Tritium Handling and Safe Storage, DOE Handbook, DOE-HDBK-1129-2008 (U.S. Department of Energy, Washington, DC, 2008).
L. F. Belovodskii, V. K. Gaevoi, and V. I. Grishmanovskii, Tritium (Energoatomizdat, Moscow, 1985) [in Russian].
G. Grigoriev, Sh. Nabiev, A. Nadezhdinskii, Ya. Ponurovskii, and D. Stavrovskii, “Diode Laser Spectroscopy of Water Isotopomers in Near IR,” in Proceedings of the 7th International Conference on Tunable Diode Laser Spectroscopy (Zermatt, 2009), p. 27.
G. Yu. Grigoriev, Sh. Sh. Nabiev, A. I. Nadezhdinskii, Ya. Ya. Ponurovskii, and D. B. Stavrovskii, “Diode Laser Spectroscopy of Vapours of Heavy and Super-heavy Water in Near IR,” in Proceedings of the 24th Workshop on Spectroscopy (Moscow, Troitsk, 2010), pp. 70–71.
Sensing with Terahertz Radiation, Ed. by D. Mittleman (Springer, Heidelberg, 2002).
Terahertz Spectroscopy: Principles and Applications, Ed. by S. Dexheimer (CRC, New York, 2007).
Yun-Shik Lee, Principles of Terahertz Science and Technology (Springer, Berlin, Heidelberg, 2008).
M. Exter, C. Fattinger, and D. Grischkowsky, “Terahertz Time-Domain Spectroscopy of Water Vapor,” Opt. Lett. 14, 1128–1130 (1989).
X. Xin, H. Altan, A. Saint, D. Matten, and R. R. Alfano, “Terahertz Absorption Spectrum of Para and Ortho Water Vapors at Different Humidities at Room Temperature,” J. Appl. Phys. 100, 094905 (2006).
V. L. Vaks, A. B. Brailovsky, and V. V. Khodos, “Millimeter Range Spectrometer with Phase Switching-Novel Method for Reaching of the Top Sensitivity,” Infrared Millim. Waves 20, 883–896 (1999).
V. L. Vaks, A. N. Panin, S. A. Basov, A. V. Illyuk, S. I. Pripolzin, D. G. Pavel’ev, and Yu. I. Koshurinov, “Nonstationary Spectroscopy of 1-2.5 THs Frequence Range on Solid State Devices,” Izv. Vyssh. Uchebn. Zaved., Radiofiz. 52, 569–575 (2009).
V. L. Vaks, E. G. Domracheva, S. D. Nikiforov, E. A. Sobakinskaya, and M. B. Chernyaeva, “Application of Microwave Nonstationary Spectroscopy for Noninvasive Medical Diagnostics,” Izv. Vyssh. Uchebn. Zaved., Radiofiz. 51, 490–498 (2008).
J. H. Seinfeld and S. N. Pandis, Atmospheric Chemistry and Physics: from Air Pollution to Climate Change, 2nd ed. (Wiley-Intersci., New York, 2006).
B. M. Andreev, Ya. D. Zel’venskii, and S. G. Katal’nikov, Heavy Hydrogen Isotopes in Nuclear Technique (Energoatomizdat, Moscow, 1987) [in Russian].
E. Evans, Tritium and Its Compounds (London, Butterworths, 1966; Atomizdat, Moscow, 1970).
Advances in Chemical Physics, Vol. 141, Ed. by S. A. Rice (Wiley-Intersci., New York, 2009).
A. Yu. Toptygin, K. G. Gribanov, V. I. Zakharov, Ya. Kasai, A. Kagava, Ya. Murayama, R. Imasu, G. A. Shmidt, G. Khoffmann, and Zh. Zhuzel’, “Determination of HDO/H2O Vertical Profile from High Resolution Spectra of Atmosphere Transmission,” Opt. Atmos. Okeana 20, 247–252 (2007).
H. Herbin, D. Hurtmans, C. Clerbaux, L. Clarisse, and P.-F. Coheur, “H2 16O and HDO Measurements with IASI/MetOp,” Atmos. Chem. Phys. 9, 9433–9447 (2009).
S. Brünken, H. S. P. Müller, C. P. Endres, T. F. Giesen, H. Mäder, J. C. Pearson, and B. J. Drouin, “Measurements and Analysis of High Resolution Terahertz Spectra of Water,” in Proceedings of the 231st Symposium of the International Astronomical Union, Pacific Grove, California, USA, 2005, p. 134.
B. L. Yu, Y. Yang, F. Zeng, X. Xin, and R. R. Alfano, “Terahertz Absorption Spectrum of D2O Vapor,” Opt. Commun. 258, 256–263 (2006).
S. Brünken, H. S. P. Müller, C. P. Endres, F. Lewen, T. F. Giesen, B. J. Drouin, J. C. Pearson, and H. Mäder, “High Resolution Rotational Spectroscopy on D2O up to 2.7 THz in Its Ground and First Excited Vibrational bending States,” Phys. Chem. Chem. Phys. 9, 2103–2112 (2007).
G. Grigoriev, J. Jo, Sh. Nabiev, A. Nadezhdinskii, Ya. Ponurovskii, U. Rohatgi, and D. Stavrovskii, “HTO Detection Using TDLS,” in Proceedings of the 7th International Conference on Tunable Diode Laser Spectroscopy (TDLS-2009) (Zermatt, Switzerland, 2009), p. 107.
G. Yu. Grigoriev, Sh. Sh. Nabiev, A. I. Nadezhdinskii, Ya. Ya. Ponurovskii, and D. B. Stavrovskii, “Diode Laser Spectroscopy of Heavy and Super-Heavy Water Vapors in the Near-IR Range,” in Proceedings of the International Workshop on Non-Proliferation and Nuclear Materials (Obninsk, 2009), pp. 46–48.
Combining Quantum Mechanics and Molecular Mechanics, Some Recent Progresses in QM/MM Methods, Ed. by S. Canuto and J. R. Sabin (Academic Press, New York, 2010).
M. A. Belkin, Q. J. Wang, C. Pflugl, A. Belyanin, S. P. Khanna, A. G. Davies, E. H. Linfield, and F. Capasso, “High-Temperature Operation of Terahertz Quantum Cascade Laser Sources,” IEEE J. Sel. Top. Quantum. Electron. 15, 952–967 (2009).
G. N. Gol’tsman and D. N. Ludkov, “Terahertz Superconducting Hot-Electron Bolometer Mixers and Their Application in Radio Astronomy,” Izv. Vyssh. Uchebn. Zaved., Radiofiz. 46, 671–686 (2003).
J. Chen, L. Kang, B. B. Jin, W. W. Xu, P. H. Wu, W. Zhang, L. Jiang, N. Li, S. C. Shi, and G. N. Gol’tsman, “Properties of Terahertz Superconducting Hot Electron Bolometer Mixers,” Terahertz Sci. Technol. 1, 37–41 (2008).
Author information
Authors and Affiliations
Additional information
Original Russian Text © Sh.Sh. Nabiev, V.L. Vaks, E.G. Domracheva, L.A. Palkina, S.I. Pripolzin, E.A. Sobakinskaya, M.B. Chernyaeva, 2011, published in Optica Atmosfery i Okeana.
Rights and permissions
About this article
Cite this article
Nabiev, S.S., Vaks, V.L., Domracheva, E.G. et al. Express analysis of water isotopomers in the atmosphere with the use of nonstationary subterahertz and terahertz spectroscopy methods. Atmos Ocean Opt 24, 402–410 (2011). https://doi.org/10.1134/S1024856011040129
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1024856011040129