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Electrocatalytic Reduction of Carbon Dioxide to Formic Acid on Sn- and Bi-Based Gas-Diffusion Electrodes in Aqueous Media (a Review)

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Abstract

Carbon dioxide, as a greenhouse gas, is one of the most significant contributors to climate changes on the planet. The CO2 electrocatalytic reduction to value-added products is the key to the achieving of practical renewable energy conversion and storage, as well as green chemical production based on the CO2 and H2O. Sn- and Bi-based electrocatalysts are considered being the most promising for the electrolytic reduction of CO2 to formic acid, which has a wide range of applications, a pure hydrogen carrier, in particular. Due to the low solubility of carbon dioxide in aqueous solutions, the most promising high-rate and selective electrodes for its reduction are gas-diffusion electrodes, which make it possible to overcome restrictions on the mass transfer of the substrate (CO2) to a highly developed three-phase contact surface. In this review, we have systematized the most significant practical results obtained over the 2019–2021 period by various research groups in the electrocatalytic reduction of carbon dioxide to formic acid in aqueous electrolyte solutions at gas-diffusion electrodes based on Sn and Bi and their compounds.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation.

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Authors and Affiliations

  1. Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Federal Research Center “Krasnoyarsk Scientific Center”, 660036, Krasnoyarsk, Russia

    V. L. Kornienko, G. A. Kolyagin & O. P. Taran

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  1. V. L. Kornienko
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  2. G. A. Kolyagin
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  3. O. P. Taran
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Correspondence to V. L. Kornienko or G. A. Kolyagin.

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Translated by Yu. Pleskov

A tribute to outstanding electrochemist Oleg Aleksandrovich Petrii (1937–2021).

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Kornienko, V.L., Kolyagin, G.A. & Taran, O.P. Electrocatalytic Reduction of Carbon Dioxide to Formic Acid on Sn- and Bi-Based Gas-Diffusion Electrodes in Aqueous Media (a Review). Russ J Electrochem 58, 647–657 (2022). https://doi.org/10.1134/S1023193522080079

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