Skip to main content
SpringerLink
Log in

Electrical and Dielectric Properties of Sb2O3–PbCl2–AgCl Glass System

  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

Electrical and dielectric properties of ternary glasses in the Sb2O3–PbCl2–AgCl system were investigated across a broad temperature and frequency range. The studied glass system is interesting since it possesses a high ionic conductivity. The (Sb2O3)x–(PbCl2)100 –y – x–(AgCl)y glasses were prepared by melt-quenching method from high purity components. Different batches of these glasses were investigated with varying molar content of both Sb2O3 (45 ≤ x ≤ 70 mol %) and AgCl (5 ≤ y ≤ 25 mol %). The colour of the prepared chloro-antimonite glasses varies between yellow and brown. The glass transition temperature (Tg) decreases with increasing AgCl concentrations. DC and AC electrical conductivities and complex electrical modulus were measured across a temperature range from room temperature up to 200°C and across a frequency range between 0.2 and 105 Hz. The dependence of DC conductivity on temperature follows the so-called Arrhenius-like equation. The DC conductivity at constant temperature significantly increases with increasing AgCl or PbCl2 content. It was found that the activation energy of conduction process decreases with the substitution of PbCl2 by AgCl from 1 eV down to 0.56 eV for (Sb2O3)50-(PbCl2)45–(AgCl)5 and (Sb2O3)50–(PbCl2)25–(AgCl)25, respectively. The influence of the composition on the AC conductivity of the investigated glasses is also discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.

Similar content being viewed by others

REFERENCES

  1. Dubois, B., Aomi, H., Videau, J.J., Portier, J., and Hagenmuller, P., New oxyhalide glasses involving Sb2O3, Mat. Res. Bull., 1984, vol. 19, no. 10, p. 1317.

    Article  CAS  Google Scholar 

  2. Zavadil, J., Ivanova, Z.G., Kostka, P., Hamzaoui, M., and Soltani, M.T., Photoluminescence study of Er-doped zinc-sodium-antimonite glasses, J. Alloy. Compd., 2014, vol. 611, p. 111.

    Article  CAS  Google Scholar 

  3. Soltani, M.T., Hamzaoui, M., Houhou, S., Touiri, H., Bediar, L., Ghemri, A.M., and Petkova, P., Physical characterization of Sb2O3–M2O–MoO3 (M = Li, K) new glasses, Acta Phys. Pol. A, 2013, vol. 123, p. 227.

    Article  CAS  Google Scholar 

  4. Hamzaoui, M., Azri, S., Soltani, M.T., Lebullenger, R., and Poulain, M., Thermal and elastic characterization of Sb2O3–Na2O–ZnO glasses, Phys. Scr., 2013, vol. 157, p. 014029. https://doi.org/10.1088/0031-8949/2013/T157/014029

    Article  CAS  Google Scholar 

  5. Minelly, J. and Ellison, A., Applications of antimony-silicate glasses for fiber optic amplifiers, Opt. Fiber Technol., 2002, vol. 8, p. 123.

    Article  CAS  Google Scholar 

  6. Dubois, B., Videau, J.J., Couzi, M., and Portier, J., Structural approach of the (xPbCl2-(1-x)Sb2O3) glass system, J. Non-Cryst. Solids, 1986, vol. 88, p. 355.

    Article  CAS  Google Scholar 

  7. Bošák, O., Kostka, P., Minárik, S., Trnovcová, V., Podolinčiaková, J., and Zavadil, J., Influence of composition and preparation conditions on some physical properties of TeO2–Sb2O3–PbCl2 glasses, J. Non-Cryst. Solids, 2013, vol. 377, p. 74.

    Article  Google Scholar 

  8. Goumeidane, F., Legouera, M., Iezid, M., Poulain, M., Nazabal, V., and Lebullenger, R., Synthesis and physical properties of glasses in the Sb2O3–PbCl2–MoO3 system, J. Non-Cryst. Solids, 2011, vol. 357, p. 3572.

    Article  CAS  Google Scholar 

  9. Labaš, V., Poulain, M., Kubliha, M., Trnovcová, V., and Goumeidane, F., Electrical, dielectric and optical properties of Sb2O3–PbCl2–MoO3 glasses, J. Non-Cryst. Solids, 2013, vol. 377, p. 66.

    Article  Google Scholar 

  10. Macháček, J., Kostka, P., Liška, M., Zavadil, J., and Gedeon, O., Calculation and analysis of vibrational spectra of PbCl2–Sb2O3–TeO2 glass from first principles, J. Non-Cryst. Solids, 2011, vol. 357, p. 2562.

    Article  Google Scholar 

  11. Gedikoglu, N., Ersundu, M.C., Kostka, P., Basinova, N., and Ersundu, A.E., Investigating the influence of transition metal oxides on temperature dependent optical properties of PbCl2–TeO2 glasses for their evaluation as transparent large band gap semiconductors, J. Alloys Compd., 2018, vol. 748, p. 687.

    Article  CAS  Google Scholar 

  12. Poirier, G., Poulain, M., and Poulain, M., Copper and lead halogeno-antimoniate glasses, J. Non-Cryst. Solids, 2001, vol. 284, p. 117.

    Article  CAS  Google Scholar 

  13. Cozic, S., Bréhault, A., Usuki, T., and Le Coq, D., GeS2–Ga2S3–LiCl glass system: electrical conductivity and structural considerations, Int. J. Appl. Glass Sci., 2016, vol. 7, no. 4, p. 513.

