Skip to main content
Log in

Calculation of the Number of Nuclei at Potentiostatic Electrochemical Nucleation with Regard to the Kinetic Stage

  • Short Communications
  • Published:
Russian Journal of Electrochemistry Aims and scope Submit manuscript

Abstract

The disagreement between experimental and calculated numbers of nuclei formed on the surface during electrocrystallization under potentiostatic conditions is shown to be caused by disregard of the kinetics of the electrochemical stage of this process. A new equation is proposed which allows correctly determining the mentioned number.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

References

  1. Gamburg, Yu.D., Current vs. time dependence at potentiostatic growth of clusters under conditions of potentiostatic deposition, Russ. J. Electrochem. (in press).

  2. Scharifker, B.R. and Mostany, J., Three-dimensional nucleation with diffusion controlled growth, J. Electroanal. Chem., 1984, vol. 177., p. 13.

    Google Scholar 

  3. Mirkin, M.V. and Nilov, A.P., 3D nucleation and growth under controlled potential, J. Electroanal. Chem., 1990, vol. 283, p. 35.

    CAS  Google Scholar 

  4. Gamburg, Yu.D., Overlapping of diffusion zones during the growth of electrodeposited crystal nuclei, Russ. J. Electrochem., 2003, vol. 39, p. 318.

    Article  CAS  Google Scholar 

  5. Danilov, A.I., The nature of active sites, kinetics, and mechanism of initial stages of copper electrocrystallization, Doctoral (Chem.) Dissertation, Moscow: Frumkin Inst. Fiz. Khim. Elektrokhim., 2002.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yu. D. Gamburg.

Additional information

Original Russian Text © Yu.D. Gamburg, 2019, published in Elektrokhimiya, 2019, Vol. 55, No. 2, pp. 253–255.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Gamburg, Y.D. Calculation of the Number of Nuclei at Potentiostatic Electrochemical Nucleation with Regard to the Kinetic Stage. Russ J Electrochem 54, 1301–1303 (2018). https://doi.org/10.1134/S1023193518130153

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1023193518130153

Keywords

Navigation