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Oxygen-Ionic Conductivity in Isovalent-Doped Layered BaLaInO4-Based Perovskites

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Abstract—

The oxygen-ionic conductivity of isovalent-doped complex oxides characterized by the Ruddlesden–Popper structure is studied. The BaLa0.9Nd0.1InO4 sample was obtained for the first time by substitution in the La sublattice, and its transport properties are studied. A comparing of the results with the data for samples obtained earlier by isovalent substitution in the In-sublattice of BaLaInO4 is presented. The introducing of a dopant is shown to lead to increase in the contribution from oxygen-ionic conductivity and also in the total conductivity by ~2 orders of magnitude.

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Funding

This work was supported by the Russian Science Foundation, project no. 22-79-10003.

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Authors and Affiliations

  1. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    A. O. Bedarkova, P. V. Cheremisina, E. V. Abakumova, K. G. Davletbaev, N. A. Tarasova & I. E. Animitsa

  2. Ural Federal University named after the first President of Russia B.N. Eltsin, Yekaterinburg, Russia

    A. O. Bedarkova, P. V. Cheremisina, E. V. Abakumova, I. S. Fedorova, K. G. Davletbaev, N. A. Tarasova & I. E. Animitsa

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  1. A. O. Bedarkova
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  2. P. V. Cheremisina
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  3. E. V. Abakumova
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  4. I. S. Fedorova
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  5. K. G. Davletbaev
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  6. N. A. Tarasova
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  7. I. E. Animitsa
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Correspondence to A. O. Bedarkova.

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The authors declare that they have no conflict of interest.

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Translated by Yu. Pleskov

Based on the materials of the 16th International Meeting “Fundamental Problems of Solid State Ionics,” Chernogolovka, June 27–July 7, 2022.

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Bedarkova, A.O., Cheremisina, P.V., Abakumova, E.V. et al. Oxygen-Ionic Conductivity in Isovalent-Doped Layered BaLaInO4-Based Perovskites. Russ J Electrochem 59, 269–275 (2023). https://doi.org/10.1134/S1023193523040031

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  • DOI: https://doi.org/10.1134/S1023193523040031

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