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Bimetallic Alkoxocomplexes of Rhenium, Cobalt, and Nickel as Precursors for Alloys Production

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Abstract

Rhenium alkoxocomplexes (Re4O6(OMe)12) and Re4O6(OPri)10) were obtained by the anodic dissolution of rhenium. The complexes were studied using the IR spectrometry and Energy Dispersive Analysis. Bimetallic rhenium–nickel alkoxocomplexes (Re4 – xNixO6(OMe)12, Re4 – xNixO6(OPri)10) and rhenium–cobalt alkoxocomplexes (Re4 – xCoxO6(OMe)12, Re4 – xCoxO6(OPri)10) were synthesized of monometallic alkoxocomplexes and characterized using the IR spectrometry. It is shown that homogeneous bimetallic powder of Re0.79Ni0.21 alloy can be produced of rhenium–nickel methylate and isopropylate and the powder of Re0.67Co0.33 alloy, of rhenium–cobalt methylate using the reduction in the hydrogen atmosphere at a temperature of 650°C and a pressure of 5 atm.

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Funding

The work was supported by the MIREA project NICh ICMR 21/2020.

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Authors and Affiliations

  1. National Research Center “Kurchatov Institute”, Moscow, Russia

    E. S. Kulikova

  2. MIREA—Russian Technological University, Moscow, Russia

    O. V. Chernyshova & D. V. Iordan

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    I. A. Mikheev & D. V. Drobot

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  1. E. S. Kulikova
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  2. O. V. Chernyshova
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Correspondence to E. S. Kulikova.

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Translated by T. Kabanova

Published based on the materials of the VII All-Russian Conference with International Participation “Fuel Cells and Power Plants Based on Them”, Chernogolovka, 2020.

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Kulikova, E.S., Chernyshova, O.V., Iordan, D.V. et al. Bimetallic Alkoxocomplexes of Rhenium, Cobalt, and Nickel as Precursors for Alloys Production. Russ J Electrochem 58, 131–135 (2022). https://doi.org/10.1134/S1023193522020057

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