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Experimental study by the IR spectroscopy method of the interaction between ethylene and nanopores of various densities

Abstract

The combination vibrational bands ν5 + ν9 and ν1 + ν11 of ethylene absorption adsorbed by silica aerogel nanopores of different densities have been studied for the first time in the 5700- to 6300-cm−1 spectral region. The conducted measurements show significant differences between the spectra of ethylene in aerogels and ethylene in the gas phase, which consist of the change of the absorption band shapes, the shift of the band frequency, and the increase of the absorption intensity. It was concluded that in the studied pressure range of 88–952 mbar, the adsorbed ethylene is in the same structural state.

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References

  1. L. Little, Infrared Spectra of Adsorbed Molecules (Academic, New York, 1966; Mir, Moscow, 1969).

    Google Scholar 

  2. A. I. Gusev, Nanomaterials, Nanostructures, Nanotechnologies (Fizmatlit, Moscow, 2007) [in Russian].

    Google Scholar 

  3. I. Scheele, A. Conjusteau, C. Callegari, R. Schmied, K. K. Lehmann, and G. Scoles, “Near-Infrared Spectroscopy of Ethylene and Ethylene Dimer in Superfluid Helium Droplets,” J. Chem. Phys. 122(3), 104307-1–104307-4 (2005).

    ADS  Google Scholar 

  4. U. Buck and B. Schmidta, “Frequency Shifts in Infrared Spectra of Ethylene Clusters,” J. Chem. Phys. 101(7), 6365–6366 (1994).

    Article  ADS  Google Scholar 

  5. W. Zhou, T. Yildirim, E. Durgun, and S. Ciraci, “Hydrogen Absorption Properties of Metal-Ethylene Complexes,” Phys. Rev. B 76, 085434-1–085434-9 (2007).

    ADS  Google Scholar 

  6. T. Platz and W. Demtröder, “Sub-Doppler Optothermal Overtone Spectroscopy of Ethylene and Dichloroethylene,” Chem. Phys. Lett. 294, 397–405 (1998).

    Article  ADS  Google Scholar 

  7. M. Bach, R. Georges, M. Herman, and A. Perrin, “Investigation of the Fine Structure in Overtone Absorption Bands of 12C2H4,” Mol. Phys. 97(1), 265–277 (1999).

    Article  ADS  Google Scholar 

  8. Yu. N. Ponomarev and V. A. Kapitanov, “High Resolution Ethylene Absorption Spectrum between 6035 and 6210 cm−1,” Appl. Phys. B 90(2), 235–241 (2008).

    Article  ADS  Google Scholar 

  9. H. Liu and R. J. Hamers, “Stereoselectivity in Molecule-Surface Reactions: Adsorption of Ethylene on the Silicon (001) Surface,” J. Am. Chem. Soc. 119(32), 7593–7594 (1997).

    Article  Google Scholar 

  10. S. Namuangruk, P. Pantu, and J. Limtrakul, “Investigation of Ethylene Dimerization over Faujasite Zeolite by the ONIOM Method,” Chem. Phys. Chem. 6(7), 1333–1339 (2005).

    Google Scholar 

  11. Y.-Y. Huang, “Ethylene Complexes in Copper (l) and Silver (I) Y Zeolites,” J. Catal. 61(2), 461–476 (1980).

    Article  Google Scholar 

  12. V. Bernardet, A. Decrette, J. M. Simon, O. Bertrand, G. Weber, and J. P. Bellat, “Experimental and Simulated Infrared Spectroscopic Studies of the Interaction of Ethylene on a MFI Zeolite,” Mol. Phys. 102, 1859–1870 (2004).

    Article  ADS  Google Scholar 

  13. R. Georges, M. Bach, and M. Herman, “The Vibrational Energy Pattern in Ethylene (12C2H4),” Mol. Phys. 97(1), 279–292 (1999).

    Article  ADS  Google Scholar 

  14. Yu. N. Kharzheev, “Use of Silica Aerogels in Cherenkov Counters,” Fiz. Elem. Chastits At. Yadra 39(1), 271–325 (2008) [Phys. Part. Nucl. 39, 107 (2008)].

    Google Scholar 

  15. T. Inagaki, H. Yonenobu, and S. Tsuchikawa, “Near-Infrared Spectroscopic Monitoring of the Water Adsorption/Desorption Process in Modern and Archaeological Wood,” Appl. Spectrosc. 62(8), 860–865 (2008).

    Article  ADS  Google Scholar 

  16. S. Tsuchikawa and S. Tsutsumi, “Adsorptive and Capillary Condensed Water in Biological Material,” J. Mater. Sci. Lett. 17(8), 661–663 (1998).

    Article  Google Scholar 

  17. Yu. N. Ronomarev, T. M. Retrova, A. M. Solodov, and A. A. Solodov, “Spectroscopic Properties of Some Atmospheric Gases in Aerogel Nanopores,” in Proc. of the 16th Intern. Symp. on High Resolution Molecular Spectroscopy, Pos. Listvyanka, July, 2009, p. 171.

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Original Russian Text © Yu.N. Ponomarev, T.M. Petrova, A.M. Solodov, A.A. Solodov, A.F. Danilyuk, 2010, published in Optica Atmosfery i Okeana.

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Ponomarev, Y.N., Petrova, T.M., Solodov, A.M. et al. Experimental study by the IR spectroscopy method of the interaction between ethylene and nanopores of various densities. Atmos Ocean Opt 23, 266–269 (2010). https://doi.org/10.1134/S1024856010040044

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  • DOI: https://doi.org/10.1134/S1024856010040044

Keywords

  • Zeolite
  • Ethylene Absorption
  • Aerogel Sample
  • Adsorbed Ethylene
  • Silica Dioxide