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Peculiarities of the Electrochemical Behavior of Chlorophenoxy-Substituted Phthalocyanines of Cobalt and Copper in Non-Aqueous Media

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Abstract

The electrochemical behavior of tetra-4-[4-(2,4,5-trichlorophenoxy)]phthalocyaninates of cobalt(II) (CoPc) and copper(II) (CuPc) in N,N-dimethylformamide with 0.1 M nBu4NBF4 as a supporting electrolyte is studied by cyclic voltammetry. It is shown experimentally that both metal complexes are capable of irreversible reduction. In this case, the reverse CV-scan for CoPc demonstrates an oxidation peak which is absent in the anodic scan and corresponds to the cathodic reaction product. The metal complexes themselves are not oxidized under these conditions.

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ACKNOWLEDGMENTS

The study was carried out using the resoursces of the Center for Shared Use of Scientific Equipment of the Ivanovo State University of Chemistry and Technology (with the support of the Ministry of Science and Higher Education of the Russian Federation, grant no. 075-15-2021-671). The studies by I.F. Sakhapov, Z.N. Gafurov, and D.G. Yakhvarov were supported by the State Project of the Federal Research Center of the Kazan Scientific Center of the Russian Academy of Sciences.

Funding

This study was financially supported by the Council for Grants of the President of the Russian Federation (project no. MK-4839.2022.1.3).

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, Ivanovo, Russia

    M. A. Kovanova, T. V. Tikhomirova & A. S. Vashurin

  2. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of Russian Academy of Sciences, Kazan, Russia

    I. F. Sakhapov, Z. N. Gafurov & D. G. Yakhvarov

Authors
  1. M. A. Kovanova
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  2. T. V. Tikhomirova
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  3. I. F. Sakhapov
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  4. Z. N. Gafurov
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  5. D. G. Yakhvarov
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  6. A. S. Vashurin
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Corresponding author

Correspondence to M. A. Kovanova.

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The authors declare that they have no conflict of interest.

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Translated by T. Safonova

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Kovanova, M.A., Tikhomirova, T.V., Sakhapov, I.F. et al. Peculiarities of the Electrochemical Behavior of Chlorophenoxy-Substituted Phthalocyanines of Cobalt and Copper in Non-Aqueous Media. Russ J Electrochem 59, 646–650 (2023). https://doi.org/10.1134/S1023193523090070

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  • DOI: https://doi.org/10.1134/S1023193523090070

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