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Solid-State Synthesis of SnO2–Zn2SnO4 Nanocomposite and Its Application for Electrochemical Detection of Cabergoline as Dopamine Receptor Antagonists

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Abstract

In the present work, the synthesis of SnO2–Zn2SnO4 nanocomposite was fulfilled according to solid-state technique followed by calcination. The SnO2–Zn2SnO4 nanocomposites were specified by X-ray diffraction and scanning electron microscopy. Then, oxidation response of cabergoline (Cab) was investigated on the surface of SnO2–Zn2SnO4 modified carbon paste electrode (SnO2–Zn2SnO4/CPE), exhibiting a well-defined single oxidation peak at +0.84 V vs. Ag/AgCl, NaCl (3 M) in an irreversible process. In oxidation reaction of Cab, equal number of protons and electrons are participated and the oxidation reaction rate is controlled by an adsorption step. The calibration curve from differential pulse voltammetry showed linearity in the concentration range of 3.0 to 155.0 µM (R2 = 0.9936) and detection limit was calculated to be 0.01 µM. The analysis results certified that SnO2–Zn2SnO4/CPE possess considerable potential to detect Cab in biological fluids.

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ACKNOWLEDGMENTS

The authors gratefully acknowledge the Research Council of Payame Noor University for support this work and Mrs Atefeh Naghsh for review the manuscript.

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Authors and Affiliations

  1. Department of Chemistry, Payame Noor University, 19395-4697, Tehran, Iran

    Masoumeh Taei

  2. Department of Biochemistry, Falavarjan Branch, Islamic Azad University, Isfahan, Iran

    Masoud Fouladgar

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  1. Masoumeh Taei
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  2. Masoud Fouladgar
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Correspondence to Masoud Fouladgar.

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Masoumeh Taei, Masoud Fouladgar Solid-State Synthesis of SnO2–Zn2SnO4 Nanocomposite and Its Application for Electrochemical Detection of Cabergoline as Dopamine Receptor Antagonists. Russ J Electrochem 58, 1–9 (2022). https://doi.org/10.1134/S1023193522010141

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  • DOI: https://doi.org/10.1134/S1023193522010141

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