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Cold-Rolled Binary Palladium Alloys with Copper and Ruthenium: Injection and Extraction of Atomic Hydrogen

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Abstract

The effect of annealing and chemical composition of cold-rolled palladium–copper (57 at % Cu) and palladium–ruthenium (6 at % Ru) alloys on the processes of injection and extraction of atomic hydrogen in an aqueous solution of 0.1 M H2SO4 was studied by two-stage cathode–anode chronoamperometry. The close values of the parameters of hydrogen permeability, found from the cathode and anode chronoamperograms, indicate a low level of imperfection of the alloy structure. It has been established that the choice of a mathematical model for processing the chronoamperometry results is determined by the thickness of the alloy samples. The finite-thickness model can be applied if the sample thickness does not exceed 10 µm. Preliminary annealing of samples leads to a decrease in hydrogen permeability and an increase in the effective rate constants of the injection and extraction of atomic hydrogen. At the same time, the palladium-ruthenium alloy is characterized by a higher rate of diffusion mass transfer, while the copper–palladium alloy is characterized by increased values of the kinetic parameters of atomic hydrogen transfer.

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Notes

  1. The palladium alloy samples were produced at the Baikov Institute of Metallurgy and Materials Science of the Russian Academy of Sciences.

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Funding

This work was supported by the Russian Science Foundation (project no. 19-19-00232).

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Authors and Affiliations

  1. Voronezh State University, 394018, Voronezh, Russia

    A. I. Fedoseeva, N. B. Morozova, A. I. Dontsov, O. A. Kozaderov & A. V. Vvedenskii

  2. Baikov Institute of Metallurgy and Materials Science, Russian Academy of Sciences, 119334, Moscow, Russia

    A. I. Dontsov

Authors
  1. A. I. Fedoseeva
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  2. N. B. Morozova
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  3. A. I. Dontsov
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  4. O. A. Kozaderov
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  5. A. V. Vvedenskii
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Correspondence to N. B. Morozova.

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Translated by E. Chernokozhin

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Fedoseeva, A.I., Morozova, N.B., Dontsov, A.I. et al. Cold-Rolled Binary Palladium Alloys with Copper and Ruthenium: Injection and Extraction of Atomic Hydrogen. Russ J Electrochem 58, 812–822 (2022). https://doi.org/10.1134/S1023193522090051

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