Abstract—
Composite electroactive materials of polyaniline and manganese oxide (MnOx) are obtained via layer-by-layer potentiodynamic deposition of MnOx from MnSO4 aqueous solutions on a stainless-steel electrode and subsequent electrosynthesis of polyaniline from aniline sulfate in 1 M H2SO4 on the MnOx surface. The composite electroactive materials demonstrated the characteristic redox properties of polyaniline in acidic aqueous solution. Characterization of the composite electroactive materials by the XPS method showed the amorphous nature of MnOx in the films in which manganese was in the +2, +3, and +4 oxidation states. The composite materials showed higher values of the specific capacitance (up to 2000 F/g on a weight of deposited-polyaniline basis) as compared with the pure polyaniline coating (228 F/g), measured at 1.0 A/g in 1 M H2SO4 solution. The composite electroactive materials obtained layerwise retained 90–100% of their capacitance after 2500 cycles and 500 charge–discharge cycles, with a Coulomb efficiency of 98%.
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REFERENCES
Frackowiak, E., Jurewicz, K., Delpeux, S., and Beguin, F., Nanotubular materials for supercapacitors, J. Power Sources, 2001, vol. 97, p. 822.
Prasada, K.R. and Miura, N., Polyaniline-MnO2 Composite Electrode for High Energy Density Electrochemical Capacitor, Electrochem. Solid-State Lett., 2004, vol. 7, p. A425.
Reddy, R.N. and Reddy, R.G., Sol–gel MnO2 as an electrode material for electrochemical capacitors, J. Power Sources, 2003, vol. 124, p. 330.
Miura, N., Onishi, S., and Prasad, K.R., Electrochemically deposited nanowhiskers of nickel oxide as a high-power pseudocapacitive electrode, Electrochem. Solid-State Lett. 2004, vol. 7, p. A247.
Reshetniak, O.V., Yatsyshym, M.M., and Bazilyak, L.I., Polyaniline: the role of particules of radical nature in obtaining of polymer/copolymers with system of conjugated π-bands, Mater. Lett., 2004, vol. 58, p. 3257.
Long, J.W., Young, A.L., and Rolison D.R., Spectroelectrochemical Characterization of Nanostructured, Mesoporous Manganese Oxide in Aqueous Electrolytes, J. Electrochem. Soc., 2003, vol. 150, p. A1161.
Xiea, Yi, Yanga, Ch., Chena, P., Yuana, D., and Guoa, K., MnO2-decorated hierarchical porous carbon composites for high performance asymmetric supercapacitors, J. Power Sources, 2019, vol. 425, p. 1.
Feng, X., Li, Y., Chen, G., Liu, Z., Ning, X., Hu, A., Tang, Q., and Chen, X., Free-standing MnO2/nitrogen-doped graphene paper hybrids as binder-free electrode for supercapacitor applications, Mater. Lett., 2018, vol. 231, p. 114. https://doi.org/10.1016/j.matlet.2018.08.026
Prasad, K.R. and Miura, N., Potentiodynamically deposited nanostructured manganese dioxide as electrode material for electrochemical redox supercapacitors, J. Power Sources, 2004, V. 135, P. 354.
Jaidev, Razzak, I.J., Ashish, K.M., and Ramaprabhu, S., Polyaniline–MnO2 nanotube hybrid nanocomposite as supercapacitor electrode material in acidic electrolyte, J. Mater. Chem., 2011, vol. 21, p. 17601.
Zhang, X., Ji, L., Zhang, Sh., and Yang, W., Synthesis of a novel polyaniline-intercalated layered manganese oxide nanocomposite as electrode material for electrochemical capacitor, J. Power Sources, 2007, vol. 173, p. 1017. https://doi.org/10.1016/j.jpowsour.2007.08.083
Ghasemi, S., Hosseini, S.R., and Boore-Talari, O., Sonochemical assisted synthesis MnO2/RGO nanohybrid as effective electrode material for supercapacitor, Ultrason. Sonochem., 2018, vol. 40, p. 675. https://doi.org/10.1016/j.ultsonch.2017.08.013
Sun, L.-J., Liu, X.-X., Lau, K.K., Chen, L., and Gu, W.-M., Electrodeposited hybrid films of polyaniline and manganese oxide in nanofibrous structures for electrochemical supercapacitor, Electrochim. Acta, 2008, vol. 53, p. 3036.
Hu, C.-C. and Wang, C.-C., Nanostructures and Capacitive Characteristics of Hydrous Manganese Oxide Prepared by Electrochemical Deposition, J. Electrochem. Soc., 2003, vol. 150, p. A1079.
Radhamani, A.V., Surendra, M.K., and Ramachandra, Rao, M.S., Zn doped δ-MnO2 nano flakes: an efficient electrode material for aqueous and solid state asymmetric supercapacitors, Appl. Surf. Sci., 2018, vol. 450, p. 209. https://doi.org/10.1016/j.apsusc.2018.04.081
Sun, L.-J., Liu, X.-X., Lau, K.K.-T., Chen, L., and Gu, W.-M., Electrodeposited hybrid films of polyaniline and manganese oxide in nanofibrous structures for electrochemical supercapacitor, Electrochim. Acta, 2008, vol. 53, p. 3036.
Chigane, M. and Ishikawa, M., Manganese Oxide Thin Film Preparation by Potentiostatic Electrolyses and Electrochromism, J.Electrochem. Soc. 2000, vol. 147, p. 2246.
Cruz-Silva, R., Romero-García, J., Angulo-Sánchez, J.L., Flores-Loyola, E., and Díaz, J.A., Comparative study of polyaniline cast films prepared from enzymatically and chemically synthesized polyaniline, Polymer, 2004, vol. 45, p. 4711.
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The study is carried out according to the State Task АААА-А19-119071190044-3 and, in part, АААА-А19-119061890019-5. Equipment from the Analytical Core facilities center of Institute of Problems of Chemical Physics, RAS, and Research Center in Chernogolovka, RAS, was used.
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Translated by Yu. Pleskov
Based on the materials of the report at the 15th International Meeting “Fundamental Problems of Solid State Ionics”, Chernogolovka, 30.11.–07.12.2020.
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Abalyaeva, V.V., Efimov, O.N., Dremova, N.N. et al. Polyaniline–MnO2 Composite Electrode for Electrochemical Supercapacitor. Russ J Electrochem 57, 996–1007 (2021). https://doi.org/10.1134/S1023193521080036
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DOI: https://doi.org/10.1134/S1023193521080036