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Oxygen-Ion and Proton Transport in Sc-Doped Layered Perovskite BaLaInO4

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Abstract—The effect of isovalent doping Sc3+ → In3+ on the transport properties is studied for complex oxide BaLaInO4 characterized by the Ruddlesden–Popper structure. It is shown that the introduction of scandium increases the oxygen-ionic and protonic conductivity. In the humid air atmosphere at 500°С, both BaLaInO4 and BaLaIn0.9Sc0.1O4 are the protonic conductors with ~90–95% contribution of proton transfer.

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Authors and Affiliations

  1. Ural Federal University named after the First President of Russia B.E. Yel’tsin, Yekaterinburg, Russia

    N. A. Tarasova, A. O. Galisheva, I. E. Animitsa & E. L. Lebedeva

  2. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Russia

    N. A. Tarasova & I. E. Animitsa

Authors
  1. N. A. Tarasova
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  2. A. O. Galisheva
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  3. I. E. Animitsa
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  4. E. L. Lebedeva
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Correspondence to A. O. Galisheva or I. E. Animitsa.

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The authors declare that they have no conflict of interest.

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Translated by T. Safonova

Based on the materials of the report at the 15th International Meeting “Fundamental Problems of Solid State Ionics”, Chernogolovka, 30.11.–07.12.2020.

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Tarasova, N.A., Galisheva, A.O., Animitsa, I.E. et al. Oxygen-Ion and Proton Transport in Sc-Doped Layered Perovskite BaLaInO4. Russ J Electrochem 57, 1008–1014 (2021). https://doi.org/10.1134/S1023193521080127

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  • DOI: https://doi.org/10.1134/S1023193521080127

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