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Electrochemical Properties of Cobalt(II), Nickel(II) and Iron(II) Ions in the Presence of 2,2'-Bipyridine

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Abstract

The electrochemical properties of cobalt(II), nickel(II), and iron(II) ions are studied by cyclic voltammetry in the presence of increasing amounts of 2,2'-bipyridine (bpy). It is shown that the addition of insignificant amounts of bpy (10–50 mol %) to solutions containing cobalt(II), nickel(II), and iron(II) ions leads to stabilization of the reduced metal(0) forms and prevents both their electrochemical deposition and the formation of unsoluble metal associates.

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Funding

This study was supported by the Russian Science Foundation (project no. 18-13-00442).

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Authors and Affiliations

  1. Kazan (Volga Region) Federal University, 420008, Kazan, Russia

    A. F. Khusnuriyalova, A. V. Sukhov, G. E. Bekmukhamedov & D. G. Yakhvarov

  2. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, 420088, Kazan, Russia

    A. F. Khusnuriyalova, A. V. Sukhov, G. E. Bekmukhamedov & D. G. Yakhvarov

Authors
  1. A. F. Khusnuriyalova
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  2. A. V. Sukhov
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  3. G. E. Bekmukhamedov
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  4. D. G. Yakhvarov
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Correspondence to D. G. Yakhvarov.

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Translated by T. Safonova

Published on the basis of materials of the XIX All-Russian Conference “Electrochemistry of Organic Compounds” (EKHOS-2018) (with international participation), Novocherkassk, 2018.

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Khusnuriyalova, A.F., Sukhov, A.V., Bekmukhamedov, G.E. et al. Electrochemical Properties of Cobalt(II), Nickel(II) and Iron(II) Ions in the Presence of 2,2'-Bipyridine. Russ J Electrochem 56, 293–299 (2020). https://doi.org/10.1134/S1023193520040059

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  • DOI: https://doi.org/10.1134/S1023193520040059

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