    Article  CAS  Google Scholar 

  14. Castro, A., Bréhault, A., Carcreff, J., Bošák, O., Kubliha, M., Trnovcová, V., Dománková, M., Šiljegović, M., Calvez, L., Labaš, V., and Le Coq, D., Lithium and lead chloride antimonate glasses, J. Non-Cryst. Solids, 2018, vol. 499, p. 66.

    Article  CAS  Google Scholar 

  15. Sahar, M.R., Ahmed, M.M., and Holland, D., The crystallisation of Sb2O3–PbCl2–ZnCl2 glasses, Phys. Chem. Glasses, 1990, vol. 31, no. 3, p. 126.

    CAS  Google Scholar 

  16. Yezli, D., Legouera, M., El Abdi, R., Poulain, M., and Burgaud, V., Mechanical, thermal, and optical properties of new chloroantimonite glasses in the Sb2O3–PbCl2–AgCl system, Mat. Sci., 2016, vol. 52, no. 1, p. 33.

    Article  CAS  Google Scholar 

  17. Kubliha, M., Investigating Structural Changes and Defects of Non-Metallic Materials via Electrical Methods, 1 st ed., Dresden: Forschungszentrum Dresden-Rossendorf, 2009.

  18. Kalužný, J., Kubliha, M., Labaš, V., Poulain, M., and Taibi, Y., Electrical and dielectrical properties of Sb2O3–V2O5–K2O glasses, J. Non-Cryst. Solids, 2009, vol. 355, nos. 37–42, p. 2031.

    Article  Google Scholar 

  19. Kubliha, M., Soltani, M.T., Trnovcová, V., Legouera, M., Labaš, V., Kostka, P., Le Coq, D., and Hamzaoui, M., Electrical, dielectric, and optical properties of Sb2O3–Li2O–MoO3 glasses, J. Non-Cryst. Solids, 2015, vol. 428, p. 42.

    Article  CAS  Google Scholar 

  20. Moynihan, C.T., Boesch, L.P., and Laberge, N.L. Decay function for electric-field relaxation in-vitreous ionic conductors, Phys. Chem. Glasses, 1973, vol. 14, p. 122.

    CAS  Google Scholar 

  21. Molak, A., Paluch, M., Pawlus, S., Klimontko, J., Ujma, Z., and Gruszka, I., Electric modulus approach to the analysis of electric relaxation in highly conducting (Na0.75Bi0.25)(Mn0.25Nb0.75)O3 ceramics, J. Phys. D: Appl. Phys., 2005, vol. 38, p. 1450.

    Article  CAS  Google Scholar 

  22. Davidson, D.W. and Cole, R.H., Dielectric relaxation in glycerine, J. Chem. Phys., 1950, vol. 18, p. 1417.

    Article  CAS  Google Scholar 

  23. Ashok, J., Kostrzewa, M., Ingram, A., Venkatramaiah, N., Srinivasa Reddy, M., Ravi Kumar, V., Piasecki, M., and Veeraiah, N., Structural and dielectric features of silver doped sodium antimonate glass ceramics, J. Alloy. Compd., 2019, vol. 791, p. 278.

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported by the Slovak Science Foundations, projects VEGA 1/0235/18, VEGA 1/0144/20, APVV SK-FR-19-0007, and APVV DS-FR-19-0036, P. Kostka acknowledges the Czech Science Foundation—project no. 19-07456S and the Ministry of Education, Youth and Sports of the Czech Republic—project no. 8X20053.This publication is partially supported by the European Union through the European Regional Development Fund (ERDF), the Ministry of Higher Education and Research, the French region of Brittany and Rennes Métropole.

Author information

Authors and Affiliations

  1. Faculty of Materials Science and Technology, Slovak University of Technology, 91724, Trnava, Slovakia

    O. Bošák, M. Kubliha, S. Minarik & M. Domankova

  2. Laboratory of Inorganic Materials, Institute of Rock Structure and Mechanics of the Czech Academy of Sciences, V Holešovičkách, 18209, Prague, Czech Republic

    P. Kostka

  3. Laboratory of Inorganic Materials, University of Chemistry and Technology Prague Technická, 16628, Prague 6, Czech Republic

    P. Kostka

  4. Université de Rennes, CNRS – ISCR UMR 6226, F-35000, Rennes, France

    D. Le Coq

Authors
  1. O. Bošák
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Kubliha
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. Kostka
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. Minarik
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. Domankova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. D. Le Coq
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to O. Bošák.

Ethics declarations

CONFLICT OF INTERESTS

The authors declare that they have no conflict of interest.

INFORMATION OF PERSONAL CONTRIBUTIONS OF AUTHORS

D. Le Coq prepared samples of glasses for experiments and performed DSC experiments. O. Bošák and M. Kubliha performed measurements of direct electrical conductivity and modular spectra. S. Minarik analysed modular spectra. O. Bošák, M. Kubliha, M. Domankova, and P. Kostka wrote the first draft of the manuscript. All authors edited the manuscript and approved the final version.

ADDITIONAL INFORMATION

Authors ORCID ID. O. Bošák (0000-0001-6467-5398), M. Kubliha (0000-0003-4987-6233), P. Kostka (0000-0003-2868-1322), S. Minarik (0000-0002-6851-0053), M. Domankova(0000-0002-0595-1943), D. Le Coq (0000-0001-7898-3463).

Additional information

Based on the materials of the report at the 15th International Meeting “Fundamental Problems of Solid State Ionics,” Chernogolovka, 30.11.–07.12.2020.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Bošák, O., Kubliha, M., Kostka, P. et al. Electrical and Dielectric Properties of Sb2O3–PbCl2–AgCl Glass System. Russ J Electrochem 57, 681–687 (2021). https://doi.org/10.1134/S1023193521070041

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193521070041

Keywords:

Search

Navigation